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1

Simultaneous removal of SO2 and NOx from sintering flue gas using ammonia-Fe(II)EDTA combined with electrolytic regeneration

Liang Y., Yao X., Quin L., Chen W., Han J.

Environment Protection Engineering

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2018

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Vol. 44, nr 2

19--36

EN

Sulfur dioxide and nitrogen oxide are health hazardous gases, which contribute to the formation of submicron acidic particulates. To reduce SO2 and NOx emission from the sintering flue gas, the combination of ammonia-Fe(II)EDTA solution scrubbing with Fe(III) electrolytic regeneration is proposed. The above method has the following advantages: direct conversion of NOx and SO2 to harmless N2 and SO4 2−, recovery of the by-product (NH4)2SO4), simultaneous removal of NOx and SO2 emission from flue gas in the reactor. The effect of the pH, initial Fe(II)EDTA concentration, and voltage on the desulfurization and denitration efficiencies was investigated using a bench-scale reactor. The maximal desulfurization and denitration efficiencies were 98% and 52%, respectively. The optimum parameters were pH ˃ 5.0, 2.1 V, and 0.05 mol·dm–3 Fe(II)EDTA concentration. SO2 and NOx removal from the sintering flue gas by ammonia-Fe(II)EDTA solution scrubbing combined with electrolytic regeneration was also demonstrated in a pilot-scale reactor.

2

Surface Effect on the Buckling of a Stretchable Electronic Structure

Zhang X., Ou Z., Yao X.

Przegląd Elektrotechniczny

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2012

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R. 88, nr 9b

137-140

EN

The structure of a stiff thin film on a compliant substrate has important applications in stretchable electronics. However, such structures are micro-nano-order of magnitude, where surface effects cannot be ignored. Gurtin-Murdoch theory is applied to model the thin film including surface effects. Through energy method, the size-dependent relations between the buckling features, material properties and geometric parameters are deduced. At last the influence of surface effects is illustrated by the case of silicon film and PDMS substrate.

PL

Badano strukturę cienkiej warstwy nałożonej na podłoże. Taka struktura może mieć rząd nanometrów kiedy efekt podłoża nie może być ignorowany. Zaproponowano model matematyczny struktury bazując na teorii Gurtin-Murdoch.

3

Photosynthetic and physiological responses of Swida hemsleyi (C.K. Schneid. et Wangerin) Sojak (Cornaceae) subjected to enhanced UV-B radiation and to nitrogen supply

Yao X., Liu Q.

Polish Journal of Ecology

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2009

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Vol. 57, nr 3

483-494

EN

Atmospheric ozone remains depleted which in turn leads to the increase of UV-B radiation reaching the surface of the earth and in the same time more and more nitrogen will be imported into the terrestrial ecosystems through nitrogen deposition. These two factors will operate simultaneously. The photosynthetic and physiological responses of deciduous broad leaved species Swida hemsleyi occurring commonly at 1350-3700 m a.s.l. subjected to enhanced UV-B and to nitrogen supply were studied. The experimental design included two levels of UV-B treatments (ambient UV-B, 11.02 KJ m[^-2] day[^-1] and enhanced UV-B, 14.33 KJ m[^-2] day[^-1] and two nitrogen levels (without supplemental nitrogen supply and with supplemental nitrogen supply). An experiment was conducted in open semi-field condition in Maoxian Ecological Station of Chinese Academy of Sciences, Sichuan province, China at 1820 m a.s.l. Enhanced UV-B caused a marked decline in growth parameters, net photosynthetic rate, stomatal conductance to water vapour, chlorophyll pigments, whereas it induced an increase in rate of reactive oxygen species (ROS) production and ROS accumulation and malondialdehyde (MDA) content. Enhanced UV-B also induced an increase in leaf thickness and antioxidant compounds content, such as carotenoids and proline content. On the other hand, nitrogen supply caused an increase in some growth parameters, chlorophyll pigments and antioxidant compounds, and reduced ROS accumulation. However, nitrogen supply did not affect MDA content under enhanced UV-B, though it increased antioxidant compounds content and reduced the rate of ROS production and ROS accumulation. These results implied that enhanced UV-B brought harmful effects on Swida hemsleyi seedlings and supplemental nitrogen supply could alleviate the adverse effects of UV-B radiation on plants to some extent.

4

Potential Jurassic/Cretaceous boundary in northeastern China

Sha J., Chen S., Cai H., Jiang B., Yao X., Pan Y., Wang J., Zhu Y., He Ch.

Volumina Jurassica

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2006

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Vol. 4, no. 1

269-270

EN

On the basis of the geological ranges of the Buchia and dinoflagellate cyst assemblages and their global correlation, two distinct biostratigraphical boundaries (event horizons) can be distinguished in the continu ous deposits spanning the Jurassic/Cretaceous boundary in the Dong'anzhen Formation of Dong'an, Raohe County and the Dongrong Formation of boreholes SB86-11 and SB79-1 of Suibin, Suibin County of eastern Heilongjiang, northeasteren China (Fig. 1.). Level 1. The base of the Buchia fischeriana - Buchia unschensis assemblage is characterized by the occurrence of Buchia (e.g. B. unschensis) with inversoid ontogenetic growth of the right valve, and the absence of the underlying B. russiensis, one of the index species of the Buchia russiensis - Buchia fischeriana assemblage, with obliquoid ontogenetic growth of the right valve (Fig. 1, column 2b). The top of the dinoflagellate cyst Amphorula delicate assemblage underlies, but it is near this boundary (Fig. 1, column 2a). This level basically corresponds to the currently accepted Tethyan version of the Jurassic/Cretaceous boundary and the working base of the Cretaceous as recommended by the International Commission on Stratigraphy (www.stratigraphy.org) (Fig. 1, column 1), and approximately corresponds to the boundary between the Boreal Middle-Upper Volgian substages (Fig. 1, column 3). This is because the base of the Buchia unschensis Zone or the base of the Buchia fischeriana - Buchia unschensis assemblage nearly coincides with that of the Boreal Craspedites exoticus Subzone or Craspedites okensis ammonite Zone, which in turn correspond closely to the base of Tethyan Lower Berriasian Berriasella jacobi ammonite Zone (Fig. 1, column 1), which is the index ammonite zone of the Tethyan or the international chronostratigraphic base of Berriasian, and thus the base of the Cretaceous (Fig. 1, column 1). Level 2. The base of the Buchia volgensis - Buchia cf. subokensis - Buchia cf. okensis - Buchia unschensis assemblage, is characterized by those easy-to-recognize large-sized Buchia with inversoid ontogenetic growth of the right valve and even of the left valve, and absence of Buchia fischeriana (Fig. 1, column 2b). The base of the Oligosphaeridium pulcherrimum dinoflagellate cyst assemblage probably corresponds approximately to the base of this Buchia assemblage (Fig. 1, column 2a). This level is very near the Boreal version of the Jurassic/Cretaceous boundary, which corresponds approximately to the base of the Tethyan middle part of Middle Berriasian. This is because the bases of both Buchia volgensis and Buchia cf. okensis in the assemblage of Buchia volgensis - Buchia cf. subokensis - Buchia cf. okensis - Buchia unschensis are closely coincident with the base of the upper Lower Berriasian Boreal Hectoroceras kochi Zone (Fig. 1, columns 2b, 3), and the Tethyan upper Berriasella privasensis Subzone of the Tirnovella occitanica Zone of the middle part Middle Berriasian, approximately corresponds to the middle of the Boreal Lower Berriasian Substage (Fig. 1, columns 1, 3).

5

Syntheses, Structure and Magnetism of Heterobinuclear mi-Oxamido Cu(II)-Ni(II) Complexes Containing tacn as a Terminal Ligand

Yau H., Yan S., Liao D., Wang G., Yao X., Wang H.

Polish Journal of Chemistry

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2004

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Vol. 78 / nr 7

911-917

EN

Two new heterobinuclear complexes, namely Ni(tacn)Cu(oxpn)(ClO4)2.2H2O (1) and Ni(tacn)Cu(pmoxd)(ClO4)2.CH3OH (2), have been prepared from the planar fragments Cu(oxpn) and Cu(pmoxd) (tacn denotes 1,4,7-triazacyclononane, oxpn and pmoxd stand for the dianions of N,N'-bis(3-aminopropyl)oxamide and N,N'-bis(2-pyridylmethyl) oxamide, respectively). Compound 1 crystallizes in the triclinic system, space group Pî, with a= 8.573(2), b= 12.808(3), c = 13.122(3) A, alfa = 99.63(3), beta = 104.72(3) and gama = 96.45(3) graduate at 299 K, Z = 2. The Cu(II) ions are in square-pyramidal surroundings and the Ni(II) ions in octahedral surroundings. The temperature dependence of the magnetic susceptibilities of 1 has been studied in the 5-300 K range, giving the exchange integral J = -92.7 cm-1. This value, while close to those reported for other Cu(II)-Ni(II) complexes involving Cu(oxpn), represents the minimum exchange constant of such heterobinuclear system.