Porous and non-porous gas separation membranes were used for concentration of biohydrogen produced by a heterotrophic hyper-thermophilic, anaerobic micro-organisms. A laboratory-scale integrated system was designed and built based on a liquid seal system and more than 70% hydrogen concentration was achieved from the initial gaseous mixture containing hydrogen, carbon dioxide and nitrogen. Liquid absorption and desorption of the carbon dioxide were also studied.
Polyimide-silica hybrid films with covalently bound phases were prepared via a sol - gel process. The starting materials were p-aminophenyltrimethoxysilane terminated poly(amic acid)s of controlled molecular weight and tetramethoxysilane. The actual extent of the sol-gel process was monitored by thermogravimetric analysis. The dependence of the membrane properties on the silica content and/or concentration of bonds between phases was studied.Pč/!
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