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2 Polish Journal of Chemistry

2 2001

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Synthesis, Crystal Structure and Magnetism of Vanadium(IV/V) Complex: K3[V2O3(nta)2]ź3H2O

Shi J. M., Xu J. Q., Yu W. T., Liu L. D., Wu C. J.

Polish Journal of Chemistry

2001

Vol. 75, nr 11

1695-1701

The crystal of the titled vanadium(IV/V) complex K3[V2O3(nta)2]ź3H2O (nta denotes nitrilotriacetate) has been synthesized and its structure determined. The unit cell contains two different binuclear vanadium(IV/V) groups. The vanadium(IV/V) ions are coordinated by six atoms and each vanadium(IV/V) ion is located in the sphere of distorted octahedral coordination. In each dimer two vanadium ions are in exact equivalent sites and one free electron is shared equally between the two vanadium ions.

Synthesis and Crystal Structure of Copper(II) Complex with Bis(2-aminoethyl)sulfide and Thiocyanate as Ligands

Shi J., Xu W., Yin H. L., Liu L. D., Wu C. J., Hu M. Y.

Polish Journal of Chemistry

2001

Vol. 75, nr 7

1063-1066