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2006 | Vol. 18, nr 1-2 | 111--114
Tytuł artykułu

Electrochemical behavior of Ni-Ti alloy after surface modification

Wybrane pełne teksty z tego czasopisma
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The shape memory effect and superelasticity make the nickel-titanium alloy an interesting material for medical applications. But the biocompatibility has been questioned due to conflicting results in the literature. The latest research has shown that this situation may be caused by a variation in NiTi surface treatment. The appropriate surface treatment increases the corrosion resistance. The paper presents the electrochemical behavior of NiTi alloy after surface modification with the use of various techniques. Design/methodology/approach: The evaluation of the electrochemical behavior of NiTi alloy was realized both by recording of anodic polarization curves with the use of the potentiodynamic method and by an electrochemical impedance spectroscopy technique (EIS). Findings: Surface condition of metallic biomaterial determines its corrosion resistance. In the course of the work it was observed that the lowest values of corrosion current were recorded for the sterilized and the thermally passivated samples. The highest values of corrosion current were recorded for the ground samples. These samples obviously had also the highest corrosion rate. Research limitations/implications: The obtained results are the basis for the optimization of physicochemical properties of the metallic biomaterial. The future research should be focused on selected specific implants specially with respect to their application features. Practical implications: On the basis of the obtained results it can be stated that the suggested surface treatment can be applicable for medical implants due to the increase of the corrosion resistance and in consequence the increase of biocompatibility. Originality/value: The paper presents the influence of various methods of the surface treatment on corrosion resistance of the NiTi alloy. The suggested methods can be applied in treatment of the material intended for medical applications especially in cases where the surface roughness plays important role.
Wydawca

Rocznik
Strony
111--114
Opis fizyczny
Bibliogr. 20 poz., rys., tab., wykr.
Twórcy
  • Division of, Biomedical Engineering Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, marcin.kaczmarek@polsl.pl
autor
  • Division of, Chemistry and Inorganic Technology, Silesian University of Technology, 44-100 Gliwice, Poland
autor
  • Division of, Biomedical Engineering Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
  • Division of, Biomedical Engineering Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
  • Division of, Biomedical Engineering Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
Bibliografia
  • [1] N.B. Morgan, Medical shape memory alloy applications - the market and its products, Materials Science and Engineering A 378 (2004) 16–23.
  • [2] M.Kaczmarek, J.Tyrlik-Held, Z.Paszenda, J.Marciniak: Characteristics of stents in application and material aspect, Proceeding of the 12th International Scientific Conference „Achievements in Mechanical and Materials Engineering 2003”, Gliwice-Zakopane (2003) 421-428, (in Polish).
  • [3] J. Szewczenko, J. Marciniak: Corrosion of steel implants electrically stimulated, Proceeding of the 12th International Scientific Conference „Achievements in Mechanical and Materials Engineering 2003”, Gliwice-Zakopane (2003) 905-910.
  • [4] A. Ziębowicz, J. Marciniak: Maxillo-facial surgery - new generation of implants. Proceedings of the 3rd Scientific Conference on Materials, Mechanical and Manufacturing Engineering, Gliwice-Wisła (2005). 349-356.
  • [5] W. Walke, Z. Paszenda, J. Filipiak: Experimental and numerical biomechanical analysis of vascular stent. Journal of Materials Processing Technology, COMMENT’2005, Journal of Materials Processing Technology Vol. 164-165 (2005) 1263÷1268.
  • [6] W. Kajzer, M. Kaczmarek, J. Marciniak: Biomechanical analysis of stent - oesophagus system. The Worldwide Congress of Materials and Manufacturing Engineering and Technology COMMENT'2005, Journal of Materials Processing Technology Vol 162-163 (2005) 196÷202.
  • [7] A. Krauze, A. Ziębowicz, J. Marciniak: Corrosion resistance of intramedullary nails used in elastic osteosynthesis of children. The Worldwide Congress of Materials and Manufacturing Engineering and Technology COMMENT'2005. Journal of Materials Processing Technology Vol 162-163 (2005) 209÷214.
  • [8] T.G Frank, W. Xu, A. Cuschieri, Shape Memory Applications in Minimal Access Surgery - The Dundee Experience. Proc. Sec. Int. Conf. Shap. Mem. and Super. Techn., ed. A. Pelton, D. Hodgson, S. Russell, T. Duerig, (1997) 509-514.
  • [9] D.F. Williams, J. Black, P.J. Doherty, Consensus Report of Second Conference on Definitions in Biomaterials, Elsevier, Amsterdam, (1992) 525.
  • [10] W. Wiltshire, M. Ferreira and J. Lightelm, Allergies to dental metals, Quintessence Int. 27 (1996) 513–520.
  • [11] S. Lacy, K. Meritt, S. Brown and A. Puryear, Distribution of nickel and cobalt following dermal and systematic administration with in vitro and in vivo studies, J. Biomed. Mater. Res. 32 (1996) 279–283.
  • [12] R. Goyer, Toxic effect of metals, in: Cassarett and Doull’s Toxicology, C. Klassen, M. Amdun J. Doul, eds, Macmillan, New York, (1986) 582–635.
  • [13] R. Hayes, The carcinogenicity of metals in human, Cancer Causes and Control 8 (1997) 321–327.
  • [14] A. Oller, M. Costa, Carcinoginicity assessment of selected nickel compounds, Toxicol. Appl. Pharmac. 143 (1997) 152–166.
  • [15] A. Shabalovskaya, Surface, corrosion and biocompatibility aspects of Nitinol as an implant material Bio-Medical Materials and Engineering 12 (2002) 69–109 IOS Press.
  • [16] F. Mansfeld, Dont be afraid of Electrochemical Techniques - but use them with care Corrosion Science 44 (1988) 856.
  • [17] J. Mieluch, Impedancy methods in electrochemical investigations, Corrosion Protect 3 (1990) 78.
  • [18] A.K. Shukla, R. Balasubramaniam, S. Bhargava: Properties of passive film formed on CP titanium, Ti-6Al-4V and Ti-13.4Al-29Nb alloys in simulated human body conditions, Intermetallics 13 (2005) 631.
  • [19] F.T. Cheng, P Shi, H.C. Man, A preliminary study of TiO2 deposition on NiTi by a hydrothermal method, Surface and Coatings Technology 187 (2004) 26.
  • [20] C. Gabrielli, Identification of Electrochemical Processes by Frequency Response, Raport no.004/83, France, 1998.
Typ dokumentu
Bibliografia
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Identyfikator YADDA
bwmeta1.element.baztech-838b2e41-a79c-44d2-9226-a5c7624ecd9e
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