The complexes of Hg(II) with 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole, 3,5-diamino- 1,2,4-triazole, 3-amino-5-methylthio-1,2,4-triazole, 1H-1,2,4-triazole-3-thiol and 3-amino-5-mercapto-1,2,4-triazole have been prepared and characterized by elemental analysis, infrared spectra and thermal analysis. The ligands form 1:2 mononuclear and 1:1 polymeric complexes. The structure and the thermal decomposition of the complexes depend on the nature of donor atoms.
The complexes of Cu(II) with 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole and 3-amino-5-methylthio-1,2,4-triazole have been preparated and characterized by metal and CHN analyses, infrared and visible spectral and magnetic susceptibility data. It has been found, that the first two ligands from mononuclear species, while the third ligand forms the polynuclear complex. All the complexes have pseudo-octahedral configuration with a tetragonal distortion.
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.