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1 Polish Journal of Chemistry

1 2008

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Real-Time Probing of Fast Photoinduced Charge-Transfer in Electron Donor-Acceptor Model Compounds and in Biological Photosensors

Martin M. M., Plaza P., Changenet-Barret P.

Polish Journal of Chemistry

2008

Vol. 82, nr 4

759-771

We review some of our results on the role of solvent reorganization as an actual reaction coordinate in a few photoinduced charge-transfer processes concerning: dimethylaminobenzonitrile (DMABN), bianthryl and its 10-cyano-derivative and anthracenedimethylaniline (ADMA), in solution at room temperature. These processes were studied by subpicosecond transient absorption spectroscopy. We also describe some of our recent results on charge-transfer processes involved in the primary response of photoactive proteins such as the photoactive yellow protein (PYP) and the oxyblepharismin-binding protein (OBIP). The deciding role of the protein environment in the photophysics of the chromophore is emphasized.