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2024 | Vol. 25, nr 9 | 182--189
Tytuł artykułu

Removal of Chromium Contaminated Soils by Electro-Kinetic Method

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Chromium-contaminated soil is a serious environmental problem that threatens human health and the environment. Electrokinetic technology is used as a promising solution to treat these soils, as it relies on applying an electric field to remove pollutants from the soil. In this study, four experiments were conducted, where experiments have shown that the use of wheat straw as an available, cheap, economical and efficient adsorbent material to prevent the occurrence of reverse osmosis. The results showed that the percentage of removal increased with the increase in the acidity of the medium, that is, as the pH decreased. This is due to an increase in the movement of pollutants as the soil particles become more positively charged, which enhances Attract negative heavy metal ions. This leads to increased movement of heavy metal ions into soil pores, making them more susceptible to transport under the influence of an electric field. The results proved that when using a disinfection solution with a pH of 2, it gave a higher result compared to pH 7 and 12, where the percentage of removal was 78.3%, 62.6 %, and 51.9% respectively. The dissolution of these metals can be enhanced by adding oxalic acid at a constant voltage gradient 1.2 v/cm and an initial concentration of 200 mg/kg. It was noted after the end of the experiment that the percentage of removal reached 81.9%, as the concentration of metals on the cathode side was higher than on the cathode side. The anode, and this is due to the migration of metals under the influence of electromigration to the cathode side, where the chromium concentration was 47 mg/kg at the cathode side, 27 mg/kg at the anode side.
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182--189
Opis fizyczny
Bibliogr. 13 poz., rys., tab.
Twórcy
  • Environmental Engineering Department, Al-Mustansiriyah University, Baghdad, Iraq
Bibliografia
  • 1. Acar, Y.B., Alshawabkeh, A.N. 1993. Principles of electrokinetic remediation. In Environmental Science & Technology. New Delhi, India.
  • 2. Ge, X., Xie, J., Song, X., Cao, X., Wang, Y., Xu, Z., Hou, X. 2022. Electrokinetic Remediation of Cadmium (Cd), Copper (Cu) and Nickel (Ni) Cocontaminated Soil with Oxalic Acid, Acetic Acid or Citric Acid as the Catholyte. International Journal of Electrochemical Science, 17(4), 220444.
  • 3. Han, D., Wu, X., Li, R., Tang, X., Xiao, S., Scholz, M. 2021. Critical review of electro-kinetic remediation of contaminated soils and sediments: mechanisms, performances and technologies. Water, Air, & Soil Pollution, 232(8), 335.
  • 4. Hawal, L.H., Al-Sulttani, A.O., Kariem, N.O. 2021a. Adsorption of lead ions from aqueous solutions onto rice husks, continuous system. Journal of Ecological Engineering, 22(10), 269–274. https://doi.org/10.12911/22998993/141936
  • 5. Hawal, L.H., Allah, S.A., Karbol, M.S. 2021b. Cadmium ions adsorption from aqueous solutions by Bentonite clay, fixed bed column. Journal of Physics: Conference Series, 1895(1), 012040 IOP Publishing. https://doi.org/10.1088/1742-6596/1895/1/012040.
  • 6. Hawal, L.H., Al-Sulttani, A.O., Hamza, J.N. 2023a. Cadmium removal from contaminated soil by electro-kinetic method. Journal of Ecological Engineering, 24(1), 79–86. https://doi.org/10.12911/22998993/156007.
  • 7. Hawal, L.H., Saeed, K.A., Al-Sulttani, A.O. 2023b. Copper metal elimination from polluted soil by electro-kinetic technique. Environmental Monitoring and Assessment, 195(4), 443. https://doi.org/10.1007/s10661-023-11057-4
  • 8. Herngren, L., Goonetilleke, A., Ayoko, G.A. 2005. Understanding heavy metal and suspended solids relationships in urban stormwater using simulated rainfall. Journal of environmental management, 76(2), 149–158.
  • 9. Idera, F., Omotola, O., Paul, U.J., Adedayo, A. 2014. Evaluation of the effectiveness of different acid digestion on sediments. matrix, 12, 13.
  • 10. Reddy, K.R., Shirani, A.B. 1997. Electrokinetic remediation of metal contaminated glacial tills. Geotechnical & Geological Engineering, 15, 3–29.
  • 11. Rosestolato, D., Bagatin, R., Ferro, S. 2015. Electrokinetic remediation of soils polluted by heavy metals (mercury in particular). Chemical Engineering Journal, 264, 16–23.
  • 12. Shariatmadari, N., Weng, C.H., Daryaee, H. 2009. Enhancement of hexavalent chromium [Cr(VI)] remediation from clayey soils by electrokinetics coupled with a nano-sized zero-valent iron barrier. Environmental Engineering Science, 26(6), 1071–1079.
  • 13. Srivastava, R.K., Tiwari, R.P., Ramudu, P.B. 2007. Electrokinetic remediation study for cadmium contaminated soil. Journal of Environmental Health Science & Engineering, 4(4), 207–214.
Typ dokumentu
Bibliografia
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Identyfikator YADDA
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