Insight into Nano Zero-Valent-Copper Process for Degradation Dye Wastewater–Optimization by Box-Behnken Design and Toxicity Evaluation

• Autorzy: Nguyen, Hoa Thanh , Nguyen, Nguyen Thi The
• Języki publikacji: EN

Abstrakty

EN

This study focuses on utilization of a zero-valent metal (zero-valent iron, zero-valent aluminum, and nanoscale zerovalent copper) in conjunction with H₂O₂ conducted to treat real dye wastewater. Box-Behnken methodology was applied to describe effects of five independent factors involved in optimization of advanced oxidation system, which was type of zero-valent metals, dosage of zero-valent metals, pH, time and dosage of H₂O₂, for treating dye wastewater. Correlation coefficients for model, shown by the value R², were 0.9996 for removing color and 0.9708 for reducing COD. Mass of nZVC equaled 1.09 g/L, H₂O₂ equaled 5.39 mg/L were found to be the optimal reaction conditions when the pH was equal to 3.71. After 120 minutes of optimal settings, there was a reduction of 87.3% in COD and 98.72% in color of dye wastewater after heterogeneous treatments (nZVC/H₂O₂). The reusability of nZVC for degrading dye wastewater has been tested in four cycles and showed up to 70% COD removal. Ecotoxicological testing indicated that the raw textile effluent was extremely toxic to Chlorella sp. and V. fischeri. Even while wastewater after treatment collected definitely had a lower toxicity level with both V. fischeri and Chlorella sp. This research findings highlight the nZVC/H₂O₂ process as a feasible and effective method for real dye wastewater treatment and detoxification, positioning it as a valuable alternative oxidation process for treating organic contaminants.

Słowa kluczowe

EN

advanced oxidation process; Box Behnken design; dye wastewater; nano zero-valent copper

• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2024
• Tom: Vol. 25, nr 10
• Strony: 42--52
• Opis fizyczny: Bibliogr. 31 poz., rys., tab.

Twórcy

autor

Nguyen, Hoa Thanh

• Faculty of Chemistry and Environment, Thuyloi University, 175 Tay Son, Dong Da, Hanoi, Vietnam,

autor

Nguyen, Nguyen Thi The

• Faculty of Chemistry and Environment, Thuyloi University, 175 Tay Son, Dong Da, Hanoi, Vietnam,

Bibliografia

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Identyfikatory

DOI

10.12911/22998993/191671