Cu(II), Co(II), Ni(II) and Zn(II) metal complexes of new heterocyclic Schiff base derived from 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one with salicylaldehyde have been synthesized and characterized by elemental analyses, mass, electronic, IR and 1H NMR spectra, and also by molar conductivity measurements, magnetic moment measurements and thermogravimetric analyses (TGA). It has been found that the Schiff bases behave as a neutral bidentate (NO) and tridentate (ONO) ligands forming chelates with 1:2 (metal:ligand) stoichiometry. Octahedral environment is suggested for metal complexes. The conductivity data for the Ni(II) complexes are consistent with those expected for an electrolyte.
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