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Lower Toarcian organic-rich sediments from the Tuscan Succession (Northern Apennines, Italy): preliminary results

Perilli N., Rodrigues R., Veiga de Oliveira L., Catanzariti R.

Volumina Jurassica

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2009

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Vol. 7, no. 1

55-65

EN

For the first time is here documented the presence of Lower Toarcian black shales in the lower portion of the Calcari e marne a Posidonia (Posidonia Marls auctt.) belonging to the Tuscan Nappe. It consists of alternations of 30 cm to 5 m thick black laminated marlstone and marly claystone, with TOC values ranging from 0.43% to 2.49%. Based on calcareous nannofossils, the basal portion of the Calcari e marne a Posidonia spans the Lotharingius hauffii to Carinolithus superbus zones, and the organic-rich interval lies within the Carinolithus superbus Zone.

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Pliensbachian – lowermost Toarcian chemostratigraphy (elemental and TOC) of the Peniche section (Lusitanian Basin, Portugal)

Veiga de Oliveira L., Duarte L., Rodrigues R.

Volumina Jurassica

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2006

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Vol. 4, no. 1

217-218

EN

In Portugal, the Peniche section constitutes one of the most continuous series of Lower Jurassic. This study is based on a detailed chemostratigraphic analysis of the Pliensbachian - lowermost Toarcian marly limestones, belonging to the Vale das Fontes, Lemede and Cabo Carvoeiro formations. 196 samples of limestones and marls were analyzed in terms of minor and major elements (Fig. 1). Total organic carbon (TOC) was determined in 233 samples. Besides the stratigraphic distribution of these geochemical parameters, the aim of this work is to perform a discussion about biogenic influx and aluminosilicate phasefluxes. The Al concentrations are a good indicator of detrital flux and good correlations between them signify aluminosilicate affiliation. In Peniche, K (0.98), Si (0.96) and Ti (0.98) show, in all section, excellent correlation with Al2O3. Mg (0.82), Ba (0.80), Cr (0.78), Li (0.80), Na (0.74), Sc (0.80), V (0.81) and Zr (0.86) correlate well with Al2O3 but other secondary factors, beyond the detrital flux, affect the resultant concentrations. The Pearson's coefficients between Al2O3 and CaO is strongly negative (-0.98), suggesting divergent behaviours for this elements. Al2O3 and Fe2O3 correlate moderately (0.61). However, the correlation coefficients calculated for each stratigraphic unit show variable values. Lemede Formation and the Members Marls and Limestones with Uptonia and Pentacrinus (MLUP), Lumpy Marls and Limestones (LML), to the Vale das Fontes Formation, and CC1, to the Cabo Carvoeiro Formation, show high correlation coefficients between Al2O3 and Fe2O3 (0.87, 0.91, 0.88 and 0.97, respectively). On the other hand, the Member CC2 has moderate correlation (0.67) and the Member Marls and Limestones with Bituminous Shales (MLBF) has weak correlation (0.20). These variations suggest that the elemental inputs change during the Pliensbachian - lowermost Toarcian, in the Peniche area. Ba enrichment is considered an indicator of high flux of biogenic material and high surface-water productivity. But, in the studied section, correlation between Al2O3 and Ba is high (0.80) and Ba lacks any correlation with TOC (0.17). Thus, in the Peniche region, the distribution of Ba is dominated by the original detrital flux and transported to the basin, mainly, as a constituent of clays. The mainly TOC values in the Pliensbachian - lowermost Toarcian of the Peniche section are below 2. But the MLBF (Ibex to Margaritatus zones) represents a high TOC interval with concentrations up to 15%, correlated with the 2nd order flooding interval, well know in the Lusitanian Basin.

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Lower Toarcian organic-rich sediments from the Tuscan Succession (Northern Apennines, Italy)

Perilli N., Veiga de Oliveira L., Rodrigues R., Catanzariti R.

Volumina Jurassica

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2006

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Vol. 4, no. 1

203-204

EN

This work is aimed to improve lithostratigraphy and biostratigraphy, based on calcareous nannofossils, of the deep-marine Lower Toarcian sediments belonging to Tuscan Nappe (Northern Apennines). The sampled lower part of the Calcari e marne a Posidonia (Posidonia Marls) correlates with the Marne del Monte Serrone of the Umbria-Marche Basin, which is characterized by the presence of the Lower Toarcian black shales. The Calcari e marne a Posidonia consists of grey to greenish hemipelagic to pelagic bivalves-bearing marlstones and limestones with interbedded grey to grey dark, sometimes reddish, clayey marlstones and marly claystones. In some localities, in the lower portion of this formation is recognized a thin to medium thick organic-rich interval of black marlstones and marly claystones. The recovered calcareous nannofossil assemblages allow to assigne the basal portion of the Marne a Posidonia to the Lower Toarcian with the thin organic-rich interval comprised between the appearances of the genera Carinolithus and Discorhabdus.

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Calcareous nannofossils biostratigraphy and oxygen isotope composition of belemnites: Pliensbachian – lowermost Toarcian of Peniche (Lusitanian Basin, Portugal)

Veiga de Oliveira L., Duarte L., Rodrigues R., Perilli N.

Volumina Jurassica

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2006

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Vol. 4, no. 1

219-219

EN

The Lusitanian Basin is located in the western Iberian margin, opened during the Triassic.The Lower Jurassic is particularly well represented at Peniche, which exhibits a continuous seriesof carbonate sediments, more than 450 m thick and aged between Sinemurian and Toarcian.In lithostratigraphic terms it corresponds to the Agua de Madeiros, Vale das Fontes, Lemede and CaboCarvoeiro formations. In this study, 145 m thick section (from the Jamesoni to the Levisoni ammonite zones),was analyzed in terms of calcareous nannofossils biostratigraphy and oxygen isotopes of belemnite rostra.The nannofossil biozones NJ4a, NJ4b, NJ5a (Pliensbachian; upper part of Jamesoni to Spinatumammonite zones), NJ5b (uppermost Pliensbachian - lowermost Toarcian; upper part of Spinatumto Levisoni ammonite zones) and NJ6 (lowermost Toarcian; upper part of Levisoni ammonite Zone) wereidentified based on proposed NW European schema and correlated with ammonite zones. Additionally,the secondary biostratigraphic events were registered which will be useful to refine the nannofossilsbiozonation: the first occurrences (FO) of Biscutum grande and B. finchii were found in the upper part ofthe NJ4a biozone (lower part of Margaritatus ammonite Zone); the FO of Lotharingius frodoi wasidentified at the same stratigraphical level as L. hauffii; the FO of L. sigillatus was found in the upper partof the NJ5a biozone (Spinatum Zone); the first common occurrence (FCO) of Calyculus spp. was recognizedin the NJ5b base, near the Pliensbachian/Toarcian boundary; the FO of Carinolithus spp. was identifiedwithin NJ5b biozone, correlated with the lower part of the Levisoni ammonite Zone and below the extinctionlevels of Calcivascularis jansae and B. grande which are other nannofossil secondary events.The oxygen-isotope profile of the Peniche section seems to reflect primary signals and can be usedto interpret the sea water paleotemperatures variations. In the Early Pliensbachian the temperature showsa gradual cooling trend (NJ3 and the lower part of the NJ4a; Jamesoni ammonite Zone). Afterward,there is a warm period (NJ4a and NJ4b; Jamesoni to lower part of Spinatum ammonite Zone) correlatedwith high TOC values interval (up to 15%), suggesting a relative sea level rise and concomitant high surfacewaterproductivity. In fact, the Margaritatus ammonite Zone corresponds, in the Lusitanian Basin,to 2nd-order flooding interval. In the Late Pliensbachian and Early Toarcian (NJ5a and lowermost partof NJ5b; Spinatum to Polymorphum ammonite zones), the isotopic values show slight variations.However, they suggest a small cooling trend in the upper part of Spinatum ammonite Zone and a warmtendency in the lower part of Polymorphum ammonite Zone.