Czasopismo
Tytuł artykułu
Warianty tytułu
Języki publikacji
Abstrakty
A model of electrode reaction complicated by slow adsorption of the reactant is developed for square-wave voltammetry with inverse scan direction. The relationship between the dimensionless net peak current and the logarithm of dimensionless rate constant of adsorption is a curve with a minimum and a maximum. For this reason the ratio of real net peak current and the square-root of frequency is a non-linear function of the logarithm of frequency and exhibits either a maximum or a minimum. The frequency of extreme serves for the estimation of the rate constant: log(k ads /D 1/2 ) = log(k*ads )crit + 0.5 log f crit , where (k*ads )crit is a critical dimensionless rate constant of adsorption. Square-wave voltammetry is sensitive to the kinetics of adsorption if k ads 2 cm s−1 [...]
Słowa kluczowe
Czasopismo
Rocznik
Tom
Numer
Strony
513-518
Opis fizyczny
Daty
wydano
2010-06-01
online
2010-04-25
Twórcy
autor
- Department of Marine and Environmental Research, “Rudjer Bošković” Institute, P.O. Box 180, HR-10002, Zagreb, Hrvatska (Croatia), mlovric@irb.hr
autor
- Department of Marine and Environmental Research, “Rudjer Bošković” Institute, P.O. Box 180, HR-10002, Zagreb, Hrvatska (Croatia)
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0034-y