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Processing of phosphorites with extraction of phosphorus, obtaining calcium carbide and ferroalloy

Shevko Victor M., Uteyeva Raisa A., Badikova Alexandra D., Tleuova Saltanat T.

Physicochemical Problems of Mineral Processing

2023

Vol. 59, iss. 6

art. no. 174463

The article considers the results of studying the thermodynamic computer modeling of the interaction of phosphorite (Karatau basin, Kazakhstan) with carbon and coke performed using the HSC-10 software package and electric smelting of the phosphorite with coke and steel shavings in an arc furnace. The modeling allowed us to determine the equilibrium extraction degrees of phosphorus into gas (Р2, Р4), silicon into ferroalloy in the form of iron silicides (FeSi2, FeSi, Fe3Si, Fe5Si3, Si) and calcium into CaС2. At temperatures above 1500 °C, regardless of the amount of iron, the extraction degree of phosphorus into gas is more 99%. The resulting ferroalloy contains 21.2-23.8% of Si, 1.6-2.8% of Al; the calcium carbide has a capacity of 288-325 dm3/kg. The extraction degree of silicon into the alloy was 89.8%, calcium in CaC2 - 72.5%, phosphorus into gas - 99.4%. The ferroalloy, formed at the electric smelting of the Chulaktau phosphorite together with coke and steel shavings and containing 24.9-29.8% of Si, is FS25 grade ferrosilicon, and the formed calcium carbide has a capacity of 278-290 dm3/kg and belongs to the third and second grades. The developed technology makes it possible to increase the degree of phosphorites’ comprehensive use two times (up to 87.5%).

Kinetic study of oil-containing wastewater treatment with the use of natural sorbents

Tleuova Saltanat T., Userbayeva Banu A., Tleuov Alibek S., Yeskendirova Marina M., Yakubova Raissa R., Kerimbayeva Kulyash Z.

Journal of Water and Land Development

2021

no. 49

252--258

The study has investigated the technical characteristics of a number of sorption materials (natural mineral) and the possibility of their use for the purification of surface and wastewater from oil and oil products. At the first step, regularities of the process of purification of oily waters have been established taking into account the processes of filtration and sorption. After that, the sorption capacity of the sorbents has been estimated, and the factors influencing it analysed. As a final step, the optimal conditions for the sorption process have been selected depending on the conditions and nature of purification. Results indicated that the maximum purification degree has been reached at the concentration of 500 mg∙dm–3 and temperature of 20°С.