Synthesis of bio-active titanium oxide coatings stimulated by electron-beam plasma

• Autorzy: Tatiana Vasilieva , Igor Sokolov , Andrey Sigarev , Aung Tun Win
• Języki publikacji: EN

Abstrakty

EN

Advantages of the electron-beam plasma (EBP) for production of bioactive titanium oxide coatings were experimentally studied. The coatings were synthesized in EBP of oxygen on the surface of plane titanium substrates. A number of analytical techniques were used to characterize morphology, chemical composition, and structure of the synthesized titanium oxide. The analysis showed the titanium oxide (IV) in the rutile form to predominate in the coatings composition. The samples with plasmachemically synthesized TiO2-coatings were more hydrophilic than untreated titanium. The effect was stable during two weeks and then the degradation of the wettability began. The EBP-stimulated TiO2 synthesis improved the hydroxyapatite formation on the surface of plane titanium substrates. The EBP-stimulated TiO2 synthesis is promising technique to produce bioactive coatings on the surface of titanium medical dental and bone implants. The computer simulation of plasma-surface interaction was carried out to predict the plasma composition, to find the spatial distribution of the sample temperature, and to calculate the flows of the chemically active plasma particles bombarding the tube wall. The flows of atomic and singlet oxygen were found to be the most intensive and, therefore, these particles are likely to be responsible for the formation of the biocompatible TiO2-coaings.

Słowa kluczowe

EN

Titanium oxide (IV); rutile; hydroxyapatite; oxygen species; computer simulation

• Czasopismo: Open Chemistry
• Rocznik: 2015
• Tom: 13
• Numer: 1

Daty

otrzymano

2013-12-29

zaakceptowano

2014-03-17

online

2014-11-17

Twórcy

autor

Tatiana Vasilieva

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia,

autor

Igor Sokolov

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

autor

Andrey Sigarev

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

autor

Aung Tun Win

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

Bibliografia

• [1] Park J.B., Lakes R.S., Biomaterials an Introduction, Plenum Press, New York, 1992
• [2] Lin F.H., Hsu Y.S., Lin S.H., Chen T.M., Mater. Chem. Phys., 2004, 87, 24[Crossref]
• [3] Massaro C., Rotolo P., De Riccardis F., Milella E., Napoli A., Wieland M., et al., J. Mater. Sci. Mater. Med., 2002, 13, 535[Crossref]
• [4] Kim H.W., Kim H.E., Salih V., Knowles J.C., J. Biomed. Mater. Res. B Appl. Biomater., 2004, 72B, 1
• [5] Park J.B., Kim Y.S., Lee G., Yun B.G., Kim C.H., J. Tissue. Eng. Regen. Med., 2013, 10, 115[Crossref]
• [6] Dudek A., Arch. Metall. Mater., 2011, 56, 135
• [7] Boyd A.R., Burke G.A., Duffy H., Holmberg M., O’Kane C., Meenan B.J., Kingshott P., J. Mater. Sci. Mater. Med., 2011, 22, 71[Crossref]
• [8] Shtansky D.V., Kiryukhantsev-Korneev P.V., Bashkova I.A., Sheveiko A.N., Levashov E.A., Int. J. Refract. Met. Hard Mater., 2010, 28, 32[Crossref]
• [9] Katayama H., Katto M., Nakayama T., Surf. Coat.Technol., 2009, 204, 135
• [10] Roy M., Balla V.K., Bandyopadhyay A., Bose S., Acta Biomater., 2011, 7, 866[Crossref]
• [11] Rautray T.R., Narayanan R., Kwon T.Y., Kim K.H., Thin Solid Films, 2010, 518, 3160
• [12] Sobieszczyk S., Zieliński A., Adv. Mater. Sci., 2008, 8, 35
• [13] Yoshinari M., Watanabe Y., Ohtsuka Y., Derand T., J. Dent. Res., 1997, 76, 1485[Crossref]
• [14] Bai X., More K., Rouleau C.M., Rabiei A., Acta Biomater., 2010, 6, 2264[Crossref]
• [15] Vasiliev M.N., In: Fortov V.E. (Ed.), Encyclopedia of low-temperature plasma, Nauka, Moscow, 2001, V IX 436 [WoS]
• [16] Greenler R.G., J. Chem. Phys., 1969, 50, 1963
• [17] Transferetti B.C., Davanzo C.U., Zoppi R.A., Cruz N.C., Moraes M.A.B., Phys. Rev. B., 2001, 64, 125404[Crossref]
• [18] Zhang J.Y., Boyd I.W., O`Sullivan B.J., Hurly P.K., Kelly P.V., Senateur J.P., J. Non-Sryst. Solids, 2002, 303, 134
• [19] Bellamy L.J., The infrared spectra of complex molecules, Methuen & Co., London, 1954
• [20] Van der Houwen J.A.M., Cressey G., Cressy B.A., Valsami-Jones E., J. Cryst. Growth, 2003, 96, 249
• [21] Rapacz-Kmita A., Elosarczyk A., Paszkiewicz Z.C., Paluszkiewicz C., J. Mol. Struct., 2004, 65, 704
• [22] Berzina-Cimdina L., Borodajenko N., In: T. Theophanides (Ed.), Infrared spectroscopy – Materials science, engineering and technology, 2012, 123
• [23] Sato K., Kumagai Y., Tanaka J., J. Biomed. Mater. Res., 2000, 50, 16[Crossref]
• [24] Kokubo T., Ito S., Huang Z.T., Hatashi T., Sakka S., Kitsugi T., Yamamuro T., J. Biomed. Mater. Res., 1990, 24, 331[Crossref]
• [25] Vasilieva T.M., IEEE Transac. Plasma Sci., 2010, 38, 1903[Crossref]
• [26] Vasilieva T.M., Bayandina D.V., Instr. Exp. Tech., 2010, 53, 289
• [27] Thull R., Grant D., In: Brunette D.M. (Ed.), Titanium in Medicine: Material Science, Surface Science, Engineering, Biological Responses and Medical Applications, Springer-Verlag, Berlin and Heidelberg, 2001, 283
• [28] Handbook of Deposition Technologies for Film and Coatings, 2nd edition, Noyes, Park Ridge, NJ, 1994
• [29] Yuan Y., Lee T.R., In: Bracco G., Holst B. (Eds.), Surface Science Techniques, Springer-Verlag, Berlin and Heidelberg, 2013, 3
• [30] Aleksandrov N.L., Vasiliev M.N., Lysenko S.L., Negodaev S.S., In: 4-th European Conference for Aerospace Sciences, 4-8 July 2011, S-Petersburg, Russia
• [31] Aleksandrov N.L., Konovalov V.P., Son E.E., In: Son E.E. (Ed.), Encyclopedia of low-temperature plasma, Yanus-K, Moscow, 2010, Ser. B. V III-3, 265
• [32] Aleksandrov N.L., Vasiliev M.N., Lysenko S.L., Mahir A.Kh., Plasma Physics Reports, 2005, 31, 425[WoS]
• [33] Kutasi K., Sa P.A., Guerra V., J. Phys. D: Appl. Phys., 2012, 45, 19205

Identyfikatory

DOI

10.1515/chem-2015-0015