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Abstrakty
We studied the electric properties of phosphatidylcholine bilayers modified with crown ether (dibenzo[18] crown-6). The studies were carried out for various crown ether concentrations in forming solutions and various potassium ion concentrations in electrolyte solutions. The presence of crown ether in the membrane influences the membrane's impedance; there is a reduction in its resistivity, a decrease in its resistance of phase transfer and an increase in its capacity of phase transfer with an increase in crown ether concentration in the bilayer and in K+ ion concentration in the electrolyte solution.
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Opis fizyczny
p.383-389,fig.
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autor
- University of Bialystok, Al.J.Pilsudskiego 11-4, 15-443 Bialystok, Poland
autor
autor
Bibliografia
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- 2.Gokel, G.W. and Durst, H.D. Crown ether chemistry: principles and applications. Synthesis 168 (1975) 79-88.
- 3.Kafarski, P. and Lejczak, B. in: Chemia Bioorganiczna, (PWN, Ed.), Warszawa, 1994.
- 4.Lauger, P. Carrier-mediated ion transport. Science 178 (1972) 24-30.
- 5.Molisak-Tołwińska, H., Wencel, A. and Figaszewski, Z.A. Impedance of polypropylene membranes hydrophelized with ethyl alcohol. J. Mac. Sci., Pure Appl. Chem. 8 (1997) 1413-1427.
- 6.Naumowicz, M., Petelska, A.D. and Figaszewski, Z.A. Capacitance and resistance of the bilayer lipid membrane formed of phosphatidylcholine and cholesterol, Cell. Mol. Biol. Lett. 8 (2003) 5-18.
- 7.Benz, R., Frohlich, O., Lauger, O. and Montal, M. Electrical capacity of black films and of lipid bilayers made from monolayers. Biochim. Biophys. Acta. 374 (1975) 323-334.
- 8.Boukamp, B.A. in: Equivalent Circuit (Equivcrt. Pas), (University of Twente, Ed.), 1988.
- 9.Steinem, C., Janshoff, A., Ulrich, W.P., Sieber, M. and Galla H.J. Impedance analysis of supported lipid bilayer membranes: a scrunity of different preparation techniques. Biochim. Biophys. Acta. 1279 (1996) 169-180.
- 10.Scibona, G., Scuppa, B., Fabiani, C. and Pizzichini, M. Non-isothermal potential of phospholipid bilayer films. Influence of cholesterol and macrocyclic carrier effects. Biochim. Biophys. Acta. 512 (1978) 41-53.
- 11.Tosteson, D.C. Effect of macrocyclic compounds on the ionic permeability of artificial and natural membranes. Fed. Proc. 27 (1968) 1269-1277.
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Bibliografia
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