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2 Polish Journal of Chemistry

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New Optically Active Manganese(II) Complexes with Schiff Bases Obtained from (1R,2R)-(-)-1,2- Cyclohexanediamine and Salicylaldehyde Derivatives

Szłyk E, Surdykowski A., Goździkiewicz M.

Polish Journal of Chemistry

2001

Vol. 75, nr 11

1781-1784

Spectroscopic and Thermal Studies of Silver(I) Complexes with Aliphatic Carboxylates and Triphenylphosphine

Szłyk E., Łakomska I., Surdykowski A., Goliński A.

Polish Journal of Chemistry

1999

Vol. 73, nr 11

1763-1769

Results of spectral analysis are in favour of Ag(I) trigonal coordination with unidentately bonded triphenylphosphine and bidentate carboxylates, forming bridges between silver(I) ions. Thermal decomposition was studied in 293-973 K range in nitrogen. The multistage decomposition initiates with the detachment of carboxylates and is followed by triphenylphosphine dissociation. The final product is metallic silver, formed between 605-683 K.