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EN
Climate-related trends and meteorological conditions in the Porsanger fjord, in the vicinity of the Barents Sea, have been analyzed. Meteorological data include wind speed and direction, air temperature (AT) and precipitation from Era-Interim reanalysis (1986-2015) as well as local observations (2006-2015) from Honningsvaag and Lakselv. Statistically significant trends in annual AT means are 0.0485°C year−1 near the fjord mouth and 0.0416°C year−1 near the fjord head. Wind speed and precipitation data do not reveal any definite trends. Statistical analysis confirms the significant spatial variability of meteorological conditions in the fjord. For example, there are large differences in the annual AT cycle, with respective monthly means for January and July of −8.4 and 12.6°C at Lakselv (fjord head) and −2.5 and 10.1°C at Honningsvaag (fjord mouth). Strong wind events (>12 m s−1) are more frequent at Honningsvaag than at Lakselv. The annual cycle is characterized by stronger winds in winter and seasonality of wind direction. At Lakselv, the dominant wind directions in summer are: N, NNW and S and in winter: S and SSE. At Honningsvaag, the wind directions in summer present strong variability, no fixed pattern being pronounced, whilst the dominant sectors in winter are: S and SSW. Daily cycles in AT and wind speed are also observed. Precipitation at a given location can change by about 30% year-on-year and varies spatially. Estimates of terrigenous water discharge (derived from the E-HYPE model) reveal a seasonal cycle with the maximum discharge in late spring/early summer.
EN
Facing the still growing demand for metals, particularly for zinc, the recovery of metals from secondary sources should be considered. Spent pickling solutions can be the source of valuable products such as hydrochloric acid, zinc or iron salts or even metallic zinc. The selection of an efficient, selective and economical method for the regeneration of such solutions is a key issue for hot dip galvanizing plants, especially in reference to strict environmental protection regulations.
EN
The extraction of palladium(II) from hydrochloric acid solutions of various concentrations in the presence of different amounts of sodium chloride with phosphonium ionic liquid CyphosŽIL101 in toluene was investigated. The extraction of Pd(II) is very effective. The percentage extraction of Pd(II) from 0.1 mol dm-3 HCl solution amounts to 97% with CyphosŽIL101. Both the increase in HCl concentration and the presence of NaCl have a negative influence on the extraction. The extent of extraction from 0.1 mol dm-3 HCl solution in the presence of 0.5 mol dm-3 NaCl is about 80% and from 3 mol dm-3 HCl is lower and amounts to 56%. The extraction of Pd(II) from aqueous 0.1 mol dm-3 HCl and from 0.1 mol dm-3 HCl in the presence of 0.5 mol dm-3 NaCl with this phosphonium ionic liquid is rapid and the equilibrium is achieved after 1 - 2 minutes. The extraction of Pd(II) from aqueous 3 mol dm -3 HCl is slower and the equilibrium is achieved after 5 - 6 minutes.
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