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EN
The paper presents an assessment of rheological properties of commercial potato starch pastes as a binding liquid source in the process of granulation of single and multi-component loose materials using by Carreau-Yasuda model Based on the obtained results, it was found that high viscosity values of starch pastes and significant stiffness of their internal structure are not a guarantee of resistance of this structure to external forces, and may also reduce the efficiency of the granulation process itself.
PL
W pracy przedstawiono ocenę właściwości reologicznych kleików komercyjnej skrobi ziemniaczanej, jako źródła stanowiącego ciecz wiążącą w procesie granulacji jedno i wieloskładnikowych materiałów sypkich poprzez zastosowanie modelu Carreau-Yasudy. Na podstawie uzyskanych wyników stwierdzono, że wysokie wartości lepkości kleików skrobiowych i znacząca sztywność ich struktury wewnętrznej nie są gwarancją odporności tej struktury na działanie sił zewnętrznych, mogą ponadto obniżać efektywność samego procesu granulacji.
PL
Przedstawiono stan wiedzy i przegląd literatury w zakresie właściwości reologicznych polimerowych kompozytów drzewnych. Poddano dyskusji zagadnienie wyznaczania właściwości reologicznych kompozytów drzewnych na podstawie reometrii kapilarnej. Wskazano na rozległe możliwości reometrii kapilarnej w zakresie wyznaczania nie tylko krzywych płynięcia i krzywych lepkości, ale także badania zjawiska poślizgu, oceny granicy płynięcia, różnic naprężeń normalnych oraz lepkości podłużnej. Poddano dyskusji zagadnienie wpływu poprawek reometrycznych Rabinowitscha, Bagleya i Mooneya na położenie krzywej lepkości względem nieskorygowanej krzywej lepkości.
EN
Rheological studies of polymer-wood composite (WPC) with polypropylene matrix contg. 50 or 70% by mass wood filler were performed. Flow and viscosity curves were detd. at 180, 190 and 200°C, and tests of longitudinal viscosity and yield stress at 190°C were carried out. The tested composites had typical pseudoplastic properties, but yield stress, slip phenomenon and stretching (longitudinal viscosity) were obsd. during the flow. The effect of Rabinowitsch, Bagley and Mooney rheometric corrections on the position of the viscosity curve in relation to the uncorrected viscosity curve was discussed.
PL
Przedstawiono ocenę możliwości zastosowania kleików z komercyjnej skrobi ziemniaczanej jako źródła stanowiącego ciecz wiążącą w procesie granulacji jedno- i wieloskładnikowych materiałów sypkich. Oceny tej dokonano poprzez analizę właściwości reologicznych badanych kleików skrobiowych, uwzględniając m.in. stabilność struktury tych kleików oraz ich granicę płynięcia. Na podstawie uzyskanych wyników stwierdzono, że wysokie wartości lepkości kleików skrobiowych i znacząca sztywność ich struktury wewnętrznej nie są gwarancją odporności tej struktury na działanie sił zewnętrznych, mogą ponadto obniżać efektywność samego procesu granulacji.
PL
Przedstawiono rozpoznanie możliwości zastosowania koagulantów do separacji układów wielofazowych. Separacja jest procesem stosowanym w różnych obszarach gospodarki, takich jak ochrona środowiska, przemysł metalurgiczny i chemiczny. Przedstawiono badania określające podstawowe właściwości fizykochemiczne zawiesiny ziarnistej oraz koagulantów wpływających na efektywność procesu separacji. Ich celem było uzyskanie szczegółowych informacji na temat wpływu koagulantów na proces przemysłowego rozdzielania zawiesin. Badania dodatkowe pozwoliły sklasyfikować płyny pod względem reologicznym oraz określić ich lepkość.
EN
PAX XL 19F or PAX 16 coagulants were added to a model aq. suspension of PVC of a specific particle size and at various solid phase concns., mixed and left for phase separation. The turbidity of the overlying water after the separation process was detd., and the rheological tests of the hydrated solid phase were performed and its viscosity was detd. The suspensions formed with PAX XL 19F showed higher viscosity.
PL
Celem niniejszej pracy było zbadanie wpływu dodatku skrobi modyfiko-wanej na stabilność reologiczną mieszanek powlekających zawierających węglan wapnia. Wyznaczone zostały krzywe lepkości i krzywe płynięcia z uwzględnieniem czynnika czasu zarówno dla mieszanek, jak i roztworu skrobi modyfikowanej oraz dyspersji węglanu wapnia. Zawartość skrobi modyfikowanej w mieszankach powlekających wpływa na właściwości reologiczne tych mieszanek, zwiększając ich lepkość i naprężenie ścinające. Wykazano, że mimo reostabilnego charakteru roztworu skrobi i dyspersji węglanu wapnia przygotowane mieszanki powlekające okazały się być płynami reoniestabilnymi. Ich lepkość i naprężenie ścinające zmniejszały się przy wydłużeniu czasu ścinania, co świadczy o właściwościach tiksotropowych. Im większy był dodatek skrobi, tym większa była rozpiętość ramion pętli histerezy krzywych płynięcia i lepkości. A zatem, reologiczna niestabilność mieszanek powlekających wzrastała z dodatkiem skrobi.
EN
The rheological properties of coating color affect its flow behavior during technological process. If upon constant shearing, fluid properties do not change with time, the fluid exhibits rheological stability (rheo-stability). On the other hand, a fluid is said to exhibit rheological instability (rheo-instability) if shear time (for a given shearing conditions) affects its flow behavior. The objective of the conducted research was to examine the effect of modified starch on rheological instability of the coating colors. For this purpose, viscosity curves and flow curves were determined considering the time factor. Such experiments enabled to determine time-dependent rheology. Rheological tests were carried out for calcium carbonate-based coating colors with different starch content (1 pph, 2 pph, 5 pph and 10 pph) as well as for the raw materials used for their preparation, i.e. 10% solution of modified starch and 60% calcium carbonate dispersion. During the research, the rotary rheometer Brookfield RVDV - III+ with the Rheocalc V2.3 control software was used. The measurement principle is based on the determination of the torque for a given shear rate or rotational speed. The measuring element (e.g. spindle, coaxial cylinders), immersed in the test fluid, is set in rotation. A viscous liquid resists the measuring element by generating a torque which is a function of the apparent viscosity of the liquid. During the tests, both RV spindles and DIN coaxial cylinders were used, with the rotating inner cylinder and the stationary outer one. Programs in the B.E.A.V.I.S (Brookfield Engineering Advanced Viscometer Instruction Set) programming language were developed to control the rheometer and collect measurement results. This enabled the experiments to be performed automatically. In order to examine the influence of shear time on the flow and viscosity curves, measurements were made at time intervals of 10, 30 and 60 seconds (the measurement was carried out after 10, 30 or 60 s from the moment of changing the shear conditions, i.e. shear rate or rotational speed). The effect of time on viscosity for constant shear conditions was also investigated. Measurements were made within 4 minutes, and data were collected every 2 seconds. Time factor studies enabled to research rheo-stability and/or rheo-instability (time-dependent rheology). For all tested properties, at least 7 measurements were carried out, and the coefficients of variation did not exceed 4.75%. The starch solution exhibited rheo-stable shear-thinning behavior, whereas calcium carbonate dispersion was a rheo-stable shear thickening fluid. This means that the rheological properties of these liquids depended on shear field but did not depend on shear time (for a given shearing conditions). The content of modified starch in coating colors affects the rheological properties of these liquids, increasing their viscosity and shear stress. It was found that despite the rheo-stable character of both the starch solution and the calcium carbonate dispersion, the prepared coating colors were rheologically unstable as they exhibited time-dependent flow behavior. The viscosity of the coating colors decreased not only with the increase in rotational speed, but also with the increase in shear time. The decrease in their viscosity and shear stress with increasing shear time proves that the tested coating colors exhibited rheo-unstable thixotropic flow behaviors. Additionally, the higher the addition of starch was, the wider was the span of the hysteresis loop arms for both the flow and viscosity curves. Thus, the rheological instability increased with increasing starch content.
EN
Synovial joints are a basic part of the human body. Lack of proper lubrication of joints can lead to significant wear of their surfaces. The tribological and rheological properties of artificial synovial fluid solutions based on hyaluronic acid were studied. It was found that the concentration of selected hyaluronic acid solutions significantly affects the investigated parameters. The most promising results were obtained for 8 wt% hyaluronic acid solution, which showed the highest viscosity and wettability, and the lowest wear.
PL
Stawy maziowe stanowią podstawową część organizmu człowieka. Brak odpowiedniego smarowania stawów może prowadzić do znacznego zużycia ich powierzchni. W pracy zbadano właściwości tribologiczne i reologiczne roztworów sztucznej cieczy synowialnej na bazie kwasu hialuronowego. Stwierdzono, że stężenie wybranych roztworów kwasu hialuronowego znacząco wpływa na badane parametry. Najlepsze wyniki uzyskano dla 8% mas. roztworu kwasu hialuronowego, który charakteryzował się największą lepkością, zwilżalnością, a także najmniejszym zużyciem.
EN
This scientific work presents a study of areas of application and improvement for the Clapeyron–Mendeleev equation to determine the technological parameters of natural and associated petroleum gas under field conditions. As a result of scientific and practical research and laboratory work, the authors, based on the molecular kinetic theory of gases, developed and improved the Clapeyron– Mendeleev equations of state of real gases by adding some genuine parameters for natural and associated petroleum gases produced from oil and gas condensate fields. In this regard, two additional parameters are introduced in the Clapeyron–Mendeleev equation-relative density and relative velocity of gas: and this, as a new scientific result, helps determine any parameter from the seven included in the equation of state of natural and associated petroleum gases developed by the authors. Continuous technological process according to the system of “production, collection, preparation and transportation of products (oil + gas)”, including, separately in non-equilibrium conditions of “collection, preparation and transportation of gas” due to internal energy, causes a natural change in a wide range of basic technological parameters that contribute to frequent changes in the physical and chemical state of the gas. Therefore, this work establishes that one of the main tasks is to show the composition of natural and associated petroleum gas as a result of irreversible transformations of hydrocarbon and acidic components of its internal energy, as a result of which the gas is characterised by a number of patterns in the composition and distribution of components of various hydrocarbon and heterogeneous compositions (i.e., physically and chemically heterogeneous). In these conditions, a practical calculation of gas facilities (gas treatment point, selection of gas separators, field gas pipelines, compressor stations) is carried out to determine process parameters using the Clapeyron–Mendeleev equation of state for real gases, and the results show large errors. This proves once again that many authors have developed equations of state for real gases based on the results of laboratory studies with single-atomic and laboratory gases (hydrogen, nitrogen, oxygen, carbon dioxide, etc.). However, the authors here carried out laboratory studies with products and associated petroleum gas. According to the results of laboratory studies, the authors recommend an improvement of the equation of state of natural and associated petroleum gases.
PL
W pracy przedstawiono studium obszarów zastosowania i doskonalenia równania Clapeyrona–Mendelejewa do wyznaczania parametrów technologicznych gazu ziemnego i towarzyszącego gazu ropopochodnego w warunkach złożowych. W wyniku badań naukowych i praktycznych oraz prac laboratoryjnych autorzy, w oparciu o molekularną teorię kinetyczną gazów, opracowali i udoskonalili równania stanu gazów rzeczywistych Clapeyrona–Mendeleeva poprzez dodanie niektórych parametrów rzeczywistych dla gazu ziemnego i towarzyszących gazów ropopochodnych wydobywanych ze złóż ropnych i kondensatowych. W związku z tym do równania Clapeyrona– Mendeleeva wprowadzono dwa dodatkowe parametry – gęstość względną i prędkość względną gazu, co, jako nowy wynik naukowy, pozwala na wyznaczenie dowolnego parametru z siedmiu parametrów zawartych w opracowanym przez autorów równaniu stanu gazu ziemnego i towarzyszącego gazu ropopochodnego. Ciągły proces technologiczny zgodnie z systemem „produkcji, odbioru, przygotowania i transportu produktów (ropa + gaz)”, w tym osobno w warunkach nierównowagi „odbioru, przygotowania i transportu gazu”, ze względu na energię wewnętrzną powoduje naturalną zmianę w szerokim zakresie podstawowych parametrów technologicznych, które przyczyniają się do częstych zmian stanu fizykochemicznego gazu. Dlatego też przedmiotowa praca jako jedno z głównych zadań stawia przedstawienie składu gazu ziemnego i towarzyszącego mu gazu ropopochodnego powstałego w wyniku nieodwracalnych przemian węglowodorowych i kwasowych składników jego energii wewnętrznej, w wyniku czego gaz ten charakteryzuje się szeregiem prawidłowości pod względem składu i rozprzestrzenienia poszczególnych składników węglowodorowych (o niejednorodnym składzie pod względem fizycznym i chemicznym). W tych warunkach przeprowadzono praktyczne obliczenia dla instalacji gazowych (punkt uzdatniania gazu, dobór separatorów gazu, gazociągi terenowe, tłocznie) w celu określenia parametrów technologicznych z wykorzystaniem równania stanu Clapeyrona–Mendelejewa dla gazów rzeczywistych. Wyniki wykazują duże błędy. Dowodzi to po raz kolejny, że wielu autorów opracowało równania stanu dla gazów rzeczywistych na podstawie wyników badań laboratoryjnych z gazami jednoatomowymi i laboratoryjnymi (wodór, azot, tlen, dwutlenek węgla itp.). Natomiast obecnie autorzy przeprowadzili badania laboratoryjne z udziałem eksploatowanych węglowodorów i towarzyszącego im gazu ropopochodnego. Na podstawie wyników badań laboratoryjnych autorzy zalecili korektę równania stanu dla gazu ziemnego i towarzyszących mu gazów ropopochodnych.
EN
An analysis has been carried out to study the two-dimensional free convective boundary layer MHD nanofluid flow past an inclined plate with heat generation, chemical reaction and radiation effects under convective boundary conditions. The partial differential equations describing the flow are coupled nonlinear. They have been reduced to nonlinear ordinary differential equations by utilizing a similarity transformation, which is then solved numerically with the aid of the Runge-Kutta-based shooting technique. Graphs depict the influence of different controlling factors on the velocity, temperature, and concentration profiles. Numerical findings for skin friction, Nusselt number and Sherwood number are reviewed for distinct physical parameter values. In a limited sense, there is a good correlation between the current study's results and those of the earlier published work.
EN
Drilling fluids most commonly used are generally based on polymers. Polymers such as methylcellulose carboxylate (CMC), polyanionic cellulose (PAC) and xanthan (Xn) have a very important role in the success of drilling operations. Indeed, they are also used to improve certain properties, in particular rheological. However, these polymers can lose their characteristics under the influence of increasing temperature at the bottom of oil wells, thus affecting the ability of the mud to perform its useful role in the drilling operation, namely to raise the cuttings from the bottom of the well to the surface. The present work aims to study the effect of temperature on the main rheological properties (shear stress and plastic viscosity) as well as on the rheological behavior of water-based drilling muds (WBM). WBM_CMC and WBM_PAC (at Xn content fixed) were selected to evaluate the temperature effect (20°C; 40°C; 60°C and 80°C) on the rheological parameters and the rheological behavior. The results revealed that the shear stress and the plastic viscosity of the studied muds were considerably affected by an increase in temperature. A significant decrease in these drilling mud parameters as a function of temperature up to 80°C. A reduction of 58.8% in shear stress and 78.5% in plastic viscosity was observed. The results show that regardless of the test temperature, the shear thinning behavior of the WBM_CMC and WBM_PAC drilling muds is the same as the Herschel-Bulkley model.
EN
The flow of an electrically conducting fluid across a vertically positioned oscillating semi-boundless plate with uniform mass diffusion and temperature is examined in this study in terms of the effects of thermal radiation and viscous dissipation. The dimensionless governing equations were solved using an effective and unconditionally stable implicit finite-difference approach known as the Crank-Nicolson method. Based on the numerical results, the impacts of various physical parameter values on concentration, temperature; velocity; Sherwood numbers, Nusselt numbers and skin-friction profiles are displayed graphically and their consequences thoroughly analyzed. We observed that when the magnetic field, radiation and phase angle parameters are increased, the velocity is reduced. This shows that plate oscillation, radiation and magnetic fields affect the flow pattern significantly.
EN
A theoretical analysis of an asymmetric roller bearing system with cavitation that is hydro-dynamically lightly loaded and lubricated by a thin, incompressible fluid is presented. The lubricant adheres to the non-Newtonian Bingham plastic fluid concept, in which the viscosity of the fluid should change depending on the mean film temperature. The continuity and momentum equations, which regulate fluid flow, are first solved analytically and then numerically using MATLAB. Through graphs and tables, some key bearing features are addressed and further explained. This leads to the conclusion that there is a discernible difference between Newtonian and non-Newtonian fluids in terms of pressure, temperature, load, and traction. The findings are good in line with the body of literature.
EN
An incompressible unsteady free convective viscous MHD rotating flow past a moving plate embedded in a porous medium is considered with the influence of viscous dissipation, heat source effects. It is assumed that the flow rotates with angular velocity which is normal to the plate and also that a transverse magnetic field is applied along the normal to the plate. Appropriate dimensionless quantities are applied to change the governing equations into dimensionless form. Then the equations are solved numerically using the Galerkin finite element method. Some important characteristics of the fluid are studied. The results are in good agreement with the available literature.
EN
The article presents the results of tests, replaced according to the vehicle manufacturer's recommendations, of engine oils. The sample of engine oils in service came from spark-ignition and compression-ignition vehicles used in urban or mixed mode. During their collection, the type of drive unit, the mileage of the car and the number of kilometers the oil was used for were recorded for each sample (this was the main criterion for differentiating samples). In addition, a control group of samples consisting of fresh oils of the same viscosity grade and distributed by the same producer was set up to observe changes in the parameters of individual lubricants after the operating period. The first part of the empirical study consisted of determining the physico-chemical properties of the lubricants, i.e.: kinematic viscosity, density and water content. The second part involved anti-wear tests using a T-02U tribometer. The use of the tribometer made it possible to record the anti-wear parameter, i.e. moment of friction, and also the load imposed on the friction node, as a result of which it was possible to calculate the friction force and friction coefficient. The research was complemented by an analysis of worn surfaces of the friction node on a microscope. The tests carried out can be used for predictive purposes, in terms of assessing the condition of a lubricant subjected to an operating process in an internal combustion engine.
EN
The axial, radial and tangential velocity profiles of six fluids were extracted from computational fluid dynamics simulation results at points in a pump chamber 1 mm distant from the blades in a vortex pump at the specific speed of 76. The critical radius was specified in the axial velocity radial profiles to determine the impeller inlet and outlet at six viscosities and part-load, design, and over-load points. A mean-line flow model and hydraulic loss model were built from the profiles. The incidence, incidence loss in the inlet, deviation angle, and slip factor in the outlet were calculated. The impeller theoretical head, pump hydraulic efficiency and volumetric efficiency were analyzed. It was shown that the axial, radial and tangential velocity profiles relate closely to the flow rate as usual, but also the viscosity, especially at low flow rates and in the inlet. The low flow rate and viscosity lead to near zero axial and radial velocities, a faster tangential velocity than the blade speed, negative incidence, and a small incidence loss coefficient in the inlet. The dimensionless critical radius ranged within 0.77–0.89 and reduces with the increasing flow rate and viscosity. The mean slip factor is between 0.11 and 0.20 and rises with the increasing flow rate and viscosity. The mean incidence loss coefficient is within 0.0020–0.15 and augments with the increasing flow rate but increases with the decreasing viscosity under part-load conditions. The theoretical head estimated by using the fluid tangential velocity between the outlet of the impeller and the inlet of the chamber is more reasonable.
15
Content available Heterogeneous polymers degradation – microplastic
EN
The process of semicrystalline polymers thermo-oxidative degradation was analyzed on the example of isotactic polypropylene (iPP). Oxygen degradation takes place mainly in the amorphous phase into which oxygen diffuses. This leads to oxidation (formation of hydroperoxides) and next the chains scission. The polymer becomes brittle and breaks down into small pieces (e.g. microplastics). The crystalline phase is more difficult to access for oxygen that initiates the thermo-oxidation process. An increase in the crystallinity degree and a decrease in the viscosity of the solutions diluted in p-xylene as a function of the degradation time were observed. The number of iPP chain scission (change in molecular weight) as a function of degradation time was also calculated. These values depend on the polymer initial crystallinity degree and its supermolecular structure.
PL
Na przykładzie izotaktycznego polipropylenu (iPP) przeprowadzono analizę procesu termooksydacyjnej degradacji polimerów semikrystalicznych. Degradacja z udziałem tlenu obydwa się przede wszystkim w fazie amorficznej, do której dyfunduje tlen. Prowadzi to do utleniania (powstawania wodoronadtlenków), a następnie pękania łańcucha polimerowego. Polimer staje się kruchy i rozpada na małe fragmenty (m.in. mikroplastik). Faza krystaliczna jest trudniej dostępna dla tlenu inicjującego proces termoutleniania. Stwierdzono wzrost stopnia krystaliczności i zmniejszenie lepkości roztworów rozcieńczonych w p-ksylenie w funkcji czasu degradacji. Obliczono również liczbę pęknięć łańcucha iPP (zmianę masy cząsteczkowej) w funkcji czasu degradacji. Wielkości te zależą od początkowego stopnia krystaliczności polimeru i jego struktury nadcząsteczkowej.
EN
The aim of this study is to consider the effect of pressure on the viscosity of lubricating oil in the adopted model of hydrodynamic lubrication and on the calculated flow parameters and operating parameters of a conical slide bearing. The numerical analysis consisted in solving the Reynolds type equation for the process of stationary hydrodynamic lubrication.
PL
Celem niniejszej pracy jest zbadanie, w jakim stopniu uwzględnienie wpływu ciśnienia na lepkość oleju smarnego, w przyjętym modelu hydrodynamicznego smarowania, oddziałuje na obliczane parametry przepływowe i eksploatacyjne analizowanego stożkowego łożyska ślizgowego. W badaniach wykorzystano znane z literatury równanie typu Reynoldsa, określające proces stacjonarnego hydrodynamicznego smarowania.
EN
This computational work explores the heat and mass transfer of copper water nanofluid flowing along an inclined plate with varying surface temperature and concentration in the presence of a magnetic field and radiation through a permeable medium. The dimensionless governing equations are solved numerically using an efficient finite-difference technique, which is fast convergent and unconditionally stable. The findings are reviewed and illustrated through graphs for pertinent parameters.
EN
analysis is carried out to study chemically reactive, viscous dissipative effects of an incompressible and electrically conducting fluid with MHD free convection adjacent to a vertical surface with variable thermal conductivity (VTD) and variable mass diffusivity (VMD). An approximate numerical solution for the steady laminar boundary layer flow over a wall of the surface in the presence of species concentration and thermal mass diffusion has been studied. Using numerical techniques the governing boundary layer equations are solved to get the exact solution. Numerical calculations are carried out for different values of dimensionless parameters. The results are exhibited through various graphs and it is observed from the analysis of the results that the velocity field is appreciably influenced by the magnetic effect, porous effect, chemical reaction and buoyancy ratio between the species and thermal diffusion at the wall of the surface.
EN
The influence of slip parameter, viscous dissipation, and Joule heating parameter on MHD boundary layer nanofluid flow over a permeable wedge-shaped surface was analysed. The PDEs and the associated boundary conditions were transformed to a set of non-similar ODEs and the obtained system of equations was solved numerically with the help of the spectral quasi-linearization method (SQLM) by applying suitable software. This method helps to identify the accuracy and convergence of the present problem. The current numerical results were compared with previously published work and are found to be similar. The fluid velocity, fluid temperature, and nanoparticle concentration within the boundary layer region for various values of the parameters such as the slip effect, magnetic strength, Prandtl number, Lewis number, stretching ratio, viscous dissipation, suction, Brownian motion, Joule heating, heat generation, and thermophoresis are studied. It is observed that the Brownian motion, Joule heating, viscous dissipation, and thermophoresis lead to decreases in the heat and mass transfer rate. The skin friction coefficient enhances with slip, magnetic, permeability, and suction parameters, but reduces with the Brownian motion, wedge angle, and stretching ratio parameters whereas there is no effect of mixed convection, thermophoresis, heat generation parameters, the Prandtl and Eckert number.
EN
In this paper, heat transfer in flow between two horizontal parallel porous plates through a porous medium when the upper plate oscillates in its own plane has been analyzed taking into account the effect of viscous dissipation. An increment in the Prandtl number or Reynolds number results in an increment of the temperature profile. With an increase in viscous dissipative heat the temperature distribution decreases.
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