Development and validation of the simple and sensitive spectrophotometric method of sulphanilamides determination with 4-(2-thiazolylazo)-resorcinol in veterinary preparations

• Autorzy: Maria Smolinska , Olha Korkuna , Teodoziya Vrublevska , Petro Rudchuk , Grigory Teslyar
• Języki publikacji: EN

Abstrakty

EN

New simple, rapid, and accurate spectrophotometric techniques for sulphanilamides assay in combination drugs have been elaborated. The method is based on the formation of coloured products of sulphanilamides diazonium salt azoсoupling with heterocyclic azo reagent 4-(2-thiazolylazo)-resorcinol (TAR) in alkaline medium (pH 9.5) with the following measurement of their absorbance at λmax = 615 nm. Formed products are stable for 1 hour at room temperature. Effective molar absorptivities at absorbance maximum 615 nm for disazo dyes were ~ 104 M-1 cm-1. Linear ranges for sulphanilamides determination were 0.5−30.0 μg mL-1. The developed method was used for the suphanilamides determination in tablets, powder, solutions, suspensions and ointments.

EN

Słowa kluczowe

EN

Sulphanilamides; 4-(2-thiazolylazo)-resorcinol; Spectrophotometry; Diazotization; Azocoupling; Medicines

• Czasopismo: Open Chemistry
• Rocznik: 2015
• Tom: 13
• Numer: 1

Daty

otrzymano

2014-09-22

zaakceptowano

2015-04-02

online

2015-10-21

Twórcy

autor

Maria Smolinska

• Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine
• State Scientific Research Control Institute of Veterinary Preparations and Fodder Additives, Donetska Str.,11, 79019, Lviv, Ukraine

autor

Olha Korkuna

• Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine

autor

Teodoziya Vrublevska

• Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine

autor

Petro Rudchuk

• Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine

autor

Grigory Teslyar

• State Scientific Research Control Institute of Veterinary Preparations and Fodder Additives, Donetska Str.,11, 79019, Lviv, Ukraine

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Identyfikatory

DOI

10.1515/chem-2015-0139