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Experimental and kinetic study of zinc leaching from metallurgical slag by 5-sulfosalicylic acid

Wang Long, Gao Hanyu, Song Shimin, Xue Na, Zhang Jinxia, Yang Siyuan, Liu Cheng

Physicochemical Problems of Mineral Processing

2021

Vol. 57, iss. 3

8--20

As an organic acid with the characters of low corrosivity and extensive source, 5-sulfosalicylic acid (5-SSA) was firstly utilized as a potential leaching reagent for the recovery of zinc from metallurgical slag. Effects of stirring speed, leaching temperature, 5-SSA concentrations and size fraction on the leaching zinc leaching rate were investigated. A zinc leaching efficiency of 94.2% was achieved under the appropriate operating conditions (450 rpm of stirring speed, 50 ℃ of leaching temperature, 0.3 mol/L of 5-SSA concentration and d90=65 µm of size fraction), indicating that 5-SSA was an excellent leaching reagent of zinc oxide. SEM-EDS and specific surface aperture analyzer further reveal the well-developed micropores and cracks from zinc metallurgical slag, which could be assigned to the removal of zinc oxide encapsulated in the sample. In addition, the leaching kinetics of zinc metallurgical slag in the 5-SSA was studied. It was found that the surface chemical reaction model satisfactorily predicted the zinc leaching rate. A reaction kinetic equation was finally established for the zinc leaching rate.

Study on the floc-bubble adhesion behavior of hematite in static flow field

Zhang Jinxia, Feng Hongjun, Niu Fusheng, Sun Weiguang, Zhao Yawei

Physicochemical Problems of Mineral Processing

2020

Vol. 56, iss. 1

124--133

To investigate the adhesion of hematite flocs to gas bubbles in floc floatation, this paper develops an observation system for floc-bubble collision and adhesion with two charge-coupled device (CCD) cameras. The sizes of flocs and bubble were 45.36μm and 0.90mm, respectively, and the distance between a floc and the bubble center (sedimentation distance) was set to 0.25cm. Three surfactants, namely, sodium oleate, lauryl amine and sodium dodecyl sulfate (SDS), were selected for our research. Several experiments were conducted to disclose how surfactant concentration and pH affect the surface adhesion between hematite flocs and bubbles. Then, the adhesion mechanism was discussed in details based on the experimental results. The results show that the highest adhesion probability was achieved for the said floc and bubble at the lauryl amine concentration of 8mg/L, the sedimentation distance of 0.25cm and the pH of 9. After touching the bubble, the hermamite floc slid on the bubble surface, forming a stable three-phase interface after 67ms. Then, the radial position of the floc no longer changed, despite the floc motion on the bubble surface. According to the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory and the potential energy of the van der Waals force, there was a repulsive force between the floc and the bubble in the absence of surfactant and an attractive force in the presence of the surfactant of lauryl amine. In addition, a thin solvation shell is conducive to the adhesion between the floc and the bubble.