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Carbonised fluidised fly ash (CFFA); a new product for mining engineering purposes (discussion of possible applications)

Łączny Marian Jacek, Rompalski Przemysław

Journal of Sustainable Mining

2022

Vol. 21, iss. 3

191--199

The article presents and summarises the current state of research and laboratory results on the carbonation of fly ash with carbon dioxide in the context of its use in mining engineering. Based on previous publications and patent applications, the possibilities of using carbonated fly ash from fluidised bed boilers for the following applications were discussed: securing excavations particularly susceptible to fire hazards, shotcreting and securing longwalls and supports, constructing cases, securing decommissioned shafts, and others, which means wherever the use of cement is required. It was pointed out that the removal of excess free calcium oxide makes it possible to use carbonated fly ash in mining applications for placement in workings requiring increased tightness. It was also stated that carbonation allows the removal of hydrogen from fluidised fly ash (FFA) obtained during co-combustion. The research highlighted the potential and importance of granulating carbonised FFA in expanding the applications of this innovative product in mining engineering.

Evaluation of the possibility of using granulated carbonated volatile fly ash from fluidized beds (G-CVFA) in underground mining techniques

Proksa Jadwiga, Łączny Marian Jacek, Bzowski Zbigniew

Archives of Mining Sciences

2020

Vol. 65, no. 4

737--750

The application of fluidized fly ash in underground mining excavations is limited due to its significant content of free calcium and calcium sulfate. In order to increase the amount of utilized fly ash from fluidized beds, it should be converted to a product with properties that meet the requirements for mining applications. This research presents the results of an attempt to adapt fluidized fly ashes for use in underground mining techniques, by means of carbonation and granulation. Carbonation was performed with the use of technical carbon dioxide and resulted in the reduction of free calcium content to a value below 1%. Granulation on the other hand, resulted in obtaining a product with good physical and mechanical parameters. The performed mineralogical and chemical studies indicate that trace amounts of "binding" phases, such as basanite and/or gypsum are present in the carbonized ash. The addition of water, during the granulation of carbonized fluidized fly ash, resulted in changes in the mineral phases leading to the formation of ettringite and gypsum as well as the recrystallization of the amorphous substance. It was confirmed that the carbonization and granulation of flying fluidized ashes positively affects the possibility of using these ashes in underground mining excavations.