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Chlorine is a popular disinfectant used in Malaysia in the treatment process of drinking water supply because of its effectiveness. The concentration of chlorine deteriorates upon travelling in the system due to its reaction with organic matter to produce carcinogenic substances known as disinfection by-products (DBP) such as trihalomethanes (THM). This study was conducted to investigate chlorine decay and THM formation in a state's drinking water distribution system in Malaysia specifically across a 24.9 km distance. EPANET 2.0 Software program was used to perform hydraulics and water quality analysis using the extended period simulation (EPS) for 24 hours demand pattern. A simulation of the water distribution system was performed to identify the formation of THM and its relationship between chlorine and total organic carbon (TOC). The value of THM was maintained at a lower level at the water treatment plant (WTP) than at the endpoint of the distribution system. At the endpoint, which was at the targeted industrial area, the level of THM was found to increase and the obtained data showed that its formation occurred along the investigated distribution system. THM formation manifested as the natural organic matter (NOM) presence along the pipe continuously reacted with chlorine which was dosed in the distribution system.
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