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The role of β (Al12Mg17) phase on corrosion behavior of the AM90 alloy in NaCl aqueous solution

Hatakeyama Masahiko, Shimada Yusuke, Kawate Naoki, Sarayama Kaede, Sunada Satoshi

Archives of Metallurgy and Materials

2022

Vol. 67, iss. 2

759--766

The β phase (Al12Mg17) precipitated by heat treatment in some alloy compositions may result deterioration of corrosion resistance. However, much of its role remains unclear. The effect of the β phase on the corrosion resistance behavior in a NaCl solution was presented in this study. The specimen was Mg-9mass%Al (AM90) alloy and the content of the β phase precipitant was controlled systematically by aging time at 473 K. Area rate of β and lamellar phase in the specimens were 0, 10 and 100%, respectively. According to the results of cathodic polarization curves measurement, the corrosion current density of α phase was 0.215 A/m2 and β phase of it was 0.096 A/m2. While, the specimen includes 10% of β and lamellar phase showed large corrosion current density of 0.251 A/m2. Positive correlation between the β phase and the open circuit potential, suggest that the β phase acts as a cathodic electrode. Moreover, the microstructure after postentiostatic corrosion tests was also support the role of β phase.