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Abstrakty
The behavior of water solutions of dyes under the influence of oxidizing agents has been described. Decomposition of the dyes in time was observed on the basis of changes in the adsorption spectra. The obtained spectrophotometrical data were subjected to the factor analysis in order to determine the number and the spectral characteristics of colour components in the systems under study. The correctness of the accepted mechanism of decolouration (parallel and successive reactions) was tested and the number of reaction stages was determined. The rate constants of substrate decomposition and product formation were determined. Moreover, the spectral profiles of intermediate products were obtained.
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Opis fizyczny
p.425-429,fig.
Twórcy
autor
- University of Technology and Agriculture, Seminaryjna 3, 85-326 Bydgoszcz, Poland
autor
autor
autor
Bibliografia
- 1. PRZYBYŁEK M., Barwniki i Środki Pomocnicze, 2, 50, 1985.
- 2. THOMPSON K. M., GRIFFITH W. P., M Spiro, Journal of the Chemical Society - Faraday Transactions 90,(8), 1105, 1994.
- 3. DO J.S., YEH W.C., Journal of Applied Electrochemistry 26, (6), 673, 1996.
- 4. ARTEMEV, ARTEMEVA M.A., VINOGRADOV M.G., ILIKA T.I., Russian Journal of Applied Chemistry Part 2, 67, (9), 1354, 1994.
- 5. HACHEM C., BOCQUILLON F., ZAHRAA O., BOUCHY M., Dyes Pigm., 49(2), 117, 2001.
- 6. BANASZCZYK K., RADZYMIŃSKA E., GACA J., Gaz, Woda i Technika Sanitarna, 8, 233, 1994.
- 7. MALINOWSKI E.R., Factor Analysis in Chemistry, Wiley - Interscience, New York 2002.
- 8. ALBERGALI A., NYGERN J., KUBISTA M., Anal. Chim. Acta, 379, 143, 1999.
- 9. OTTO M., Chemometrics, Wiley - VCH Verlag GmbH, Weinheim, 1999.
- 10. MALINOWSKI E. R, Anal. Chim. Acta, 103, 339, 1978.
- 11. DE LEVIE R., J.Chem.Educ., 76, 1594, 1999.
Typ dokumentu
Bibliografia
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