The kinetics of the Sn(II)/Sn electrode reaction in pure molten tin dichloride

• Autorzy: Kaźmierczak, J. , Kowalczewska, K.
• Języki publikacji: EN

Abstrakty

EN

Results of electrochemical investigation of the Sn(II)/Sn electrode reaction in pure molten tin(II) chloride are presented. The exchange current density has been determined by relaxation and impedance methods as 1.6 A cm(-2) for the anodic and 1.2 A cm(-2) for the cathodic process, both exhibiting a weak temperature dependence. Both, the inductive model of a double layer of a metallic electrode immersed in its pure molten salt, and a barrierless electron transition have been confirmed.

Słowa kluczowe

EN

electrode kinetics; exchange current; impedance; relaxation method; activation energy; high energy electrodes

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 6
• Strony: 1037-1044
• Opis fizyczny: Bibliogr. 9 poz., tab., wykr.

Twórcy

autor

Kaźmierczak, J.

autor

Kowalczewska, K.

• Faculty of Chemistry Wrocław University F.Joliot-Curie 14 50-383 Wrocław Poland,