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1 Polish Journal of Chemistry

1 2004

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The State Dependency of the Effective Pair Potential Parameters

Keshavarzi E., Hashemi F., Ghazvini Z.

Polish Journal of Chemistry

2004

Vol. 78 / nr 10

1893-1906

The state dependency of the effective pair potential parameters [epsilon eff (T,ro ), sigma eff (T)] has been studied for gas, liquid and supercritical regions for different types of fluids.We have assumed that the configuration of potential energy between Nmolecules can be divided into independent pair clusters with an effective pair potential, in which the parameters of the potential are state dependent.We have obtained the values of epsilon eff (T, ro),and sigma eff (T) using p-V-T data. The results show, that epsilon eff (T, ro) increases with density for those thermodynamic states, at which pair interactions are dominant, while it decreases with density for those systems, where triplet and higher clusters are dominant. Both epsilon eff (T, ro) and sigma eff (T) decrease with temperature, which coincides with the literature data. Aremarkable result of the present work is the determination of density, at which triplet clusters come into account. We have also shown new corresponding states for the effective well depth parameter, which is held for all examined fluids, including Ar, Xe, CH4, N2, CO, H2O, CO2, CH3OH, C2H6 and C6H6 for different isotherms. Alinear dependence of epsilon eff (T, ro) versus density and temperature on the zeno-line is predicted.