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Content available Modeling and experimental studies of carbon dioxide separation on zeolite fixed bed by cyclic pressure swing adsorption
Aleksandrzak Tomasz, Zabielska Kamila, Gabruś Elżbieta
Polish Journal of Chemical Technology
|
2024
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Vol. 26, nr 1
8--15
EN
The paper presents the results of experimental and model studies of the pressure swing adsorption (PSA) process in a column with a zeolite 13X bed with a height of 0.5 m. The gas mixture consisted of CO2 (10–20%), N2, and H2O (RH 50%) in different ratios. As a result of the column tests, concentration, and temperature evolutions were obtained for each of the adsorption and desorption stages, which were used to determine the breakthrough and bed saturation times and other parameters important for the analysis of the column operation. A mathematical model of the PSA process for the separation of CO2 from the gas mixture was developed. The system of second-order partial differential equations was solved using Matlab software. The research focuses on adsorptive CO2 capture and shows the influence of water vapor and operational parameters on the quality of model validation.
2
Content available Adsorption behaviour of polar solvent and water vapours on Sorbonorit B4 activated carbon
Downarowicz Dorota, Gabruś Elżbieta
Polish Journal of Chemical Technology
|
2023
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Vol. 25, nr 4
28--35
EN
In this work, the affinity of the heterogeneous Sorbonorit B4 (SB4) activated carbon toward methyl ethyl ketone (MEK), isopropyl alcohol (IPA), n-propyl alcohol (NPA) and isobutyl alcohol (IBA), and water vapours was examined. Adsorption equilibrium measurements demonstrate a higher adsorption capacity of water vapour than organic compounds at relative pressures above 0.4. The adsorption capacities of SB4 at the same vapor pressure followed the order: NPA> IPA> MEK> IBA. The Langmuir, Dubinin-Radushkevich, Dubinin-Astakhov, and Toth isotherm models were chosen to describe experimental results. Based on the multi-temperature isotherms, the values of the isosteric heat of adsorption were determined for various adsorbate loading. The results indicate a strong influence of VOC molecule structures and the surface heterogeneity of SB4 on the adsorption efficiency. For IPA-SB4 pair, the maximum temperature rise in a fixed-bed bed in the adsorption process and the energy requirement for regeneration were calculated and experimentally verified.
3
Content available Influence of humidity on carbon dioxide adsorptionon zeolite 13X
Zabielska Kamila, Aleksandrzak Tomasz, Gabruś Elżbieta
Chemical and Process Engineering
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2020
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Vol. 41, nr 3
197-–208
EN
Greenhouse gases such as carbon dioxide and water vapour can be captured from gas streams ona zeolite 13X adsorbent. Experimental water vapour adsorption isotherms and kinetic curves weremeasured in the temperature range of 293–393 K and pressure up to 2100 Pa. The equilibrium datawere developed with Toth and Sips multi-temperature isotherm models. The results of the processrate studies were described using pseudo-first and pseudo-second order kinetic models. Findings werecompared with our own results of CO2adsorption studies on the same zeolite
4
Content available Evaluation of energy saving possibilities in cyclic fixed-bedadsorption process
Kowalski Krzysztof, Gabruś Elżbieta, Downarowicz Dorota
Chemical and Process Engineering
|
2020
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Vol. 41, nr 3
209–-219
EN
The cyclic Electrothermal Temperature Swing Adsorption (ETSA) process in a fixed-bed column withSupersorbon K40 activated carbon (AC) was applied to remove propan-2-ol (IPA) from air. The bedwas electrothermally regenerated using direct resistive heating method. The tests were performed inthe range of operating parameters: IPA loading 0.18-0.26 kg/kg, voltage 19.5 V, set-point temperature393–403 K, nitrogen flow rate 0.12 m3/h.The analysis revealed, that raising the bed temperature resulted in an increase of desorption degree ofadsorbate, reduction of regeneration time and an increase in the energy consumption. The applicationof insulation enabled reduction of energy consumption and regeneration time by 27% and 10%,respectively.
5
Content available Adsorptive removal of cochineal red a dye from aqueous solutions using yeast
Borysiak Martyna, Gabruś Elżbieta
Chemical and Process Engineering
|
2020
|
Vol. 41, nr 2
105–-117
EN
This paper presents an experimental study on Cochineal Red A dye adsorptive removal by yeast. Batchequilibrium and kinetic tests were conducted in constant temperature of 30◦C for the dye’s initialconcentration range of 0.02–0.50 g/L (pH=3and 10) and 0.02–0.35 g/L (pH=7:6). The equilibriumwas reached after 105–120 min. Yeast demonstrated the adsorption capacity of 10.16 mg/g for acidicenvironment (pH=3) and slightly lower values (8.13 mg/g and 8.38 mg/g respectively) for neutral(pH=7:6) and alkaline environment (pH=10). The experimental equilibrium results were fitted withLangmuir, Freundlich, Sips and Toth isotherm models. Most of them (Freundlich model being theexception) were proven sufficient for the experimental data correlation. The adsorption kinetic studiesshowed that the pseudo-second order model fits better the experimental data than the pseudo-first-order model. Results achieved from intra-particle diffusion model indicate that powdered yeast are anonporous adsorbent. The percentage of solution discoloration reached a maximum value of 75% atpH=3for an initial dye concentration of 0.02 g/L.
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