Czasopismo
Tytuł artykułu
Autorzy
Warianty tytułu
Języki publikacji
Abstrakty
A simple analytical method for the determination of p-nitrobenzene-azo-naphthol was proposed by a sequential perturbation with different amounts of p-nitrobenzene-azo-naphthol on an oscillating chemical system. The method involves a Cu(II)-catalysed oscillating reaction between hydrogen peroxide and sodium thiocyanate in alkaline medium with the aid of continuous-flow stirred tank reactor (CSTR). A good linear relationship between the changes, oscillation amplitude or/and period, and the concentration of p-nitrobenzene-azo-naphthol was obtained. The use of analyte pulse perturbation technique provides a possibility of sequential determination in a same oscillating system, due to a new steady state that reappeared rapidly after each perturbation. The calibration curve fits a linear equation very well when the concentration of p-nitrobenzene-azo-naphthol ranging from 5.2×10−7 to 3.3×10−3M. Influence of temperature, injection point, flow rate and reactants variables on this system were investigated in detail.
Czasopismo
Rocznik
Tom
Numer
Strony
502-510
Opis fizyczny
Daty
wydano
2005-09-01
online
2005-09-01
Twórcy
autor
- Department of Chemistry, Northwest Normal University, 730070, Lanzhou, P.R. China, jzgao@nwnu.edu.cn
autor
- Department of Chemistry, Northwest Normal University, 730070, Lanzhou, P.R. China
autor
- Department of Chemistry, Northwest Normal University, 730070, Lanzhou, P.R. China
autor
- Department of Chemistry, Northwest Normal University, 730070, Lanzhou, P.R. China
Bibliografia
- [1] L.P. Tikhonova, L.N. Zakrevskaya and K.B. Yasimirskii: “Catalytic dtermination of ruthenium based on an oscillating chemical reaction”, J. Anal. Chem. USSR, Vol. 33, (1978), pp. 1991–1998.
- [2] R. Jimenez-Prieto, M. Silva and D. Perez-Bendito: “Approaching the use of oscillating reactions for analytical monitoring”, Analyst, Vol. 123, (1998), pp. 1R-8R. http://dx.doi.org/10.1039/a703354k[Crossref]
- [3] A.F. Taylor: “Mechanism and phenomenology of an oscillating chemical reaction”, Prog. React. Kinet. Mec., Vol. 27(4), (2002), pp. 247–325. [Crossref]
- [4] J.Z. Gao: “Application of oscillating chemical reaction to analytical chemistry: Recent Developments”, Pak. J. Biol. Sci., Vol. 8(5), (2005), (im press).
- [5] J.Z. Gao, J. Ren, W. Yang, X.H. Liu and H. Yang: “Determination of caffeine using oscillation chemical reaction in a CSTR”, J. Pharmaceut Biomed., Vol. 32, (2003), pp. 393–400. http://dx.doi.org/10.1016/S0731-7085(03)00241-3[Crossref]
- [6] J.Z. Gao, H. Yang, X.H. Liu, J. Ren, Q.Z. Li and J.W. Kang: “Determination of glutamic acid by an oscillating chemical reaction using the analyte pulse perturbation technique”, Talanta, Vol. 57, (2002), pp. 105–114. http://dx.doi.org/10.1016/S0039-9140(02)00009-7[Crossref]
- [7] J.Z. Gao, H. Yang, X.H. Liu, J. Ren, X.Q. Lu, J.G. Hou and J.W. Kang: “Kinetic determination of ascorbic acid by the BZ oscillating chemical system”, Talanta, Vol. 55, (2001), pp. 99–107. http://dx.doi.org/10.1016/S0039-9140(01)00403-9[Crossref]
- [8] J.Z. Gao, J. Ren, W. Yang, X.H. Liu, H. Yang, Q.Z. Li and H.L. Deng: “Kinetic determination of hydroquinone by Belousov-Zhabotinsky oscillating chemical reaction”, J. Electroanal. Chem, Vol. 520, (2002), pp. 157–162. http://dx.doi.org/10.1016/S0022-0728(01)00751-3[Crossref]
- [9] N.Q. Gan, C.J. An, Y. Liu and R.X. Cai: “Determination of hexacyanoferrates based on the diacetone −BrO 3−−Mn(II)−H2SO4 chemical oscillatory reaction”, Analyst, Vol. 123, (1998), pp. 2395–2397. http://dx.doi.org/10.1039/a805107k
- [10] R. Jimenez-Prieto, M. Silva and D. Perez-Bendito: “Simultaneous determination of gallic acid and resorcinol based on oscillating chemical reaction by the analyte pulse pertuebation technique”, Anal. Chim. Acta, Vol. 334, (1996), pp. 323–330. http://dx.doi.org/10.1016/S0003-2670(96)00346-7[Crossref]
- [11] R. Jimenez-Prieto, M. Silva and D. Perez-Bendito: “Determination of gallic acid by an oscillating chemical reaction using the analyte pulse pertuebation technique”, Anal. Chim. Acta, Vol. 321, (1996), pp. 53–60. http://dx.doi.org/10.1016/0003-2670(95)00563-3[Crossref]
- [12] R. Jimenez-Prieto, M. Silva and D. Perez-Bendito: “Application of oscillating reaction based on the determination of real samples”, Analyst, Vol. 122, (1997), pp. 287–292. http://dx.doi.org/10.1039/a606506f[Crossref]
- [13] R. Jimenez-Prieto, M. Silva and D. Perez-Bendito: “Analytical assessment of the oscillating chemical reaction by use chemiluminescence detection”, Talanta, Vol. 44, (1997), pp. 1463–1472. http://dx.doi.org/10.1016/S0039-9140(97)00047-7[Crossref]
- [14] J. Wang, S.T. Yang, R.X. Cai, Z.X. Lin and Z.H. Liu: “A new method for determination of uric acid by the lactic acid-acetone-BrO 3−−Mn2+−H2SO4 oscillating reaction. Talanta, Vol. 65, (2005), pp. 799–805 http://dx.doi.org/10.1016/j.talanta.2004.08.008[Crossref]
- [15] M. Orban: “Oscillations and bistability in the Cu(II)-catalyzed reaction between H2O2 and KSCN”, J. Am. Chem. Soc., Vol. 108, (1986), pp. 6893–6898. http://dx.doi.org/10.1021/ja00282a009[Crossref]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_BF02479278