FTIR of grafted metallocene polyolefins for hot melt adhesives

• Autorzy: Novák, I. , Pavlinec, J. , Chodák, I. , Kleinová, A. , Preťo, J. , Vanko, V.
• Języki publikacji: EN

Abstrakty

EN

The activated RXP suspended in an aqueous acrylic acid (AA) solution does contain peroxide groups in sufficient concentration. The temperature of 60°C is too low to generate free radicals to initiate grafting. FTIR absorbance for acid carbonyl compounds at 1715 cm-1 and at 1464 cm-1 show the proliferation of PAA graft quantity depending on the amount of AA in the feedstock.

Słowa kluczowe

EN

metallocene polyolefin; hot melt adhesives

• Czasopismo: Annals of Warsaw University of Life Sciences - SGGW. Forestry and Wood Technology
• Rocznik: 2018
• Tom: No. 104
• Strony: 157--162
• Opis fizyczny: Bibliogr. 10 poz.

Twórcy

autor

Novák, I.

• Polymer Institute SAS, Dúbravská cesta 9, 845 41 Bratislava, Slovakia

autor

Pavlinec, J.

• Polymer Institute Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia

autor

Chodák, I.

• Polymer Institute Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia

autor

Kleinová, A.

• Polymer Institute SAS, Dúbravská cesta 9, 845 41 Bratislava, Slovakia

autor

Preťo, J.

• VIPO, Gen. Svobodu 1069/4, Partizánske, Slovakia

autor

Vanko, V.

• VIPO, Gen. Svobodu 1069/4, Partizánske, Slovakia

Bibliografia

• 1. BUCHENSKA J. 2002: PP Fibres Grafted with Acrylic Acid. Journal of Applied Polymer Science 83, 2295, (2002).
• 2. PATEL J.B., EODICE A. K., LOW Y G. 2010: Low application temperature hot melt adhesive. PCT/US 2010/043804 (2010).
• 3. DAVIS K. T. 2012 Olefin-based hot melt adhesive compositions and nonwoven and packaging articles including the same. US20120329353 (2012).
• 4. YALVAC S., KARJALA T., O´BRYAN E. 2005: Adhesives & Sealants Industry 12, 34 (2005).
• 5. LAZÁR M., RADO R., PAVLINEC J. 1961: Grafting of methyl methacrylate to polypropylene and polyethylene. Journal of Polymer Science 53, 163 (1961).
• 6. MAŇÁSEK Z., BEREK D., MIČKO M., LAZÁR M., PAVLINEC J. 1963: Formation and decomposition of hydroperoxides of atactic polypropylene. Rubber Chem. Technol. 36, 532 (1963).
• 7. BUCHENSKA J. 2002: Polypropylene fibres grafted with acrylic acid. J. Appl. Polym. Sci. 83, 2295 (2002).
• 8. KAUFMAN M. S. 2008: Radical-mediated modification of polyolefins: Investigation of the synthesis of graft copolymers. Thesis, Queen’s University Kingston, Ontario, Canada, May 2008; 1-81.
• 9. PICCHIONI F., GOOSSENS J. G. P., VAN DUIN M. 2001: Solid-state modification of polypropylene (PP): grafting of styrene on atactic PP. Macromol Symp 176, 245 (2001).
• 10. WANG H., BROWN H. R. 2004: UV grafting of methacrylic acid and acrylic acid on high-density polyethylene in different solvents and the wettability of grafted highdensity polyethylene. II. Wettability. J Polym Sci Part A: Polym Chem 42, 263 (2004).

Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).