Czasopismo
Tytuł artykułu
Warianty tytułu
Języki publikacji
Abstrakty
In this work, several materials were studied as electrodes in a pinhole configuration of a DC plasma discharge to estimate their effect on the efficiency of the discharge, indicated by hydrogen peroxide production. Detection was carried out using a specific titanium reagent. This was combined with ICP-OES analysis of the final solutions to determine the difference between the amount of electrode material released during the discharge operation and electrolysis experiment carried out under the same conditions. It was found that from seven studied electrode materials, graphite gives the best results, while lower cost aluminum and titanium-zinc still work well. The most unsuitable materials were copper and brass; in these cases, no hydrogen peroxide was detected in the cathode part of the reactor. Results obtained by ICP analysis indicate that even in the case of brass, the absence of hydrogen peroxide is due to the presence of copper in the material. It probably affects both directly the phase of discharge creation and propagation and the decomposition reactions.
Czasopismo
Rocznik
Tom
Numer
Opis fizyczny
Daty
otrzymano
2013-12-20
zaakceptowano
2014-05-13
online
2014-11-18
Twórcy
autor
- Faculty of Chemistry, Brno University of Technology, 612 00 Brno, Czech Republic
autor
- Faculty of Chemistry, Brno University of Technology, 612 00 Brno, Czech Republic
autor
- Faculty of Chemistry, Brno University of Technology, 612 00 Brno, Czech Republic
autor
- Masaryk University, CEITEC - Central European Institute of Technology, 625 00 Brno, Czech Republic
Bibliografia
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- [5] Kim S., Sergiienko R., Shibata E., Hayasaka Y., Nakamura T., Mater. Trans., 2010, 51, 8
- [6] Stara Z., Krcma F., Slavicek P., Aubrecht V., In: Schmidt J.,Šimek M., Pekárek S., Prukner V., (Eds.), 28th International Conference on Phenomena in Ionized Gases, July 15 – 20 2007, Prague, Czech Republic, Ústav fyziky plazmatu AV ČR, Prague, Czech Republic, 2007, 1082-1085
- [7] Halamova I., Nikiforov A., Krcma F., Leys Ch., J. Phys.: Conf. Ser., 2014, 516
- [8] Lukes P., PhD thesis, Institute of Plasma Physics, AS CR, Prague, CZ, 2001
- [9] Stara Z., Davidova J., Olexova B., Krcma F., Soural I., In: IEEE 35th International Conference on Plasma Science, 15-19 June 2008, Karlsruhe, Germany, IEEE Service Center, Piscataway, NJ, USA, 2008, 193
- [10] Bruggeman P., Leys Ch., J. Phys. D: Appl. Phys., 2009, 42, 5,DOI: 10.1088/0022-3727/42/5/053001[Crossref]
- [11] Stara Z., PhD thesis, Brno University of Technology, Brno, CZ, 2006
- [12] Kozakova Z., Habilitation thesis, Brno University of Technology Brno, CZ, 2011
- [13] Krcma F., et al., J. Phys.: Conf. Ser., 2010, 207, 1, DOI: 10.1088/1742-6596/207/1/012010[Crossref]
- [14] Halliwell B., Gutteridge J.M.C., Biochem. J., 1984, 219
- [15] Hall S.B., Khudaish E.A., Hart A.L., Electrochimica Acta, 1998, 32, 5
- [16] Nikiforov A.Yu., Leys Ch., Plasma Sources Sci. Technol., 2007, 16
- [17] Lee B.-H., Kim D.-S., Choi J.-H., J. Electric. Eng. & Technol., 2010, 5, 2
- [18] De Baerdemaeker F., Šimek M., Leys Ch., Vestraete W., Plasma Chem. Plasma Process, 2007, 27
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_1515_chem-2015-0054