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2017 | 26 | 3 |
Tytuł artykułu

Comparative evaluation of environmental impact of selected ethoxylate fatty alcohols and ethoxylate fatty acid methyl esters as nonionic surfactants

Autorzy
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This work presents a comparative ecological assessment of dodecanolethoxylates and rapeseed acid methyl ester ethoxylates as nonionic surfactants. It was found that ethoxylated rapeseed acid methyl esters show higher biodegradability and lower aquatic toxicity compared to 1-dodecanol ethoxylates. A prognostic model for environmental impact of the studied series of surfactants was developed using the data from biodegradation and aquatic toxicity tests combined with estimated concentration of the surfactants in a wastewater stream. It is shown that an ecological risk of bulk application of dodecanolethoxylates can be expected over a longer term, while significant reduction of environmental fate would occur by the alternative use of ethoxylated rapeseed acid methyl esters. We concluded that ethoxylated rapeseed acid methyl esters can be considered as environmentally superior surfactants.
Słowa kluczowe
Wydawca
-
Rocznik
Tom
26
Numer
3
Opis fizyczny
p.1245-1250,fig.,ref.
Twórcy
autor
  • Institute of Heavy Organic Synthesis “Blachownia”, Energetykow 9, 47-225 Kędzierzyn-Kozle, Poland
autor
  • Institute of Heavy Organic Synthesis “Blachownia”, Energetykow 9, 47-225 Kędzierzyn-Koźle, Poland
Bibliografia
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  • 9. Alejski K., Emmons M., Lukosek M., Miesiąc I. Fatty acids methyl esters ethoxylation on heterogeneous catalyst. Experimental tests and process modeling, Inżynieria i Aparatura Chemiczna,3, 17, 2010 [In Polish].
  • 10. Zhang Q., Sun Y., Zhi L., Zhang Y., Di Serio M. Properties of ethoxylated castor oil acid methyl esters prepared by ethoxylation over an alkaline catalyst, Journal of Surfactants and Detergents, 18 (2) 365, 2015.
  • 11. Hreczuch W. Ethoxylated Rape Oil Acid Methyl Esters as New Ingredients for Detergent Formulations, Tenside Surf. Deterg. 38 (1), 72, 2001.
  • 12. Gauvrit C., Mueller T., Milius A., Trouve G. Ethoxylated rapeseed oil derivatives as non-ionic adjuvants for glyphosate, Pest Management Science, 63 (7) 707, 2007.
  • 13. Sułek M., Kulczycki A., Małysa A. Assessment of lubricity of compositions of fuel oil with biocomponents derived from rapeseed, Wear 268, 104, 2010.
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  • 16. Piotrowska J.B., Nachajski M.J., Lukosek M., Kosno J., Zgoda M.M. Surfactants from polyethoxylated fatty acids esters with glycerin group; Polimery w Medycynie 41 (1), 53, 2011 [In Polish].
  • 17. http://www.ihs.com/products/chemical/planning/world-petro-analysis/ethylene-oxide-glycol.aspx?pu=1&rd=chemihs; (09-2012).
  • 18. Blagojevic S.N., Blagojevic S.M., Pejic N.D. Performance and Efficiency of Anionic Dishwashing Liquids with Amphoteric and Nonionic Surfactants, Journal of Surfactants and Detergents, 19 (2) 363, 2016.
  • 19. OECD Guidelines for the Testing of Chemicals. No 202 Daphnia sp., Acute immobilisation Test and Reproduction Test, Part I – the 24 h EC 50 acute immobilisation test. Paris, 1, 1993.
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  • 22. Council Directive 82/242/EEC of 31 March 1982 on the approximation of the laws of the Member States relating to methods of testing the biodegrability of non-ionic surfactants and amending Directive 73/404/EEC.
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Typ dokumentu
Bibliografia
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