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Wykorzystanie nowych metod badawczych w analizie degradacji termicznej pojedynczej cząstki drewna : radiografia, tomografia, radiografia izotopowa

Kazimierski Paweł

Przemysł Chemiczny

2024

T. 103, nr 3

387--390

Techniki radiograficzne, choć nie są rozpowszechnione w badaniu pirolizy biomasy, są potencjalnie bardzo dobrym źródłem danych eksperymentalnych pozwalających na lepsze zrozumienie procesu. Omówiono zalety i ograniczenia technik radiograficznych, takich jak radiografia klasyczna, cyfrowa oraz bezpośrednia, a także technika powiązana, którą jest tomografia. Przedstawiono także metodę obrazowania z wykorzystaniem selenu 75. Przykładowe obrazowanie modelowych próbek drewna pokazało użyteczność tych metod w badaniu pirolizy pojedynczej cząstki paliwa, a także złoża paliwa.

Classic, digital and direct radiography, as welI as tomography, were used to image samples of low-d. materia/s, such as wood or solid pyrolysis products. The suitability of these methods for testing a single material particie during the pyrolysis process was discussed. The advantages and disadvantages of each technique were presented.

Pyrolysis-derived waste polypropylene oils in gas turbine engines: a comprehensive performance and emission study

Suchocki Tomasz Kacper, Kazimierski Paweł, Januszewicz Katarzyna, Lampart Piotr, Klimaszewski Piotr, Witanowski Łukasz

Archives of Thermodynamics

2023

Vol. 44, no 4

157--183

Addressing the burgeoning issue of polymer waste management and disposal, chemical recycling, specifically the production of highquality oil, presents an enticing solution. This research paper delves into the process of plastic waste pyrolysis, focusing on polypropylene, and thoroughly examines the physico-chemical properties of the resulting pyrolytic oil. The oils, obtained from waste plastic pyrolysis (referred to as WPPO), are then blended with kerosene and utilized as fuel for a gas turbine engine. The primary objective of this investigation is to ascertain how the blend composition influences the performance and emission parameters of the micro gas turbine. In our findings, it was observed that all tested waste plastic pyrolysis blends displayed a trend towards escalating regulated emissions such as nitrogen oxides (NOx) with an average increase of 26% for polypropylene pyrolysis oil (PPO). The emission index (EI) for carbon monoxide (CO) was found to be relatively consistent across all fuel blends tested in this study. Interestingly, when considering the thrust specific fuel consumption (TSFC) within the EI calculation, blends of aviation kerosene and plastic oil showed lower values in comparison to the pure Jet A-1 fuel. Furthermore, an augmentation in the proportion of WPPO in the blends consequently led to an elevation in the exhaust gas temperature (an average increase of 8.7% for PPO). Interestingly, the fuel efficiency of the Jet engine, expressed as TSFC, demonstrated a decrease, with an average reduction of 13.8% observed for PPO.