Warianty tytułu
Alternatywne podejście do usuwania/odzyskiwania wybranych metali z wody kopalnianej wypływającej z zalanej kopalni syderytu Nižná Slaná
Języki publikacji
Abstrakty
The objective of this work was the application of innovative method for metals recovery from metalliferous mine water released from the flooded siderite ore deposit Nižná Slaná. Although the metals contained in mine drainage are considered environmental pollutants, they may also be recognised as valuable resources. Several techniques can be used to obtain them by precipitation. Conventional processes using alkaline reagents produce huge amounts of mixed sludge with appropriate storage and management requirement, void of possibility of individual metals subsequent processing. This study examined the feasibility of Fe and Mn selective retrieval from real mine water. After oxidation and partial precipitation of iron using hydrogen peroxide, precipitation by sodium hydroxide was applied to the residue iron removal from mine water. In the next step potassium permanganate was used to eliminate manganese by oxidative precipitation. ORP and pH values of processed mine water was recorded in the course of oxidation/precipitation processes. The morphology and elemental composition of obtained products were studied by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The recovery efficiencies of Fe and Mn from mine water reached 99.87 % and 99.25%, respectively. Target metals were removed with high selectivity to levels that comply with environmental requirements.
Czasopismo
Rocznik
Tom
Strony
537--543
Opis fizyczny
Bibliogr. 27 poz., tab., wykr., zdj.
Twórcy
autor
- Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 040 01 Košice, Slovakia, macingova@saske.sk
autor
- Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 040 01 Košice, Slovakia, luptakal@saske.sk
autor
- Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 040 01 Košice, Slovakia, dankup@saske.sk
autor
- Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 040 01 Košice, Slovakia, briancin@saske.sk
Bibliografia
- 1. K. D. Nordstrom, R.J. Bowell, K. M. Campbell and C. N. Alpers, “Challenges in Recovering Resources from Acid Mine Drainag,” IMWA 2017 - Mine Water and Circular Economy, Lappeenranta, Finland, pp. 1138-1146, 2017.
- 2. X. Wei, S. Zhang, J. Shimko and R. W. Dengler, “Mine drainage: Treatment technologies and rare earth elements,” Water Environment Research, 91, pp. 1061–1068, 2019.
- 3. J. Lopez, M. Reig, X. Vecino, O. Gilbert and J. L. Cortina, “From nanofiltration membrane permeances to design projections for the remediation and valorization of acid mine drainage,” Science of the Total Environment, 738, 139780, 11 p., 2020.
- 4. L. F. Leon-Fernandez, H. L. Medina-Diaz, O. G. Perez, L. R. Romero, J. Villasenor and F. J. Fernandez Morales, “Acid mine drainage treatment and sequential metal recovery by means of bioelectrochemical technology,” J. Chem. Technol. Biotechnol., 96, pp. 1543–1552, 2021.
- 5. J. Yuan, Z. Ding, Y. Bi, J. Li, S. Wen and S. Bai, “Resource Utilization of Acid Mine Drainage (AMD): A Review,” Water, 14, 2385, 15 p., 2022.
- 6. E. Leon-Venegas, L. F. Vilches-Arenas, C. Fernandez-Baco and F. Arroyo-Torralvo, “Potential for water and metal recovery from acid mine drainage by combining hybrid membrane processes with selective metal precipitation,” Resources, Conservation & Recycling, 188, 106629, 10 p., 2023.
- 7. J. Brehuv, T. Špaldon, O. Šestinová, P. Slančo, P, J. Hančuľák and M. Bobro, “Contamination of the Water and Sediment Load from the Drainage Basin of the Slaná River by Influence of Former and Present Mining Activities,” Acta Facultatis Ecologiae, 16, pp. 91–100, 2007.
- 8. P. Liščák, P. Bajtoš, E. Mašlár, I. Mašlárová and I. Slaninka, “Impact of Mineral Resources Exploitation on the Environment; Geological Task: Partial Monitoring System of Geological Factors,” Annual Report 2019, MoE SR, SGIDŠ; Spišská Nová Ves, 124 p., 2020 (in Slovak).
- 9. Protocol No. 2 from the Resolution of the Reported Pollution of the Slaná Watercourse, which Occurred on 24.02.2022 in the Municipality of Nižná Slaná. Slovak Inspectorate of the Environment- Košice, Department of Water Protection Inspection, 11.03.2022, 6 p., 2022 (in Slovak).
- 10. J. Liu, Q. Chen, Y. Yang, H. Wei, M. Laipan, R. Zhu, H. He and M. F. Hochella Jr., “Coupled redox cycling of Fe and Mn in the environment: The complex interplay of solution species with Fe- and Mn-(oxyhydr)oxide crystallization and transformation,” Earth- Science Reviews, 232, 104105, 16 p., 2022.
- 11. F. J. Sikora, L. L. Behrends, G. A. Brodie and H. N. Taylor, “Design criteria and required chemistry for removing manganese in acid mine drainage using subsurface flow wetlands,” Water Environment Research, 72, pp. 536-544, 2000.
- 12. X. Liu, Y. Sang, H. Yin, A. Lin, Z. Guo and Z. Liu, “Progress in the mechanism and kinetics of fenton reaction,” MOJ Ecology & Environmental Science, vol. 3, no. 1, pp. 10-14, 2018.
- 13. P. Salgado, V. Melin, D. Contreras, Y. Moreno and H. D. Mansilla, “Fenton reaction driven by iron ligands,” Journal of the Chilean Chemical Society, 58, no. 4, pp. 2096-2101, 2013.
- 14. E. Mačingová and A. Luptáková, “Recovery of Metals from Acid Mine Drainage”, Chemical Engineering Transaction, 28, pp. 109-114, 2012.
- 15. Z. Teng, J. Y. Huang, K. Fujita and S. Takizawa, “Manganese removal by hollow fiber micro-filter. Membrane separation for drinking water,” Desalination, 139, pp. 411-418, 2001.
- 16. L. A. C. Teixeira, J. S. dos Santos, V. S. L. Costa, L. Yokoyama and C.M. Sarmiento, “Preliminary Studies on Precipitating Manganese Using Caro’s Acid and Hydrogen Peroxide,“ Mine Water Environ, 29, pp. 154-157, 2010.
- 17. J. Jönsson, P. Persson, S. Sjöberg and L. Lövgren, “Schwertmannite precipitated from acid mine drainage: phase transformation, sulphate release and surface properties,” Applied Geochemistry, 20, pp. 179-191, 2005.
- 18. A. H. Kaksonen, C. Morris, S. Rea, J. Li, J. Wylie, K. M. Usher, M. P. Ginige, K. Y. Cheng, F. Hilario and C. A. du Plessis,”Biohydrometallurgical iron oxidation and precipitation: Part I – Effect of pH on process performance,” Hydrometallurgy, 147-148, pp. 255-263, 2014.
- 19. J. M. Bigham, L. Carlson and E. Murad, “Schwertmannite, a new iron oxyhydroxysulfate from Pyhäsalmi, Finland, and other localities,” Mineralogical Magazine, 58, pp.641-648, 1994.
- 20. E. Mačingová and A. Luptáková, “Recovery of Iron from Acid Mine Drainage in the Form of Oxides,” Inżynieria Mineralna - Journal of the Polish Mineral Engineering Society, vol. 15, no. 2, pp. 193-198, 2014.
- 21. A. H. Kaksonen, C. Morris, S. Rea, J. Li, K. M. Usher, R. G. McDonald, F. Hilario, T. Hosken, M. Jackson and C. A. du Plessis,”Biohydrometallurgical iron oxidation and precipitation: Part II – Jarosite precipitate characterisation and acid recovery by conversion to hematite,” Hydrometallurgy, 147-148, pp. 264-272, 2014.
- 22. M. Ristić, S. Musić and Z. Orehovec,” Thermal decomposition of synthetic ammonium jarosite,” Journal of Molecule Structure, 744-747, pp. 295-300, 2005.
- 23. E. Mačingová, S. Ubaldini and A. Luptáková, “Study of Manganese Removal in the Process of Mine Water Remediation,” Inżynieria Mineralna - Journal of the Polish Mineral Engineering Society, vol. 17, no. 1, pp. 121-127, 2016.
- 24. L. A. C. Teixeira, J. P. L. Queiroz and C. Marquez-Sarmiento, “Oxidative precipitation of Manganese from Dilute Waters,” Mine Water and the Environment, 36, pp. 452-456, 2017.
- 25. R. M. Freitas, T. A. G. Perilli and A. C. Q. Ladeira, “Oxidative Precipitation of Manganese from Acid Mine Drainage by Potassium Permanganate,” Journal of Chemistry, 287257, 8 p., 213.
- 26. W. Sun, D. A. Kitchaev, D. Kramer and Gerbrand Ceder, “Non-equilibrium crystallization pathways of manganese oxides in aqueous solution,” Nature Communications, 10:573, pp. 1-9, 2019.
- 27. P. D. Howe, H. M. Malcolm and S. Dobson, “Manganese and its compounds: Environmental aspects,” Concise International Chemical Assesment Document, 63, World Health Organization, Geneva, 70 p., 2004.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki i promocja sportu (2025).
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-0b05e24d-b501-4ef4-aeb0-d3178fcea686