Mix-substituted phthalocyanines of a “push–pull”-type and their metal complexes as prospective nanostructured materials for optoelectronics

• Autorzy: Usol'tseva, N. V. , Smirnova, A. I. , Kazak, A. V. , Giricheva, N. I. , Galanin, N. E. , Shaposhnikov, G. P. , Bodnarchuk, V. V. , Yablonskii, S. V.
• Języki publikacji: EN

Abstrakty

EN

To study the influence of structural features of phthalocyanine (Pc) derivatives on their physico-chemical properties in bulk and thin films, 23 new phthalocyanines with different quantity and ratio of donor (alkyloxy-groups, in fragment “A”) and acceptor (Cl-, in fragment “B”) substituents in one molecule of the A3B, ABAB and AABB types with varied length of alkyloxy-substituents and their metal complexes were designed and synthesized. A comparative analysis of spectral, mesomorphic and photoelectric properties of these mix-substituted phthalocyanines of a “push–pull” type was performed. It was shown that non-peripheral substitution by alkyloxy-fragments in hetero-substituted Pcs (similar to homo-substituted Pc) leads to red-shifting of the Q-band into near-IR region. The intensity of photoluminescence, position of peaks and their splitting are strongly connected with chemical structure of Pcs and the type of solvent. In contrast to non-mesogenic octyloxy-Pc (A4) having alkyloxy-substituents in non-peripheral positions, 22 of 23 synthesized compounds possess columnar mesomorphism. The change of donor–acceptor ratio can influence the type of mesophase. A new approach to the creation of materials for optoelectronics is proposed and implemented, which includes design of compounds possessing vitrification from mesophase with maintenance of a columnar order, absorption in the near IR-region of the spectrum and good performance electrophysical characteristics simultaneously.

Słowa kluczowe

EN

push-pull phthalocyanines; liquid crystals; electronic absorption spectra; fluorescence; photoelectric properties; Langmuir–Schaefer films; DFT calculations; photovoltaics

• Czasopismo: Opto-Electronics Review
• Rocznik: 2017
• Tom: Vol. 25, No. 2
• Strony: 127--136
• Opis fizyczny: Bibliogr. 46 poz., il., rys., wykr.

Twórcy

autor

Usol'tseva, N. V.

• Nanomaterials Research Institute, Ivanovo State University, Ivanovo 153025, Russia

autor

Smirnova, A. I.

• Nanomaterials Research Institute, Ivanovo State University, Ivanovo 153025, Russia

autor

Kazak, A. V.

• Nanomaterials Research Institute, Ivanovo State University, Ivanovo 153025, Russia
• Shubnikov Institute of Crystallography of the Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences, Moscow 119333, Russia

autor

Giricheva, N. I.

• Nanomaterials Research Institute, Ivanovo State University, Ivanovo 153025, Russia

autor

Galanin, N. E.

• Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

autor

Shaposhnikov, G. P.

• Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

autor

Bodnarchuk, V. V.

• Shubnikov Institute of Crystallography of the Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences, Moscow 119333, Russia

autor

Yablonskii, S. V.

• Shubnikov Institute of Crystallography of the Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences, Moscow 119333, Russia

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Uwagi

PL

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017)

Identyfikatory

DOI

10.1016/j.opelre.2017.03.003