Warianty tytułu
Języki publikacji
Abstrakty
34-membered macrocyclic hexaamine containing two independent N-3 donor sets forms homodinuclear transition metal complexes with cobalt(II), copper(II), and nickel(II). Titration experiments show that the homodinuclear complexes are formed exclusively without formation of mononuclear complexes. Displacements of anions within the copper(II) complexes occur easily upon addition of different anions to the CuCl2 complex. All new complexes are characterized by elemental analysis, IR and UV/VIS spectroscopy, and cyclic voltammetry. The dinuclear Cu(II) complex both in the solution and immobilized in Nafion layer on the electrode undergoes revesible l e reduction independently at each copper center and exhibits catalytic activity towards oxygen reduction.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
852-859
Opis fizyczny
Bibliogr. 22 poz., tab., wykr.
Twórcy
autor
autor
autor
autor
- Institute of Physical Chemistry Polish Academy of Sciences 01-224 Warsaw Kasprzaka 44/52 Poland
Bibliografia
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BAR2-0002-0016