Synthetic alkaline-earth hydroxyapatites: Influence of their structural, textural, and morphological properties over Co2+ ion adsorption capacity

• Autorzy: Granados-Correa, Francisco , Bonifacio-Martínez, Juan
• Języki publikacji: EN

Abstrakty

EN

This work addresses the synthesis of nanocrystalline barium, strontium, and calcium hydroxyapatites (Ca-HAps) via the chemical precipitation method, followed by calcination. To give a coherent picture of the most important structural, textural, and morphological properties of these materials and to investigate the influence of these characteristics over Co²⁺ ion adsorption capacity from aqueous solutions, the powders prepared were systematically characterized by X-ray diffraction, N_2-physisorption measurements, scanning electron microscopy (SEM), energy dispersive X-ray spectrometry, and Fourier Transformed Infrared spectroscopy (FTIR). The results clearly showed that the Ca-HAp obtained exhibits better nanocrystallinity, greater structural stability, high surface area, high total pore volume, and mesoporosity, compared with the other synthesized hydroxyapatites, and that these physicochemical properties share a direct correlation with favorable Co²⁺ ion adsorption capacity at room temperature and pressure. The results proved that the physicochemical features of resulting alkaline-earth hydroxyapatites, prepared via the chemical precipitation method, played a fundamental role during the adsorption of heavy metal (with high toxicity) from aqueous solutions.

Słowa kluczowe

EN

barium hydroxyapatite; strontium hydroxyapatite; calcium hydroxyapatite; chemical precipitation synthesis; Co2+ ion adsorption

• Czasopismo: Materials Science Poland
• Rocznik: 2021
• Tom: Vol. 39, No. 2
• Strony: 252--264
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Granados-Correa, Francisco

• Instituto Nacional de Investigaciones Nucleares, Departamento de Química, A.P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C.P. 11801, Ciudad de México, México,

autor

Bonifacio-Martínez, Juan

• Instituto Nacional de Investigaciones Nucleares, Departamento de Química, A.P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C.P. 11801, Ciudad de México, México

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Identyfikatory

DOI

10.2478/msp-2021-0022