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1 2009

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Premixed combustion of acetylene-hydrogen fuel mixtures for thermodynamic state generation in a constant volume combustion vessel

Johnson S., Nesbitt J., Lee S. -Y., Naber J. D.

Journal of KONES

2009

Vol. 16, No. 2

199-208

Flammability limits and flame speeds of dilute-lean fuel mixtures of hydrogen (H2) and acetylem premixed with oxygen (02) and nitrogen (N2) were examined with a detailed kinetics model. These mixtures are used in a preburn in a constant volume combustion vessel to create elevated temperatures and pressures with gas compositions that represent the thermodynamic state in a diesel engine combustion chamber at fuel injection and auto ignition. A mixture of hydrogen and acetylene with combined atomic hydrogen to carbon ratio (HCR) of 1.85 was used to match that of typical diesel fuel and results are shown in comparison to a previously used mixture with a HCR of 1.17. The lower flammability limit (LFL) of the HCR 1.85 fuel mixture was found at an equivalence ratio of 0.235, while flame speed and adiabatic combustion temperatures were also predicted for post preburn product oxygen levels between O and 21 percent. Flame speeds were shown to decrease with a reduction in oxygen concentration, an increase in nitrogen dilution, while combustion temperatures increased over most of this range. Trends for this relation of flame speed and temperature are presented and a new premixed fuel mixture with an HCR of 1.85 is proposed.