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2 Polish Journal of Chemistry

2 2000

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Reactions of Secondary B-Ketothioamides with Ethyl Bromoacetate and Ethyl 2-Bromopropionate : The Synthesis of N-Substituted 2-Acylmethylidene-1,3-thiazolidin-4-ones

Jagodzinski T., Wesolowska A., Sosnicki J.

Polish Journal of Chemistry

2000

Vol. 74, nr 8

1101-1114

4-Morpholinocoumarin was obtained in the reaction of 4-(2-hydroxythiobenzoyl)morpholine with ethyl bromoacetate in the presence of triphenylphosphosphine and triethylamine. Analogous reactions of 3-keto thioamides with ethyl bromoacetate and ethyl 2-bromopropionate, carried out in THF or acetone, yielded cyclic derivatives.

Deuterium Isotope Effects of 0-Hydroxythioamides, Thiazolines and 5-Acyl-2-thiobarbituric Acids

Hansen P., Duus F., Neumann R., Wesolowska A., Sosnicki J., Jagodzinski T.

Polish Journal of Chemistry

2000

Vol. 74, nr 3

409-420

Deuterium isotope effects on 13C chemical schifts are studied in a series of o-hydroxythioamides, 2 delta-thiazolines and enolic 5-acyl-2-thiobabituric acids. Novel 2-hydroxy-1-thiocarboxamide naphthalenes show steric isotope effects of opposite sign to those observed in 2-hydroxy-1-acetylnaphthalenes and pyrenes. The o-hydroxyaromatic 2delta-thiazolines show tautometric behaviour and accordingly large isotope effects. Tautomerism of these and the thioamides are discussed in relation to structure. Intramolecular hydrogen bonding of non-RAHB type show only weak effects. The enolic mono N-alkyl 5-acyl 2-thiobarbituric acids show two isomers, both of which are involved in enol-enol tautomerism.