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Physicochemical and Mechanical Characterization of Ceramic Materials from Meknes Region (Morocco)

Mesrar Hamza, Mesrar Laila, Jabrane Raouf

Journal of Ecological Engineering

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2023

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Vol. 24, nr 8

183--197

EN

This scientific paper presents a comprehensive study of the physical and chemical properties of a clay sample collected from Meknes region of Morocco. X-ray diffraction analysis revealed the presence of kaolinite, muscovite, and quartz minerals in the clay sample. X-ray fluorescence analysis showed that the sample contained a significant amount of aluminum and silica. The Atterberg limit test indicated that the clay has a high plasticity index and is classified as a clay of low to medium plasticity. The ATG_DSC analysis revealed that the sample underwent multiple endothermic reactions, including dehydration, dehydroxylation, and decarbonation, at different temperature ranges. Shrinkage and weight loss experiments showed that the clay exhibited high shrinkage and weight loss upon drying. SEM-EDX analysis provided information on the microstructure and elemental composition of the clay sample. The water absorption test revealed that the clay has a low water absorption capacity. The three-point flexural test showed that the clay bricks had high flexural strength, which makes it suitable for use in high-stress applications. Overall, the results suggest that the clay sample can be used in a variety of applications, including building materials, ceramics, and other industrial uses.

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Manufacture of Clay Aggregate Doped with Pozzolan Destined for Lightweight Concrete

Mesrar Hamza, Mesrar Laila, Touache Abdelhamid, Jabrane Raouf

Journal of Ecological Engineering

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2023

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Vol. 24, nr 1

349--359

EN

In this work, marl clay was used because these materials have a very important industrial potentiality in several fields, namely ceramics. The objective was manufacturing expanded clay aggregate (ECA), with two main ingredients of marl and pozzolan at different percentages in order to integrate them into the concrete as aggregate. The physicochemical parameters of the mixture marl / Pozzolan was discussed and the results of the analyses, allowed deducing that the sample with 15% pozzolan has the most expansion rate of 16.8%, and its density of 1232 kg/m3 is in accordance with the international standard of expanded aggregates. The density of the concrete decreases with the quantity of ECA added and reaches its minimum with 1671 kg/m3 according to concrete with 50% of the expanded aggregate. The bending tests show the increase of the mechanical strength as a function of the quantities of aggregate added. The results show a very important potential with the addition of clay aggregates, density and water absorption decrease with the increase of the mechanical resistance.

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Assessment of Heavy Metals Contamination in Spoil Heaps of Ain Aouda Mine (Taza, Morocco)

Assabar Narmine, Lahmidi Ikram, Jabrane Raouf

Journal of Ecological Engineering

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2023

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Vol. 24, nr 3

224--231

EN

The purpose of this study is to evaluate the level of heavy metal contamination in the spoil heaps of the former Ain Aouda mine (Taza). In this regard, solid samples of the study area were sampled. The set of analyses carried out have detected the presence of zinc (Zn), lead (Pb), copper (Cu), arsenic (As) and nickel (Ni) that remain in these metal discharges. The calculation of contamination/pollution indices: the Geo Accumulation Index (Igeo), the Enrichment Factor (EF) and the Pollution Index (IP) were used to predict the extent of heavy metal contamination. The results of this study suggest that the spoil heaps reveal polymetallic contaminations allowing the trace metal elements to be classified in the following order Zn ˃ Pb ˃ As ˃ Cu > Ni. Knowing well that the alteration and erosion of this stock of mine waste could contribute to the degradation of the natural environment by these elements that are present.

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Geochemical Characterization of the Spoil Heaps of the Ain Aouda Mine and its Impact on the Soil (Morocco)

Assabar Narmine, Lahmidi Ikram, Choukrad Jaouad, Jabrane Raouf

Ecological Engineering & Environmental Technology

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2023

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Vol. 24, iss. 6

100--108

EN

The exploitation of the Ain Aouda zinc lead mine in the Tazekka massif (Morocco) has abandoned spoil heaps stored directly on a karstified carbonated ground, without any means of precaution. The heaps were exposed to the weather agents, such as water infiltration and air circulation, which would generate a real source of pollution for the ecosystem. This pollution will inevitably produce effluents that can be loaded with metals and metalloids, which will have a significant negative influence on the soil and the environment. In this regard, the objective of this study was to confirm the existence of contamination of soils by using the technique of atomic emission spectrometry with inductively coupled plasma, and of spoil heaps by X-ray diffractometry, which confirmed the contamination by zinc, arsenic, lead and copper. Their maximum concentrations are 19858.800 (ppm), 1280.700 (ppm), 495.750 (ppm), and 328.65 (ppm), respectively. Nevertheless, it was noted that the pH of the majority of soils always remains basic, due to the significant presence of carbonates, the majority of soils are calcareous (15% to 30%) to very calcareous (> 30%). It was noticed that the phenomenon of neutralization occurs.

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Assessment of Soil and Surface Water Quality in Makhat’s Watershed (Taza Province, Morocco)

Lahmidi Ikram, Tzoraki Ourania, Mesrar Laila, Benaabidate Lahcen, Assabar Narmine, Laaraj Marouane, Jabrane Raouf

Ecological Engineering & Environmental Technology

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2023

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Vol. 24, iss. 2

194--204

EN

Acid mine drainage (AMD) threats the soils and water bodies in the territories of the sulfide mining activities all over the world. Bouaazza’s mine (NE Morocco) lead and sulfides exploitation resulted in the surface exposure of large superficies of acid discharges. The results of physicochemical and geochemical analysis indicate an acidic pH (3.0–7.0) of water samples, with concentrations of lead exceeding Moroccan standards (50 μg/L). The pH in soils is considered from slight up to moderate acidic (< 6.5), with low limestone content (< 6% of CaCO3), and high lead and zinc values exceeding international standards (300 mg/kg). These results indicate the high health risk generated by the absence of environmental monitoring of the mining operations which threaten the water quality in the surrounding area.