Interaction of metals with humic acid isolated from oxidized coal

• Autorzy: Erdogan S , Baysal A. , Akba O. , Hamamci C.
• Języki publikacji: EN

Abstrakty

EN

The sorption behaviour of divalent cations M+ (Cu, Pb and Zn) and trivalent cations M3+ (Fe, Al) with humic acid isolated from oxidized coal (Hazro,SE Anatolia,Turkey) was followed in aqueous solution. Coal humic acid and metal ion interaction was investigated with special emphasis on the effects of pH, metal ion concentration and humic acid concentration. It has been found that the interaction of humic acid with metal ions in solution increases with pH, decreases with metal ion concentration and increases with humic acid concentration. The differences in sorption ability of particular metal ions on oxidized coal-derived humic acid are Fe> Pb> Cu> Al> Zn and Fe> Pb> Al> Cu> Zn at pH 2.5 and 3.5, respectively, while they are Fe=Pb=Cu=Al> Zn at both pH 4.5 and 5.5. The interaction of some trivalent (Fe, Al) and divalent(Cu, Pb, Zn) metal ions with humic acid prepared from coal was also studied using FTiR spectroscopy. This has proven helpful with respect to metal binding to understand better the potential sites of binding within the humic acid. Infrared spectroscopy showed the participation of cOOH and OH groups in binding to the metal ions.

Słowa kluczowe

EN

soil pollution; metal; humic acid; interaction; coal; sorption; cation; pH effect; metal ion concentration; humic acid concentration; infrared spectroscopy

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2007
• Tom: 16
• Numer: 5
• Strony: 671-675
• Opis fizyczny: p.671-675,fig.,ref.

Twórcy

autor

Erdogan S

• Dicle University, Diyarbakir, Turkey

autor

Baysal A.

autor

Akba O.

autor

Hamamci C.

Bibliografia

• 1. SPARK K.M., WELLS J.D., JOHNSON B.B., The interac­tion of a humic acid with heavy metals. Aust. J. Soil Res., 35, 89, 1997.
• 2. SLAVEK J., WOLD J., PICKERING W.F., Selective extrac­tion of metal ions associated with humic acids. Talanta, 29, 743, 1982.
• 3. ALFASSI Z.B., On the precipitation of salts/complexes of trivalent cations with humic acid. J. Radioanal. Nucl. Ch., 262, 77, 2004.
• 4. BEVERIDGE A., PICKERING W.F., Influence of humate- solute interactions on aqueous heavy metal ion levels. Water Air Soil Poll., 14, 171, 1980.
• 5. CEZIKOVA J., KOZLER J., MADRONOVA L., NOVAK J., JANOG P.J, Humic acids from coals of the North-Bohe­mian coal field.Metal-binding capacity under static condi­tions. React. Funct. Polym. 47, 111, 2001.
• 6. ERDOGAN S., MERDIVAN M., HAMAMCI C., AKBA, O., BAYSAL A., Polymer supported humic acid for sepa­ration and preconcentration of thorium(IV). Anal.Lett., 37, 2565, 2004.
• 7. GRABOWSKA E.L., GRYGLEWIEZ G., Adsorption of lignite-derived humic acids on coal-based mesoporous acti­vated carbons. J. Colloid. Interf. Sci., 284, 416, 2005.
• 8. GUIBAUD G., TIXIER N., BOUJU A., BAUDU M., Re­lation between extracellular polymers' composition an dits ability to complex Cd,Cu and Pb. Chemosphere. 52, 1701, 2003.
• 9. SHTANGEEVA I.V., VUORINEN A.V., RIETZ B., CHRIS­TIANSEN G., CARLSON L.C, Decontamination of pol­luted urban soils by plants.Our possibilities to enhance the uptake of heavy metals. J. Radioanal. Nucl. Ch. 249, 369, 2001.
• 10. LINGBO L., SONG Y., CONGBI H., GUANGBO S., Com- perensive characterization of oil refinery effluent-derived humic substances using various spectroscopic approaches. chemosphere. 60, 467, 2005.
• 11. LOGAN E.M., PULFORD I.D., COOK G.T., MACKEN­ZIE A.B., Complexation of Cu2+ and Pb2+ by peat and hu­mic acid. Eur. J. soil sci. 48, 685, 1997.
• 12. ELKINS K.M., NELSON D.J., Spectroscopic approaches to the study of the interaction of aluminum with humic sub­stances. coordin. chem. Rev. 228, 205, 2002.
• 13. IBARRA J.V., ORDUNA P., Variation of metal complexing ability of humic acids with coal rank. Fuel. 65, 1012, 1986.
• 14. GOSSART P.G, SEMMOUD A., RUCKEBUSH C., HU- VENNE J.P., Multivariate curve resolution applied to Fou­rier transform infrared spectra of macromolecules:structural characterisation of the acid form and salt form of humic acids in interaction with lead. Anal. chim. Acta. 477, 201, 2003.
• 15. EVANGELOU V.P., MARSI M., CHAPPEL M.A., Poten- tiometric-spectroscopic evaluation of metal-ion complexes by humic fractions extracted from corn tissue. Spectrochim. Acta a. 58, 2159, 2002.
• 16. GUCLU K., APAK R.,. Modeling the adsorption of free and heavy metal complex-bound EDTA onto red mud by a non- electrostatic surface complexation model. J. Colloid. Interf. sci. 260, 280, 2003.
• 17. GOLONKA I., CZECHOWSKI F., JEZIERSKI A., EPR characteristics of heat treated complexes of metals with demineralised humic brown coal in air and ammonia atmo­spheres. Geoderma. 127, 237, 2005.
• 18. ERDOGAN S., DUZ M.Z, MERDIVAN M., HAMAMCI C., Formation and characterization of humic acids from low rank Anatolian coals by air oxidation. Energ. Source. 27, 423, 2005.
• 19. DUZ M.Z., TONBUL Y., BAYSAL A., AKBA O., SAYDUT A., HAMAMCI C., Pyrolysis kinetics of chemical composi­tion of Hazro coal according to particle size. J.Therm.Anal. calorim. 81, 395, 2005.
• 20. SCHAFER H.N.S., Determination of carboxyl groups in low-rank coals. Fuel. 63, 723, 1984.
• 21. LUBAL P., SIROKY D., FETSCH D., HAVEL J., The ac- idobasic and complexation properties of humic acids.Study of complexation of Czech humic acids with metal ions Ta- lanta. 47, 401, 1998.
• 22. BARUAH M.K., UPRETI M.C., Preferential uptake of Fe(III) by humic acid extracted from lignite, Fuel. 73, 273, 1994.
• 23. PANDEY A.K., PANDEY S.D.,MISRA V., VISWANA- THAN P.N., Role of free radicals in the binding of organo- chlorine pesticides and heavy metals with humic acid. sci. Total environ. 231, 125, 1999.
• 24. HIZAL J., APAK R., Modelling of copper(II)and lead(II) ad­sorption on kaolinite based clay minerals individually and in the presence of humic acid. J. colloid. Interf. sci. 295, 1, 2006.
• 25 PRADO A.G.S., AIROLDI C., Humic acid-divalent cation interactions. Thermochim.Acta. 405, 287, 2003.
• 26. ZHOU P., YAN H., GU B., Competitive complexation of met­al ions with humic substances. chemosphere. 58, 1327, 2005.
• 27. MARTYNIUK H., WIECKOWSKA J., Adsorption of metal ions on humic acids extracted from brown coals. Fuel Pro­cess. Technol. 84, 23, 2003.
• 28. ALBERTS J.J., FILIP Z., Metal binding in estuarine humic and fulvic acids:FTIR analysis of humic acid-metal com­plexes. environ.Technol. 19, 923, 1998.
• 29. KHALILI F., Preparation and characterization of selected metal-humate complexes. Soil Sci. 150, 565, 1990
• 30. SENESI N., SPOSITO G., MARTIN J.P., Copper(II) and Iron(III)complexation by soil humic acids:an ir and esr study. sci. Total. environ. 55, 351, 1986.
• 31. SHEN Y.H., Sorption of humic acid to soil:The role of soil mineral composition. chemosphere. 38, 2489, 1999.