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Synthesis and Characterization of Iron Oxide Nanoparticles Reinforced Polyester/Nanocomposites

Kumar G. N., Reddy Y. V. M., Reddy K. H.

International Letters of Chemistry, Physics and Astronomy

2015

Vol. 52

39--52

We report on synthesis of two highly disperse nanoparticles viz. Fe2O3 & f-Fe2O3 using chemical reduction method. Reaction was initiated to mix solution A (i.e. Fecl3 6H2o) into solution B (i.e. Fecl24H2O) together under the presence of ammonium to develop nanoparticles. Mechanical properties of above mentioned nanoparticles filled with polyester polymer nanocomposites were fabricated to assess the possibility of using this filler as a new material. Methacryloxypropyl was used as a functionalization agent to prepare f-Fe2O3nanoparticles. Mechanical properties of f-Fe2O3 nanocomposites were improved with the help of functionalization when compared with Fe2O3 nanocomposites. A functionalization of nanoparticles favours the composite fabrication with a lower curing temperature as compared to the as-synthesised nanoparticles filled polyester nanocomposites. Thermogravimetric analysis showed an increased thermo-stability of f-Fe2O3 nanoparticles filled polyester nanocomposites as compared to the Fe2O3 nanoparticles filled counterparts. Mechanical and thermal properties were increased due to the homogeneous particle dispersion and chemical bonding between nanoparticles and polyester matrix. The nanoparticles become magnetically harder after incorporation into the polyester resin matrix.

Polymer Blended (Epoxy/Vinylester) Nanocomposites Resistance against Pulling & Sliding Wear Loads

Harisankar P., Reddy Y. V. M., Reddy K. H.

International Letters of Chemistry, Physics and Astronomy

2014

Vol. 18

75--90

This paper discloses the development and synthesis of polymer blended nanocomposites filled with nanoclay. The hybridization of epoxy is mixed with vinylester resin (VER) to prepare polymer blend filled with organoclay was studied to enhance mechanical properties of epoxy/VER. Clay loading was done in such a way that with different wt. proportions viz.1, 1.5, 2.0, 2.5, 3.0, 4.0, 5.0, & 7.5 w % ratios. Appropriately cured samples gave excellent mechanical and tribological properties. Results showed that the tensile strength of the composites increased with increase in filler content for the range of filler contents (2.5-4 % vol.). The results indicated that at 4 % wt. of filler concentration the tensile strength obtained is good i.e. 47.79 MPa with density 1.37 gm/cm3 and hardness 45.5. Dry Sliding wear tests were also conducted by following a well-planned experimental schedule based on Taguchi’s design of experiments, considering parameters like Filler content, Normal load, Sliding Velocity and Sliding distance, on a Pin-On-Disc set-up (ASTM G-99 standard, Make: DUCOM Engineers, Bangalore, India). In the experimentation composite pins were worn against a rotating steel disc (Europe Norm) EN-31, (Rockwell C Hardness) HRC 60 and (Roughness Average) Ra 0.02 microns. Control factors like Filler Content, Normal Load were found to be significant factors affecting the Wear rate i.e. the inclusion of nanoclay as filler found to be contributed in improving the wear resistance of the composite. SEM observations are made to probe the wear mechanisms involved.