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EN
The essence of ablation casting technology consists in pouring castings into single-use moulds made from the mixture of sand and a water-soluble binder. After pouring the mould with liquid metal yet while the casting is still solidifying, the mould destruction (washing out, erosion) takes place using a stream of cooling medium, which in this case is water. This paper focuses on the selection of moulding sands with hydrated sodium silicate for moulds used in ablation casting. The research is based on the use of water glass 145 and 150 as binders. As part of the research, loose moulding mixtures based on two silica sands from different sand mines with different content of binders were prepared. The review of literature data and the results of own studies have shown that moulding sand with hydrated sodium silicate hardened by dehydration is characterized by sufficient strength properties to be used in the ablation casting process. Our own research also confirmed the possibility of using these sand mixtures in terms of both casting surface quality and sand reclamation. The results presented in this paper prove that both sand grains and types of binder tested may be used as components in moulding sands devoted to ablation casting.
EN
Ablation casting is a technological process in which the increased cooling rate causes microstructure refinement, resulting in improved mechanical properties of the final product. This technology is particularly suitable for the manufacture of castings with intricate shapes and thin walls. Currently, the ablation casting process is not used in the Polish industry. This article presents the results of strength tests carried out on moulding sands based on hydrated sodium silicate hardened in the Floster S technology, intended for ablation casting of the AlSi7Mg (AK7) aluminium alloy. When testing the bending and tensile strengths of sands, parameters such as binder and hardener content were taken into account. The sand mixtures were tested after 24h hardening at room temperature. The next stage of the study describes the course of the ablation casting process, starting with the manufacture of foundry mould from the selected moulding mixture and ending in tests carried out on the ready casting to check the surface quality, structure and mechanical properties. The results were compared with the parallel results obtained on a casting gravity poured into the sand mould and solidifying in a traditional way at ambient temperature.
PL
W pracy przedstawiono analizę procesu wysychania warstw wierzchnich piaskowych form i rdzeni odlewniczych (wykonanych z formierskiej sypkiej masy samoutwardzalnej z uwodnionym krzemianem sodu utwardzanej ciekłym utwardzaczem estrowym) poddanych uprzednio procesowi pochłaniania wilgoci. Po 12-godzinnym procesie sorpcji wilgoci z otoczenia w warunkach wysokiej wilgotności względnej powietrza (powyżej 85%) oraz temperatury (28−33°C) analizowano proces wysychania (desorpcji) powierzchniowych warstw form i rdzeni odlewniczych w warunkach odpowiednio niższych wartości temperatury i wilgotności na przykładzie masy ze szkłem wodnym. W badaniach wykorzystano metodę grawimetryczną. Na podstawie uzyskanych wyników wykazano, że zawilgocone powierzchniowe warstwy wysychają z różną intensywnością, uzależnioną od warunków otoczenia oraz rozmiarów ziarna osnowy piaskowej (porów międzyziarnowych). Wiedza na temat przebiegu zarówno procesu sorpcji, jak i desorpcji wilgoci przez wierzchnie warstwy elementów form piaskowych jest niezbędna do zapobiegania powstawaniu powierzchniowych wad odlewów, pojawiających się okresowo w odlewniach.
EN
An analysis of the drying process of surface layers of sand moulds and cores (made of loose self-hardening moulding sand with hydrated sodium silicate hardened with a liquid ester hardener) which was previously subjected to the process of moisture sorption is presented in the hereby paper. After a 12-hour process of moisture sorption from the environment under conditions of high relative air humidity (over 85%) as well as temperature (28−33°C), an analysis was performed using the drying (desorption) process on the surface layers of sand moulds and cores under conditions of lower values of temperature and humidity on the example of water glass moulding sand. The investigations involved the use of the gravimetric method. Based on the obtained results, it was demonstrated that the moistened surface layers dry up with different intensities depending on the environmental conditions as well as the size of the sand grains (intergranular pores). The knowledge of the course of both the sorption and desorption of moisture by surface layers of sand mould components is necessary to prevent the formation of casting surface defects, which periodically appear in foundries.
EN
The purpose of this work was to the application of Si oxide coatings. This study deals with the preparation of ceria (CeO2) nanoparticles coating with SiO2 by water glass and hydrolysis reaction. First, the low temperature hydro-reactions were carried out at 30~100°C. Second, Silicon oxide-coated Nano compounds were obtained by the catalyzing synthesis. CeO2 Nano-powders have been successfully synthesized by means of the hydrothermal method, in a low temperature range of 100~200°C. In order to investigate the structure and morphology of the Nano-powders, scanning electron microscopy (SEM) and X-ray diffraction (XRD) were employed. The XRD results revealed the amorphous nature of silica nanoparticles. To analyze the quantity and properties of the compounds coated with Si oxide, transmission electron microscopy (TEM) in conjunction with electron dispersive spectroscopy was used. Finally, it is suggested that the simple growth process is more favorable mechanism than the solution/aggregation process.
EN
The aim of the study was to determine the applicability of a new product added to water glass-containing foundry sands hardened with ethylene glycol diacetate. The new additive designated by the symbol "B" is a composition of aqueous solutions of modified polyalcohols, improving the sand knocking out properties. The scope of studies included testing various mechanical and technological properties of foundry sand mixtures, such as permeability, friability, life cycle of cores and knocking out properties. In the technological studies, two types of water glass with different values of the silica modulus and density, designated as R145 and R150, were used. Moulding sands were prepared with the additive "B". For comparison, reference sands with water glass but without the additive "B" were also made. In Part I of the article, the results of studies of the effect of additive "B" on the properties of foundry sands with water glass hardened by CO2 blowing were discussed.
EN
The nanocomposites based on water glass matrix were attempted in the study. Nanoparticles of ZnO, Al2O3 or MgO in organic solutions were applied into water glass matrix in the amounts of: 1.5; 3; 4 or 5 mas. %. Wettability of the quartz sad by the nanocomposites based on water glass matrix was determined by testing changes of the wetting angle θ in time τ for the system: quartz – binder in non-stationary state, by means of the device for measuring wetting angles. Wettability measurements were carried out under isothermal conditions at an ambient temperature (20 – 25 oC). The modification improves wettability of quartz matrix by water glass, which is effective in improving strength properties of hardened moulding sands. Out of the considered modifiers in colloidal solution of propyl alcohol water glass modified by MgO nanoparticles indicated the smallest values of the equilibrium wetting angle θr. This value was equal app. 11 degrees and was smaller no less than 40 degrees than θr value determined for not modified water glass. Viscosity η of nanocomposites based on water glass matrix was determined from the flow curve, it means from the empirically determined dependence of the shearing stress τ on shear rate γ: τ = f (γ) (1), by means of the rotational rheometer. Measurements were carried out at a constant temperature of 20 oC. The modification influences the binder viscosity. This influence is conditioned by: amount of the introduced modifier as well as dimensions and kinds of nanoparticles and organic solvents. The viscosity increase of the modified binder does not negatively influence its functional properties.
PL
W artykule przedstawiono wyniki badań dotyczące nowego rodzaju spoiwa bezklinkierowego powstałego w wyniku aktywacji alkalicznej granulowanego żużla pomiedziowego. Ważnym elementem przeprowadzonych badań było określenie wpływu standardowych i przyspieszonych warunków dojrzewania na właściwości mechaniczne otrzymanych kompozytów.
EN
The article presents the results of research on a new type of non-clinker binder obtained as a result of alkaline activation of a granular copper slag. An important element of the study was determination of the maturation conditions effect (standard or accelerated) on the mechanical properties of the composites.
PL
W pracy podjęto próbę określenia wpływu dodatku zwilżającego powierzchnię osnowy kwarcowej, wprowadzonego dla zwiększenia efektywności utwardzania, wybraną metodą fizyczną, ekologicznych mas ze szkłem wodnym sodowym. Ocenę wpływu zwilżania wodą osnowy kwarcowej, przed wprowadzeniem w procesie mieszania niemodyfikowanych, nieorganicznych spoiw, przeprowadzono na podstawie porównania parametrów wytrzymałościowych i technologicznych mas świeżo sporządzonych i utwardzonych suszeniem w temperaturze 100°C. W badaniach zastosowano piasek kwarcowy średni oraz trzy gatunki uwodnionego krzemianu sodu: 137, 140 i 145. Stwierdzono, że modyfikacja sposobu przygotowania osnowy kwarcowej poprzez wprowadzenie dodatku wody, przed dodaniem niewielkiej, 1,5 cz. mas. spoiwa, korzystnie wpływa na osiągane po utwardzeniu parametry wytrzymałościowe i technologiczne mas. Wyniki pomiarów skonfrontowano z obserwacjami połączeń ziaren osnowy kwarcowej, przeprowadzonymi za pomocą mikroskopu skaningowego. Uzupełniono je również zdjęciami i analizą składu chemicznego powierzchni ziaren kwarcu. Na podstawie kompleksowej oceny, utwardzonych suszeniem klasycznym mas formierskich, stwierdzono pozytywny wpływ obecności dodatku zwilżającego w masach, którego najkorzystniejsza ilość powinna być dobierana w zależności od gatunku użytego spoiwa.
EN
An attempt has been made to determine the effect of the addition of an agent wetting the surface of silica sand grains, introduced in order to increase the hardening efficiency of selected physical methods applied to the ecological foundry sands bonded with sodium water glass. The effect of water used as a wetting agent of the silica sand grains, added during the mixing process prior to the introduction of unmodified inorganic binders, was evaluated by comparing the mechanical and technological parameters of green sands and sands hardened by drying at 100°C. Tests and studies were carried out on silica sand of medium grain size and on three grades of hydrated sodium silicate, i.e. 137, 140 and 145. It has been found that modification of the method of the base sand processing by adding water prior to the addition of a small amount (1.5 parts by weight) of binder has a beneficial effect on the technological and mechanical parameters of moulding sands obtained after the hardening process. The results of measurements were confronted with the SEM studies of bonds formed between the grains of silica sand. The studies were completed with photographs and chemical analysis of the surface of silica sand grains. Based on a comprehensive evaluation of moulding sands hardened by the conventional drying process, the beneficial effect of a wetting agent, added to the sand mixture in an amount optimum for a given type of binder, has been confirmed.
EN
The results of research on the possibility of using a gaseous medium (hot air) as a hardening agent for inorganic binders were discussed, and tests on the reclamation of waste moulding sands were carried out. The research programme also included the use of a modernized test stand for hardening of foundry sands with gaseous agents and a pilot plant for the sand reclamation. Cores made on the test stand were examined for the basic technological properties and were also used in moulds for the trial knocking out of castings. Two types of binders were tested, i.e. a modified water glass designated as Binder A and, for comparison, a reference material which was hydrated sodium silicate R145. The hardener for the sand mixtures was hot air (the dehydration of water glass). Trials of the sand reclamation were carried out in a laboratory pilot plant, installed and operating at the Foundry Research Institute. The obtained reclaim was added in different amounts to the sand mixtures subjected to technological tests. The next step included the manufacture of test moulds, pouring them with aluminium alloy, and knocking out of castings to test the collapsibility of moulds and cores.
EN
In the paper, an attempt was made to evaluate the effect of preliminary wetting of high-silica base during preparation of moulding sands containing a selected grade of sodium water-glass, designed for hardening by traditional drying or by electromagnetic microwaves at 2.45 GHz. In the research, some water was dosed during stirring the sandmix before adding 1.5 wt% of the binder that was unmodified sodium water-glass grade 137, characterised by high molar module within 3.2 to 3.4. Scope of the examinations included determining the effect of wetting the base on mechanical parameters like compression, bending and tensile strength, as well as on technological parameters like permeability, abrasion resistance and apparent density. The research revealed a significant positive effect of adding water to wet surfaces of high-silica base grains on mechanical properties and quality of moulding sands hardened by physical methods, in particular by microwave heating.
PL
W niniejszej pracy zaprezentowane zostały wyniki badań zwilżalności kwarcu przez ekologiczne spoiwo odlewnicze. W badaniach wykorzystano jako spoiwo szkło wodne modyfikowane nanocząstkami tlenków metali typu: MgO, Al2O3 oraz ZnO w rozpuszczalnikach organicznych: metanolu lub propanolu. Nanocząstki syntetyzowane były metodą elektrochemiczną w procesie anodowego roztwarzania odpowiednich metali: Zn, Al, Mg. Zwilżalność oceniano, badając zmiany kąta zwilżania θ w czasie w układzie: kwarc-szkło wodne. W badaniach wykorzystano prototypowy aparat do pomiaru kąta zwilżania wraz z opracowaną wcześniej metodyką. Systematyczne badania zwilżalności kwarcu przez zmodyfikowane nanocząstkami szkło wodne wykazały, że na parametr ten wpływa między innymi: ilość wprowadzonego modyfikatora, rodzaj nanocząstek, a także rodzaj zastosowanego rozpuszczalnika. Przeprowadzone badania wykazały, że kwarc był najlepiej zwilżalny (mała wartość kąta zwilżania) przez szkło wodne modyfikowane nanocząstkami MgO oraz Al2O3 w propanolu.
EN
The results of studies of quartz wettability by an ecological foundry binder are presented. Water glass modified with nanoparticles of metal oxides, such as: MgO, Al2O3 and ZnO in organic solvents (methanol or propanol) was used as a binder in the investigations. The nanoparticles were undergoing electrochemical synthesis in the process of anodic dissolution of metals such as Zn, Al, Mg. Wettability was assessed by measuring the time-related changes of the contact angle θ in a quartz-water glass system. In the measurements of the contact angle a prototype apparatus and previously developed methodology were used. Systematic tests of the quartz wettability by water glass modified with nanoparticles have indicated that this parameter depends, among other things, on the amount of the introduced modifier, and on the type of nanoparticles and type of the solvent applied. The performed investigations have proved that quartz was best wetted (small contact angle) by water glass modified with the nanoparticles of MgO and Al2O3 in propanol.
PL
W pracy przedstawiono wyniki badań wstępnych nad możliwością zastosowania innowacyjnych zabiegów aktywacji spoiw nieorganicznych w trakcie procesu regeneracji zużytych, utwardzanych w procesie suszenia klasycznego mas formierskich ze szkłem wodnym. Przeznaczoną do badań masę, sporządzoną z piasku kwarcowego i wybranego szkła wodnego sodowego gatunku 145, poddawano następującym etapom przerobu: mieszanie składników, zagęszczanie, suszenie w temperaturze 100°C w celu utwardzenia, studzenie, obciążanie termiczne formy do temperatury 800°C, studzenie do temperatury otoczenia, wybijanie formy, regeneracja mechaniczna sucha i mokra w celu przywrócenia właściwości wiążących masie. Do badań wytypowano kilka sposobów przerobu zużytej masy, w których zastosowano między innymi: zjawiska powierzchniowe towarzyszące regeneracji mechanicznej połączonej z odpylaniem odseparowanego od ziaren osnowy kwarcowej przereagowanego termicznie spoiwa. Wykonano również badania nad możliwością stosowania elementów regeneracji mokrej w celu rehydratacji przereagowanego termicznie spoiwa. Dla określenia skuteczności proponowanych sposobów aktywacji, po ich przeprowadzeniu mierzono wybrane parametry wytrzymałościowe. W trakcie badań ujawniono wpływ, między innymi: zastosowanych urządzeń aktywujących i odpylania w trakcie regeneracji wstępnej masy. Stwierdzono, że istnieje możliwość częściowego przywrócenia zdolności do wiązania spoiwa w zużytej, w odpowiedni sposób przerobionej masie formierskiej zawierającej szkło wodne, pod warunkiem stosowania fizycznych metod jej utwardzania. Wyniki przeprowadzonych badań, w tym także obserwacji powierzchni ziaren osnowy w regenerowanej masie, umożliwiają wytypowanie najkorzystniejszych zabiegów przerobu zużytych mas formierskich do stosowania w innowacyjnym procesie cyklicznego ich odświeżania. Wyniki badań przybliżają możliwość stosowania ekologicznej, innowacyjnej metody odświeżania mas formierskich z nieorganicznymi spoiwami utwardzanymi metodami fizycznymi, tak aby pełniły one rolę alternatywnej technologii dla tradycyjnych mas obiegowych.
EN
The article presents the results of preliminary studies on the possible application of innovative activation treatments of inorganic binders during the reclamation of waste water glass moulding sands hardened by conventional drying. The test moulding mixture based on silica sand and selected sodium water glass in grade 145 was subjected to the following processing steps: mixing of components, compaction, drying at 100°C for hardening, cooling, thermal loading of mould up to a temperature of 800°C, cooling to ambient temperature, knocking out, and dry or wet mechanical reclamation to restore the sand mixture binding properties. Several waste sand processing techniques were chosen; they use, among other things, various surface phenomena usually accompanying the mechanical reclamation combined with dedusting of the thermally reacted binder separated from the base silica sand grains. Studies also covered possible use of some elements of the wet reclamation process to rehydrate the thermally reacted binder. To check the effectiveness of the proposed methods of activation, after their implementation, selected strength parameters were measured. Studies disclosed, moreover, the importance of the type of device used for the activation and dust removal during the preliminary reclamation of moulding sand. The possibility of restoring partially the binder ability to bond the waste and properly processed moulding sand containing sodium silicate has been confirmed, providing physical methods which are applied for its hardening. The results of conducted tests, including examination of the surface of sand grains in the reclaimed mixture, allowed selecting the best method that can be used for the waste moulding sand treatment in an innovative process of the periodical sand rebonding. The results of tests highlight the possibility to use an eco-innovative method of rebonding the moulding sands with inorganic binders hardened by physical means and make them an alternative technology for the traditional system sands.
EN
The paper presents the results of basic research on the influence of the properties of sand grains on electrical properties of water glass moulding sands. It shows electrical properties of the main component – sand grains, crucial to the kinetics of moulding sands heating, such as permittivity εr and loss factor tgδ. Measurements were carried out with the use of the perturbation method for silica, chromite and olivine sands of different mineral, chemical composition and particle size distribution, as well as for moulding sands with water glass grade 145. Analysis of the results of measurements of electrical properties shows that all moulding sands are characterized by a similar permittivity εr and loss factor tgδ. It was found that the electrical properties and the quantity and quality of other components may have a decisive influence on the effectiveness and efficiency of the microwave heating of moulding sands with sand grains. In determining the ability to efficiently absorb the microwave radiation for mixtures which moulding sands are, the impact of all components influencing their individual technological parameters should be taken into account.
EN
Presented are results of a research on the possibility of using artificial neural networks for forecasting mechanical and technological parameters of moulding sands containing water-glass, hardened in the innovative microwave heating process. Trial predictions were confronted with experimental results of examining sandmixes prepared on the base of high-silica sand, containing various grades of sodium water-glass and additions of a wetting agent. It was found on the grounds of obtained values of tensile strength and permeability that, with use of artificial neural networks, it is possible complex forecasting mechanical and technological properties of these materials after microwave heating and the obtained data will be used in further research works on application of modern analytic methods for designing production technology of high-quality casting cores and moulds.
EN
The results of investigations of the sorption process of surface layers of sand moulds under conditions of a high air humidity are presented in the paper. Investigations comprised three kinds of moulding sands with inorganic and organic binders: moulding sand with hydrated sodium silicate with furfuryl resin and with alkyd resin. Tests were performed on the prototype research stand allowing to maintain a constant, high temperature of surroundings (28–33°C) and the relative air humidity (above 95%). The gravimetric method was applied in measurements. The proposed method allows to assess the amount of water which permeates by the area unit of surface layers of sand moulds into their insides. Knowledge of such parameter allows to select the proper storage conditions of casting moulds waiting for being poured with liquid metals. This can limit the occurrence of surface defects which are caused by too high humidity of casting moulds.
EN
In the paper, presented are measurements of permittivity εr and loss factor tgδ of moulding sand depending on bonding material content, taken at 2.45 GHz by perturbation method on a stand of wave-guide resonance cavity. The determined electrical properties are crucial for kinetics of microwave heating of sandmixes containing water-glass as a binder. The measurements were taken for two sandmixes with various sand grains. The results indicate that, for a moulding sands containing water-glass, the relationship between loss factor value and binder concentration is linear. All the examined moulding sands, irrespective of their base, show a relatively high susceptibility to action of microwave field of frequency 2.45 GHz. The presented measurements make a ground for developing a mathematical model of microwave heating of the systems moulding sand-foundry tooling.
EN
The modification of water glass with nanoparticles of metal oxides in organic solvents was attempted in the study. The results of investigations of moulding sands with water glass modified by nanoparticles of the selected metal oxides in organic solvents, are presented in the hereby paper [21]. Nanoparticles of ZnO, Al2O3 or MgO in methanol, ethanol or propanol solutions were applied as modifiers of binding agents. Colloidal solutions of the modifiers were introduced into water glass in the amounts of 3, 5 or 7 mass %. Influences of the applied modifier and organic solvents as well as the modifier fraction in the binder on the selected strength properties of moulding sands were tested. On the bases of the analyses of the obtained results the probable mechanism of the water glass modification with nanoparticles of metal oxides was proposed.
EN
The paper presents results of a research on a possibility to apply the innovative, combined with activation of the binder, reclamation process of microwave-hardened moulding sands containing water-glass. The sandmix to be examined, prepared of high-silica sand and the selected water-glass grade 145, was subject to the following cyclical processing stages: mixing the components, compacting, microwave hardening, cooling-down, thermal loading the mould to 800 or 1200 °C, cooling-down to ambient temperature, knocking-out, mechanical dry and wet reclamation, refreshing. After each subsequent cycle of processing the sandmix, used and overheated to various degrees, determined was tensile and bending strength. Analysis of the obtained results indicates that it is possible to activate regenerate of used sandmix containing water-glass, hardened by microwave heating. However, effectiveness of activation in subsequent life cycles of the sandmix is significantly affected by temperature of the casting alloy poured to the mould.
19
Content available remote Mechanical properties of alkali-acivated binders based on copper slag
EN
The paper describes the possibility of using copper slag, an industrial waste from smelting of copper as a basic component of hydraulic binders obtained by means of the alkaline activation. For the purpose, the aqueous sodium silicate and technical sodium metasilicate were used. Mortars, having undergone the activation process were cured under laboratory conditions (temp. 20±1°C and relative humidity approx. 60%) and were subjected to low pressure heat treatment at a temperature of 80°C. Research over the alkaline activation of slag proved that the desirable quality of alkali-activated binders is achievable just in case of using granulated copper slag, where 98% of the base mass constitutes of glassy phase, and water glass with the lowest value of silicate modulus (Mk = 1.75).
PL
W artykule przedstawiono możliwości wykorzystania odpadowego żużla pomiedziowego pochodzącego z hutnictwa miedzi jako podstawowego składnika spoiw hydraulicznych otrzymanych na drodze aktywacji alkalicznej. W procesie stosowano szkło wodne sodowe o zmiennym module krzemianowym oraz techniczny metakrzemian sodu. Zaprawy po procesie aktywacji dojrzewały w warunkach laboratoryjnych (temp. 20±1°C i wilgotność względna ok. 60%) oraz były poddane niskociśnieniowej obróbce cieplnej w temperaturze 80°C. Badania nad aktywacją alkaliczną żużla dowiodły, że możliwe jest uzyskanie pożądanej jakości spoiw aktywowanych alkalicznie tylko w przypadku stosowania granulowanego żużla pomiedziowego, w którym 98% masy zasadniczej stanowi faza szklista oraz przy użyciu szkła wodnego o najniższym module krzemianowym (Mk = 1.75).
PL
W artykule opisano badania, których celem było opracowanie nowej rodziny spoiw hydraulicznych na bazie żużla pomiedziowego, stanowiącego odpad przemysłowy z hutnictwa miedzi. Granulowany i szybowy żużel pomiedziowy nie wykazuje aktywności hydraulicznej, dlatego w badaniach podjęto próby ich alkalicznej aktywacji. W tym celu wykorzystano 5 rodzajów aktywatorów alkalicznych w postaci sodowego szkła wodnego oraz technicznego metakrzemianu sodowego o zmiennym module krzemianowym. Badania nad aktywacją alkaliczną żużla dowiodły, że najlepsze właściwości mechaniczne (wytrzymałość na ściskanie po 90 dniach wynosiła 53,5 MPa) osiągalne są tylko w przypadku stosowania granulowanego żużla pomiedziowego (100% masy zasadniczej żużla stanowi faza szklista) oraz przy użyciu szkła wodnego o najniższym module krzemianowym (Mk=1,79). Wraz z malejącym modułem krzemianowym zastosowanego szkła wodnego sodowego, widoczny był wzrost wytrzymałości.
EN
The article describes research aimed at developing a new family of hydraulic binders based on copper slag, which is industrial waste from smelting of copper. Granulated and lump copper slags do not show hydraulic activity, so the studies were based on their alkaline activation. For this purpose the five types of alkaline activators in the form of aqueous sodium silicate and technical sodium metasilicate were used. All activators were varied in terms of silicate modulus value. Studies on the alkaline activation of slags showed that the best mechanical properties (compressive strength after 90 days amounted even 53.5 MPa) is achievable only in case of using granulated copper slag (100% of the slag constitutes the glassy phase) and water glass with the lowest value of silicate modulus (Mk = 1.79). Along with decreasing silicate module of used water glass there is a significant increase in strength.
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