Emission of the odour substances from fertilizer industry

• Autorzy: Józef Hoffmann , Grażyna Gryglewicz , Krystyna Hoffmann , Stanisław Gryglewicz , Wiktor Okereke , Jakub Skut
• Języki publikacji: EN

Abstrakty

EN

Mineral fertilizers are indispensable for the intensification of plant production in agriculture. This process can cause a significant odour nuisance for the environment due to organic compounds content in apatites and phosphorites converted into fertilizers. The following chemical compounds are emitted to the gas phase among others: hydrogen sulphide, organic sulphides and (methyl, ethyl, isopropyl, butyl) disulphides, chain hydrocarbons, organic oils, waxes and carboxylic acids. A method using gas chromatography analysis with the mass detector (TD-GS-MS), to determine trace concentrations, was developed and tested for the assessment of odour nuisant substances emission from these processes. Application of additional thermal desorber to enable the intense desorption of the investigated organic compounds (previously adsorbed on classical sorbents) in the industrial research has been taken into consideration. In effect it facilitates the accumulating substances to be analyzed at short time interval providing identifying measurements. The technique has been verified during the investigation of the substances emitted in fertilizers processes at Maroko phosphorite decomposition. The organic sulfur compounds, aliphatic and aromatic hydrocarbons have been detected.

Słowa kluczowe

EN

odours; mineral fertilizers

• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2009
• Tom: 11
• Numer: 1
• Strony: 12-15

Daty

wydano

2009-01-01

online

2009-04-06

Twórcy

autor

Józef Hoffmann

• Faculty of Chemistry, Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University o Technology, ul. Smoluchowskiego 25, 50-370 Wrocław, Poland

autor

Grażyna Gryglewicz

• Faculty of Chemistry, Division of Polymer and Carbonaceous Materials, Wroclaw University o Technology, ul. Gdańska 7/9, 50-344 Wrocław, Poland

autor

Krystyna Hoffmann

• Faculty of Chemistry, Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University o Technology, ul. Smoluchowskiego 25, 50-370 Wrocław, Poland

autor

Stanisław Gryglewicz

• Faculty of Chemistry, Division of Polymer and Carbonaceous Materials, Wroclaw University o Technology, ul. Gdańska 7/9, 50-344 Wrocław, Poland

autor

Wiktor Okereke

• Faculty of Chemistry, Division of Polymer and Carbonaceous Materials, Wroclaw University o Technology, ul. Gdańska 7/9, 50-344 Wrocław, Poland

autor

Jakub Skut

• Faculty of Chemistry, Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University o Technology, ul. Smoluchowskiego 25, 50-370 Wrocław, Poland

Bibliografia

• Slack, A.V. (1968). Phosphoric acid, Marcel Dekker Inc., New York.
• Impurities in Phosphate Rock (1990). Fert. Int. 283, 27 - 31.
• Mair, A.D. (1985). Organic mater and sulfur distribution in phosphorites, National Fertilizer Development Center, Muscle Shoals.
• Kośmider, J., Mazur Chrzanowska, B. & Wyszyński, B. (2002). Odours, Wyd. Nauk. PWN, Warszawa. (in Polish)
• Becker, P. (1989). Phosphates and phosphoric acid, Marcel Dekker Inc., New York.
• Hanna, A.A. & Ali A.F. (1992). Removal of organic matter from crude wet-process phosphoric acid, J.Chem. Tech. Biotechnol. 55, 205 - 208.
• Mellah, A., Silem, A., Bonalia, A. & Koda, R. (1992). Adsorption of organic matter from a wet phosphoric acid using activated carbon: Equilibrium study, Chem.Eng.Proc. 3, 191 - 194.
• Ministry of Environmental Decree from 5 December 2002 in matter of value of references for some substances in air (2003). Dz. U., 2003, 1, 12. (in Polish)
• The Protection of Environment Law from 27 April 2001 (2006). Dz. U. 2006, 129, 902. (in Polish)
• Lowrison, G.Ch. (1989). Fertilizer Technology, Ellis Horwood Limited, Chichester.

Identyfikatory

DOI

10.2478/v10026-009-0004-3