Single-walled carbon nanotubes fractionation via electrophoresis

• Autorzy: Blazej Scheibe , Pawel Lukaszczuk , Mark Rümmeli , Ryszard Kalenczuk , Ewa Borowiak-Palen
• Języki publikacji: EN

Abstrakty

EN

This work presents the influence of the sonication time on the efficiency of the metallic/semiconducting (M/S) fractionation of diazonium salt functionalized single-walled carbon nanotubes (SWCNTs) via free solution electrophoresis (FSE) method. The SWCNTs synthesized via laser ablation were purified from amorphous carbon and catalyst particles through high vacuum annealing and subsequent refluxing processes in aqua regia solutions, respectively. The purified material was divided into two batches. The SWCNTs samples were dispersed in 1% SDS solution in ultrasound bath for 2 and 12 hours. Both dispersed SWCNTs samples were functionalized with p-aminobenzoic acid diazonium salt and fractionated via free solution electrophoresis method. Afterwards, the fractionated samples were recovered, purified from surfactant/functionalities by annealing and investigated via UV-Vis-NIR optical absorption spectroscopy (OAS). The efficiency of the fractionation process was estimated through the comparison of the van Hove singularities (vHS) presented in the obtained fractions to the starting SWCNTs.

Słowa kluczowe

EN

SWCNTs; diazonium salts; fractionation; electrophoresis

• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2011
• Tom: 13
• Numer: 3
• Strony: 1-4

Daty

wydano

2011-01-01

online

2011-10-05

Twórcy

autor

Blazej Scheibe

• Institute of Chemical and Environmental Engineering, West Pomeranian University of Technology Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland

autor

Pawel Lukaszczuk

• Institute of Chemical and Environmental Engineering, West Pomeranian University of Technology Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland

autor

Mark Rümmeli

• Leibniz Institute for Solid State and Materials Research Dresden, Helmholtzstr. 20, 01069 Dresden, Germany

autor

Ryszard Kalenczuk

• Institute of Chemical and Environmental Engineering, West Pomeranian University of Technology Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland

autor

Ewa Borowiak-Palen

• Institute of Chemical and Environmental Engineering, West Pomeranian University of Technology Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland

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Identyfikatory

DOI

10.2478/v10026-011-0028-3