Liquid chromatographic determination of glyphosate and aminomethylphosphonic acid residues in rapeseed with MS/MS detection or derivatization/fluorescence detection

• Autorzy: Piotr Kaczyński , Bożena Łozowicka
• Języki publikacji: EN

Abstrakty

EN

Glyphosate and AMPA determinations in rapeseed extracts by (a) liquid chromatography with triple quadrupole MS detection (LC-MS/MS), or (b) liquid chromatography with post-column OPA derivatization and fluorescence detection (LC-FLD) were developed. Mean recoveries for glyphosate and AMPA were (a) 88.8–95.0% and 82.1–86.1%, and (b) 70.8–74.1% and 62.4–72.6%. RSD were below (a) 11% and (b) 22%. Correlation coefficients were above 0.997 for both methods. LOD were 0.01 mg kg-1 for (a) and 0.05 mg kg-1 for (b). Both methods are simple and efficient for routine analysis of glyphosate and AMPA in a fatty matrix.

EN

Słowa kluczowe

EN

glyphosate; AMPA; rapeseed; liquid chromatography; mass spectrometry

• Czasopismo: Open Chemistry
• Rocznik: 2015
• Tom: 13
• Numer: 1

Daty

otrzymano

2014-12-08

zaakceptowano

2015-04-01

online

2015-06-22

Twórcy

autor

Piotr Kaczyński

• Institute of Plant Protection – National Research Institute, Chełmońskiego 22, 15-195 Bialystok, Poland

autor

Bożena Łozowicka

• Institute of Plant Protection – National Research Institute, Chełmońskiego 22, 15-195 Bialystok, Poland

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Identyfikatory

DOI

10.1515/chem-2015-0107