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2018 | 27 | 4 |
Tytuł artykułu

Using sodium trithiocarbonate to precipitate heavy metals from industrial wastewater – from the laboratory to industrial scale

Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This paper presents the possibility of using sodium trithiocarbonate to remove heavy metals such as copper, nickel, and tin from industrial wastewater generated by the production of printed circuit boards (PCBs). Initial metal removal studies aimed at selecting an effective precipitant and optimizing the precipitation process were conducted on an laboratory scale. The smallest concentrations of copper, nickel, and tin in treated wastewater (Cu 0.09 mg/L, Ni 0.009 mg/L, Sn <0.005 mg/L) were obtained after using a stoichiometric sodium trithiocarbonate dose at pH 9.0-9.5. Optimizing the metal removal process was possible by using the surface response method to obtain a good adjustment of the experimental data to the data obtained from the model (R² = 0.9307, R² adj. = 0.8845). The results of laboratory and model studies were used during industrial-scale testing in a wastewater treatment plant located in a PCB manufacturing plant. Optimization the wastewater treatment process on an industrial scale allowed us to obtain treated wastewater with very low copper (<0.005-0.014 mg/L), nickel (<0.005-0.008 mg/L), and tin (<0.005 mg/L) concentrations.
Słowa kluczowe
Wydawca
-
Rocznik
Tom
27
Numer
4
Opis fizyczny
p.1753-1763,fig.,ref.
Twórcy
autor
  • Chemiqua Company, Krakow, Poland
autor
  • Central Mining Institute, Department of Water Protection, Katowice, Poland
autor
  • Central Mining Institute, Department of Environmental Monitoring, Katowice, Poland
Bibliografia
  • 1. Srivastava N.K., Majumder C.B. Novel biofiltration methods for the treatment of heavy metals from industrial wastewater. Journal of Hazardous Materials, 151 (1), 1, 2008.
  • 2. Ochoa -Herrera V., Leon G., Banihani Q., Field J.A., Sierra -Alvarez R. Toxicity of copper(II) ions to microorganisms in biological wastewater treatment systems. Science of The Total Environment Volumes 412-413, 380, 2011.
  • 3. Stankovic V., Bozic D., Gorgievski M., Bogdanovic G. Heavy metal ions adsorption from mine waters by sawdust. Chemical Industry and Chemical Engineering Quarterly 15, 237, 2009.
  • 4. Sierra -Alvarez R., Hollingsworth J., Zhou M.S. Removal of copper in an integrated sulfate reducing bioreactor – crystallization reactor system. Environmental Science Technology 41, 1426, 2007.
  • 5. Thomas , M., Białecka , B., Zdebik , D. Sources of copper ions and selected methods of their removal from wastewater from the printed circuits board production, Inżynieria Ekologiczna 37, 31, 2014.
  • 6. Svecevičius G. Acute Toxicity of Nickel to Five Species of Freshwater Fish. Polish Journal of Environmental Studies 19, 2, 453, 2010.
  • 7. Brix K.V., Schlekat Ch.E., Garman E.R. The mechanisms of nickel toxicity in aquatic environments: An adverse outcome pathway analysis, Environmental Toxicology and Chemistry 36, 1128, 2017.
  • 8. Dermentzis K., Christoforidis A., Valsami-Dou E. Removal of nickel, copper, zinc and chromium from synthetic and industrial wastewater by electrocoagulation. International Journal of Environmental Sciences 5 (1), 697, 2011.
  • 9. Howe P., Watts P., Tin and Inorganic Tin Compounds. Concise International Chemical Assessment. Document 65, World Health Organization, Geneva, 1-81, 2005. http://www.who.int/ipcs/publications/cicad/cicad_65_web_version. pdf. 20.04.2017.
  • 10. Gunatilake S.K. Methods of Removing Heavy Metals from Industrial Wastewater, Journal of Multidisciplinary Engineering Science Studies 1(1), 12, 2015.
  • 11. Fu F., Wang Q. Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management 92, 407, 2011.
  • 12. Naim , R., Kisa y L., Park J., Qaisar M., Zulfiqar, A.B., Noshin M., Jamil K. Precipitation Chelation of Cyanide Complexes in Electroplating Industry Wastewater. International Journal of Environmental Research 4 (4), 735, 2010.
  • 13. Abu -El-Halawa R., Zabin S.A. Removal efficiency of Pb, Cd, Cu and Zn from polluted water using dithiocarbamate ligands. Journal of Taibah University for Science 11 (1), 57, 2017.
  • 14. Fu F., Zeng H., Cai Q., Qiu R., Yu J., Xiong Y. Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant, Chemosphere 69 (11), 1783, 2007.
  • 15. Andreottola G., Cadonna M., Foladori P., Gatti G., Lorenzi F., Nardelli P. Heavy metal removal from winery wastewater in the case of restrictive discharge regulation. Water Science & Technology 56 (2), 111, 2007.
  • 16. Pan S.W., Qiu K., Sun T.H., Zhang H., Jia J.P. Application of chelating agents for heavy metal removal from electroplating effluent Xiandai Huagong/Modern Chemical Industry 35, 61, 2015.
  • 17. Yang S., Chen Y. Synergistic effects of chelating precipitation and flocculation on removal of cadmium aminocomplex from wastewater, Fresenius Environmental Bulletin 20 (12), 3235, 2011.
  • 18. Kumar J., Bansal A. Photocatalytic degradation in annular reactor: Modelization and optimization using computational fluid dynamics (CFD) and response surface methodology (RSM). Journal of Environmental Chemical Engineering 1, 398, 2013.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
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