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Energy transfer in peptides based on phthalimide derivatives of aliphatic aminoacids

Yukhimenko N., Savchenko I., Kolendo A., Syromyatnikov V., Błażejowski J., Wiczk W.

Materials Science

2002

Vol. 20, No. 4

77-83

Model peptides containing phthalimide derivatives of aliphatic aminoacids with various number of methylene groups in side chains have been synthesized and investigated spectroscopically. The study aimed at the creation of polymers with the intramolecular triplet-triplet excitation energy transfer. In all compounds investigated, efficient triplet-triplet energy transfer is observed, resulting in the phosphorescence only from phtalimide t-electronic system in frozen solutions at 77 K.