Alternating field and thermal demagnetization of dolomite samples from the Silurian (Llandovery) horizontally-bedded sequence of central Estonia reveal two secondary magnetization components (A and B) both of chemical origin. A low-coercivity (demagnetized at -50 mT) component A (D = 60.7°, I = 7.7°, alfa95 = 16.6°) with high dispersion (k = 14.2), yields a palaeopole at 18.2°N and 139.5°E that points towards the Late Devonian — Mississipian segment of the Baltica APWP (Apparent Polar WanderPath). A high-coercivity component B (D = 13.5°, I = 60.7°, k = 67.0, alfa 95 = 4.7°) carries both normal and reversed polarities. Comparing the palaeopole (71.1°N and 173.3°E) with the European APWP reveals a Cretaceous age. These two remagnetizations are linked to mineral assemblages of magnetite and maghemite (A), and hematite (B) determined from mineralogical (X-ray, SEM and optical microscopy) and rock magnetic (acquisition and thermal demagnetization of a 3-component IRM; Lowrie-test) studies. The results suggest that the first (A) Palaeozoic remagnetization was caused by low-temperature hydrothermal circulation due to the influence of the Caledonian (more likely) or Hercynian Orogeny after the diagenetic dolomitization of carbon ates. Hematite, carrying the component B, and goethite, are the latest ferromagnetic minerals that have precipitated into the existing pore space (hematite) and walls of microscopic fractures (goethite) that opened to allow ac cess for oxygen-rich fluids during the Late Mesozoic.
The present study discusses lithology and diagenetic characteristics of the siliciclastic Cambrian and the enclosing Ediacaran and Ordovician deposits in the northern Baltic Sedimentary Basin (BSB). The Neoproterozoic and Lower Palaeozoic sediments are despite their age unconsolidated with primary porosity of 20-25% for both shales and sandstones. The sparse Fe-dolomite cementation of arenitic and subarenitic sandstones and siltstones occurs mainly at lithological contacts with the massive Ediacaran and Lower Cambrian claystones and is probably related to ions released during llitization. In contrast to weak mechanical and chemical compaction of sandstone, the clay mineral diagenesis of Cambrian deposits is well advanced. The highly illitic (80-90%) nature of illite-smectite (I-S) suggests evolved diagenetic grade of sediments which conflicts with shallow maximum burial and low compaction. Smectite-to-illite transformation has resulted in formation of diagenetic Fe-rich chlorite in claystones. Some porosity reduction of sandstones is due to formation of authigenic kaolinite at the expense of detrital mica or K-feldspar.
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