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Meso-tetraphenylporphyriniron(iii) chloride catalyzed oxidation of aniline and its substituents by magnesium monoperoxyphthalate in aqueous acetic acid medium

Raja M., Kulandaivelu K.

Polish Journal of Chemical Technology

2012

Vol. 14, nr 4

35-41

The catalytic properties of the fi rst generation catalyst meso-tetraphenylporphyriniron(III) chloride and magnesium monoperoxyphthalate (MMPP) as oxidant have been studied in the oxidation of aniline and its substituents in acetic acid medium. The thermodynamic parameters for the oxidation have been determined and discussed. It confi rms the Exner relationship (only at the low range of temperatures) and also some of the activation parameters to the isokinetic relationships. The magnesium monoperoxyphthalate oxidation with 18 ortho- meta- and para-substituted anilines fulfi lls with isokinetic relationship but not to any of the linear free energy relationships. The reaction mechanism and the rate law were proposed.

Role of pH and current density in electrodeposited soft magnetic Co-Ni-Fe alloy thin films

Sundaram K., Raja M., Thanikaikarasan S., Chu J. P., Mahalingam T.

Materials Science Poland

2011

Vol. 29, No. 3

165--170

The influence of pH and current density on the structural and magnetic behavior of soft magnetic Co-Ni-Fe alloy thin films has been studied. The effect of pH and current density on the compositional, structural, and magnetic properties of the as-obtained films was investigated by EDX (energy dispersive analysis by X-rays), XRD (X-ray diffractometer) and VSM (vibrating sample magnetometer). The EDX results revealed that at the optimized deposition conditions, nickel content was low compared with cobalt and ferrous content. X-ray diffraction patterns revealed that the deposited films have polycrystalline nature with mixed (fcc-bcc) cubic structure and small crystallite size (<20 nm). The films prepared in optimized conditions exhibit high saturation magnetization (4pMs value above 2T) and low coercivity (below 160 A/m), which may be due to the reduced crystallite size.