Geochemical investigation of alluvial sediments: validation of ICP-OES determination of heavy metals. A case study from the Utrata River Valley (central Poland)

• Autorzy: Miša Biro , Darja Kavšek , Jakub Karasiński , Piotr Szwarczewski , Ewa Bulska , Darinka Vončina
• Języki publikacji: EN

Abstrakty

EN

The development and validation of a reliable analytical procedure for the determination of selected metals (Cd, Cr, Cu, Pb, Zn and Mn) in sediments accumulated in the Utrata River (Poland) is described. The aqua regia extraction followed by inductively coupled plasma optical emission spectrometry (ICP-OES) was used for this purpose. The optimized analytical procedure was validated, and adequate quality control actions were implemented in order to provide reliable data. The precision under’ within-laboratory’ reproducibility conditions was estimated from duplicate analysis. Certified reference material (CRM) was used in order to evaluate the accuracy of the results regarding the sewage sludge amended soil CRM 143R. The detection limits for all elements of interest were well-below their content in the investigated sediment samples. The obtained reliable data could be used for assessment of the relationship between human economic activity in the past and the geochemical features of the sediments.

Słowa kluczowe

EN

Sediment; Heavy metals; ICP-OES; Method validation; Geochemical profile

• Czasopismo: Open Chemistry
• Rocznik: 2014
• Tom: 12
• Numer: 6
• Strony: 687-699

Daty

wydano

2014-06-01

online

2014-03-13

Twórcy

autor

Miša Biro

• CIVIS d.o.o.,

autor

Darja Kavšek

• Chemical-Technological Laboratory

autor

Jakub Karasiński

• Biological and Chemical Research Center

autor

Piotr Szwarczewski

• University of Warsaw

autor

Ewa Bulska

• Biological and Chemical Research Center

autor

Darinka Vončina

• University of Maribor

Bibliografia

• [1] N.C. Brady, R.R. Weil, The nature and properties of soils, 13th edition (Prentice Hall, Upper Saddle River, New Jersey, 1999)
• [2] R. Baudo, J.P. Giesy, H. Muntau, Sediments: Chemistry and Toxicity of in-place pollutants (Lewis Publishers Inc., Boca Raton, Florida, 1990)
• [3] D. Ciszewski, I. Malik, P. Szwarczewski, Pol. J. Environ. Stud. 6, 597 (2004)
• [4] K Ljung, E. Otabbong, O. Selinus, Environ. Geochem. Hlth. 28, 353 (2006) http://dx.doi.org/10.1007/s10653-005-9031-z[Crossref]
• [5] K.A. Smith, M.S. Cresser, Soil & Environmental Analysis - Modern Instrumental Techniques, 3rd edition (Marcel Dekker, Inc., New York and Basel, 2004)
• [6] J. Sastre, A. Sahuquillo, M. Vidal, G. Rauret, Anal. Chim. Acta 462, 59 (2002) http://dx.doi.org/10.1016/S0003-2670(02)00307-0[Crossref]
• [7] M.P. Carril, M.S. Corbillón, J.M. Madariaga, Accredit. Qual. Assur. 2, 301 (1997) http://dx.doi.org/10.1007/s007690050152[Crossref]
• [8] M.A. Trancoso, M.M. Correia dos Santos, M.L. Simões Gonçalves, Accredit. Qual. Assur. 8, 323 (2003) http://dx.doi.org/10.1007/s00769-003-0608-x[Crossref]
• [9] S. Alves, M.M. Correia dos Santos, M Ascensão Trancoso, Accredit. Qual. Assur. 14, 87 (2009) http://dx.doi.org/10.1007/s00769-008-0484-5[Crossref]
• [10] R.J.N. Bettencourt da Silva, M.F.G.F.C. Camões, J. Seabra e Barros, Accredit. Qual. Assur. 3, 155 (1998) http://dx.doi.org/10.1007/s007690050210[Crossref]
• [11] A. Kučak, M. Blanuša, Accredit. Qual. Assur. 2, 51 (1998)
• [12] M. Chudzinska, A. Debska, D. Baralkiewich, Accredit. Qual. Assur. 17, 65 (2012) http://dx.doi.org/10.1007/s00769-011-0812-z[Crossref]
• [13] H. Górecka, K. Chojnacka, H. Górecki, Talanta 70, 950 (2006) http://dx.doi.org/10.1016/j.talanta.2006.05.061[Crossref]
• [14] E.S. Chaves, E. José dos Santos, R.G.O. Araujo, J.V. Oliveira, V.L.A. Frescura, A.J. Curtius, Microchem. J. 96, 71 (2010) http://dx.doi.org/10.1016/j.microc.2010.01.021[Crossref]
• [15] M.S. Bispo et. al., Spectrochim Acta B 57, 2175 (2002) http://dx.doi.org/10.1016/S0584-8547(02)00179-9[Crossref]
• [16] H. Gramowska, I. Krzyzaniak, D. Baralkiewich, R. Goldyn, Environ. Monit. Assess. 160, 479 (2010) http://dx.doi.org/10.1007/s10661-008-0712-9[Crossref]
• [17] G.A. Kumar, H.S. Sahoo, S.K. Satpathy, G. Swarnabala, Accredit. Qual. Assur. 8, 21 (2003) http://dx.doi.org/10.1007/s00769-002-0549-9[Crossref]
• [18] T. Drglin, Accredit. Qual. Assur. 8, 130 (2003) http://dx.doi.org/10.1007/s00769-003-0583-2[Crossref]
• [19] WinLab32TM for ICP Software, The OptimaTM software (Perkin Elmer, USA)
• [20] ISO 11466:1995, Soil quality - Extraction of Trace Elements Soluble in Aqua Regia
• [21] D. Florian, R.M. Barnes, G. Knapp, Fresenius J. Anal. Chem. 362, 558 (1998) http://dx.doi.org/10.1007/s002160051124[Crossref]
• [22] SIST EN ISO/IEC 17025:2005/AC:2007, General requirements for the competence of testing and calibration laboratories (ISO/IEC 17025:2005/Cor.1:2006)
• [23] M.H. Feinberg, A. Gerbanowski, D.N. Rutledge, Accredit. Qual. Assur. 2, 69 (1997) http://dx.doi.org/10.1007/s007690050101[Crossref]
• [24] I. Kuselman, A. Shenhar, Accredit. Qual. Assur. 2, 180 (1997) http://dx.doi.org/10.1007/s007690050127[Crossref]
• [25] J. Nölte, ICP Emission spectrometry - A practical Guide (Wiley-VCH, Weinheim, Germany, 2003)
• [26] J.N. Miller, J.C. Miller, Statistics and chemometrics for analytical chemistry (Pearson Education Limited, England, 2005)
• [27] C.B. Boss, K.J. Fredeen, Concepts, instrumentation, and techniques in inductively coupled plasma optical emission spectrometry (Perkin Elmer, USA, 1997)
• [28] J.V. Loco, M. Elskens, C. Croux, H. Beernaert, Accredit. Qual. Assur. 7, 281 (2002) http://dx.doi.org/10.1007/s00769-002-0487-6[Crossref]
• [29] L. Brüggemann, R. Wennrich, Accredit. Qual. Assur. 7, 269 (2002) http://dx.doi.org/10.1007/s00769-002-0485-8[Crossref]
• [30] W. Funk, V. Dammann, G. Donnevert, Quality Assurance in Analytical Chemistry (Wiley-VCH, Weinheim, Germany 2007)
• [31] The fitness for Purpose of Analytical Methods: a Laboratory Guide to Method Validation and Related Topics (Eurachem, Middlesex, 1998)
• [32] J. Zupan, Kemometrija in obdelava eksperimentalnih podatkov (Kemijski inštitut: Inštitut Nove revije, zavod za humanistiko, Ljubljana, Slovenia, 2009) (in Slovene)
• [33] J. Fleming, H. Albus, B. Neidhart, W. Wegscheider, Accredit. Qual. Assur. 2, 51 (1997) http://dx.doi.org/10.1007/s007690050097[Crossref]
• [34] I. Kuselman, F. Sherman, Accredit. Qual. Assur. 4, 124 (1999) http://dx.doi.org/10.1007/s007690050331[Crossref]
• [35] P.C. Meier, R.E. Zünd, Statistical Methods in Analytical Chemistry, 2nd Edition (John Wiley & Sons, Canada, 2007)

Identyfikatory

DOI

10.2478/s11532-014-0520-8