Comparison of headspace solvent microextraction, hydrodistillation solvent microextraction, and solid-phase microextraction for the study of volatile components of Kelussia odoratissima Mozaff. by GC-MS

• Autorzy: Hashemi, P. , Yarahmadi, A. , Shamizadeh, M. , Khademi, K.
• Języki publikacji: EN

Abstrakty

EN

Kelussia odoratissima Mozaff. is a wild and endangered endemic plant found only in limited areas of central Zagros mountains, Iran. Three microextraction methods, that is, headspace solvent microextraction (HS-SME), hydrodistillation solvent microextraction (HD-SME), and solid-phase microextraction (SPME), and a conventional hydrodistillation method were used and compared for the extraction and gas chromatography- mass spectrometric (GC-MS) analysis of volatile components of the plant. In the HS-SME and HD-SME methods, a suspended n-heptadecane microdroplet was used for the extraction from the sample headspace, while in the SPME method, a PDMS fiber was applied. The highest extraction efficiency was obtained for the SPME method, with the highest number of identified components and best precision. As a consequence, the SPME method was used for the comparison of the volatile components of seeds, leaves, and pedicles of K. odoratissima collected from three different regions. One of the major components of the plant was butyl phthalide. The levels of this compound in the extractions from leaves, pedicles, and seeds were 34.1, 23.8, and 12.9%, respectively. The results also showed considerable variation between the volatile components of the samples collected from different areas.

Słowa kluczowe

EN

Kelussia odoratissima Mozaff; aerial parts; hydrodistillation solvent microextraction; headspace solvent microextraction; gas chromatography-mass spectrometry

• Czasopismo: Acta Chromatographica
• Rocznik: 2012
• Tom: Vol. 24, no. 1
• Strony: 97--109
• Opis fizyczny: Bibliogr. 16 poz., rys., tab.

Twórcy

autor

Hashemi, P.

• Lorestan University Department of Chemistry, Faculty of Science Khoramabad Iran,
• Lorestan University of Medical Sciences Razi Herbal Medicines Research Center Khoramabad Iran

autor

Yarahmadi, A.

• Lorestan University Department of Chemistry, Faculty of Science Khoramabad Iran

autor

Shamizadeh, M.

• Lorestan University Department of Chemistry, Faculty of Science Khoramabad Iran

autor

Khademi, K.

• Agriculture and Natural Resource Research Center P.O. Box 348 Khoramabad Iran

Bibliografia

• [1] Z. Zhang and J. Pawliszyn, Anal. Chem., 65, 1843 (1993)
• [2] P. Hashemi, M. Shamizadeh, A. Badiei, A.R. Ghiasvand, and K. Azizi, Chromatographia, 70, 1147 (2009)
• [3] P. Hashemi, A. Yarahmadi, K. Azizi, and B. Sabouri, Chromatographia, 67, 253 (2008)
• [4] L. Xu, C. Basheer, and H.K. Lee, J. Chromatogr. A, 1152, 184 (2007)
• [5] F. Rezaei, A. Bidari, A.P. Birjandi, M.R.M. Hosseini, and Y. Assadi, J. Hazard. Mater., 158, 621 (2008)
• [6] P. Hashemi, S. Beyranvand, R. Siah Mansur, and A.R. Ghiasvand, Anal. Chim. Acta, 655, 60 (2009)
• [7] P. Hashemi, M.M. Abolghasemi, A.R. Ghiasvand, S. Ahmadi, H. Hassanvand, and A. Yarahmadi, Chromatographia, 69, 179 (2009)
• [8] P. Hashemi, M.M. Abolghasemi, A.R. Fakhari, S.N. Ebrahimi, and S. Ahmadi, Chromatographia, 66, 283 (2007)
• [9] R. Omidbaigi, F. Sefidkon, and K. Saeedi, JEOBP, 11, 594 (2008)
• [10] F. Ahmadi, M. Kadivar, and M. Shahedi, Food Chem., 105, 57 (2007)
• [11] K. Saeedi and R. Omidbaigi, Iran. J. Med. Arom. Plants, 25, 113 (2009)
• [12] R.P. Adams, Identification of Essential Oil Components by Gas Chromatography/Mass Spectroscopy, Allured Publishing Corporation, Carol Stream, IL, 2007
• [13] R.G. Brereton, Chemometrics: Data Analysis for the Laboratory and Chemical Plant, John Wiley & Sons Ltd, West Sussex, England, 2003
• [14] M. Borzoei, M Sc. thesis, Department of Chemistry, Lorestan University, Khoramabad, Iran, 2008
• [15] G. MacLeod and J.M. Ames, Phytochemistry, 28, 1817 (1989)
• [16] P. Hashemi, B. Delfan, A.R. Ghiasvand, M. Alborzi, and F. Raeisi, Acta Chromatogr., 22, 131 (2010)